Mineralogical controls on environmental mobility of arsenic from historic mine processing residues,New Zealand

Processing of arsenopyrite ore took place at Blackwater Au mine, New Zealand, between 1908 and 1951 and no rehabilitation was undertaken after mine closure. High As concentrations in solid processing residues (up to 40 wt% As) are due to secondary As minerals. Site pH regimes vary from 4.1 to circum-neutral. Originally, all processed As was present as arsenolite (arsenic trioxide polymorph, As^III), a by-product of arsenopyrite roasting. Near the roaster, scorodite precipitated as a result of the high dissolved As concentration during arsenolite dissolution. The formation of scorodite has two major consequences. Firstly, the scorodite precipitate cements the ground in the vicinity of the roaster area, thereby creating an impermeable surface crust (up to 30 wt% As) and encapsulating weathered arsenolite grains within the cement. Secondly, formation of scorodite temporarily immobilizes some of the dissolved As that is generated during nearby arsenolite dissolution. Where all the available arsenolite has dissolved, scorodite becomes soluble, and the dissolved As concentrations are controlled by scorodite solubility, which is at least two orders of magnitudes lower than arsenolite solubility. Downstream Eh conditions fall below the As^V/As^III boundary, so that scorodite does not precipitate and dissolved As concentrations are controlled by arsenolite solubility. Dissolved As reaches up to 52 mg/L in places, and exceeds the current WHO drinking water guideline of 0.01 mg/L by 5200 times. This study shows that dissolved As concentrations in discharge waters at historic mine sites are dependent on the processing technology and associated mineralogy.     

gLucifer: next generation visualization framework for high-performance computational geodynamics

High-performance computing provides unprecedented capabilities to produce higher resolution 4-D models in a fraction of time. Thus, the need exists for a new generation of visualization systems able to maintain parity with the enormous volume of data generated. In attempting to write this much data to disk, each computational step introduces a significant performance bottleneck, yet most existing visualization software packages inherently rely on reading data in from a dump file. Available packages make this assumption of postprocessing at quite a fundamental level and are not very well suited for plotting very large numbers of specialized particles. This necessitates the creation of a new visualization system that meets the needs of large-scale geodynamic modeling. We have developed such a system, gLucifer, using a software framework approach that allows efficient reuse of our efforts in other areas of research. gLucifer is capable of producing movies of a 4-D data set “on the fly” (simultaneously with running the parallel scientific application) without creating a performance bottleneck. By eliminating most of the human efforts involved in visualizing results through postprocessing, gLucifer reconnects the scientist to the numerical experiment as it unfolds. Data sets that were previously very difficult to even manage may be efficiently explored and interrogated without writing to disk, and because this approach is based entirely on memory distributed across as many processors as are being utilized by the scientific application, the visualization solution is scalable into terabytes of data being rendered in real time.     

A geochemical model of mid-ocean ridge magma chambers

A computer model of mid-ocean ridge basalt generation using trace element geochemistry has been developed. The model simulates a periodically replenished, continually cooled and fractionated magma chamber, with periodic lava extrusion. Primitive basalts from the ocean floor are used to generate likely evolution paths for the magma chamber. The steady state variant of this model has led to the isolation of several variables which critically affect the basalt composition. Although the fraction of cumulates is an important parameter, other variables such as the volume of incoming magma batches, their frequency, and the volume of the mixing cell, play a critical part especially on slow-spreading ridges. The growing magma chamber model uses random number generators to simulate the initiation and growth of a chamber. This model predicts a rapid increase in incompatible element concentrations, immediately after chamber initiation on a fast-spreading ridge. This would occur in situations such as propagating rifts and may help in the understanding of ferrobasalt generation.     

Overview of the rocky component of Wild 2 comet samples: Insight into the early solar system,relationship with meteoritic materials and the differences between comets and asteroids

Abstract– The solid 2–10 μm samples of comet Wild 2 provide a limited but direct view of the solar nebula solids that accreted to form Jupiter family comets. The samples collected by the Stardust mission are dominated by high‐temperature materials that are closely analogous to meteoritic components. These materials include chondrule and CAI‐like fragments. Five presolar grains have been discovered, but it is clear that isotopically anomalous presolar grains are only a minor fraction of the comet. Although uncertain, the presolar grain content is perhaps higher than found in chondrites and most interplanetary dust particles. It appears that the majority of the analyzed Wild 2 solids were produced in high‐temperature “rock forming” environments, and they were then transported past the orbit of Neptune, where they accreted along with ice and organic components to form comet Wild 2. We hypothesize that Wild 2 rocky components are a sample of a ubiquitously distributed flow of nebular solids that was accreted by all bodies including planets and meteorite parent bodies. A primary difference between asteroids and the rocky content of comets is that comets are dominated by this widely distributed component. Asteroids contain this component, but are dominated by locally made materials that give chondrite groups their distinctive properties. Because of the large radial mixing in this scenario, it seems likely that most comets contain a similar mix of rocky materials. If this hypothesis is correct, then properties such as oxygen isotopes and minor element abundances in olivine, should have a wider dispersion than in any chondrite group, and this may be a characteristic property of primitive outer solar system bodies made from widely transported components.     

Detection and monitoring of offshore oil seeps using ERS/ENVISAT SAR/ASAR data and seep-seismic studies in Krishna–Godavari offshore basin,India

An attempt has been made to use synthetic aperture radar (SAR) data for detection and monitoring of offshore oil seeps in the eastern offshore areas of the Krishna–Godavari Basin, which has been supplemented and correlated with collateral free-air gravity and seismic data. Images of the study area obtained from ENVISAT ASAR image mode were processed and analysed in detail. A number of natural oil seepages were identified and distinguished from pollution and biogenic slicks. These were subsequently studied using different parameters to assign various degrees of confidence. The repetitiveness of the identified seepages was studied and a total of five areas of seep repetitions had been recognized in the study area. The seeps that are repeated in images of different dates are more likely to be of natural origin than others. Simulation and modelling of a particular oil slick arising has been attempted over the Krishna–Godavari offshore using MIKE 21 software.     

The ability of detainment bunds to decrease sediments transported from pastoral catchments in surface runoff

Erosion leading to sedimentation in surface water may disrupt aquatic habitats and deliver sediment-bound nutrients that contribute to eutrophication. Land use changes causing loss of native vegetation have accelerated already naturally high erosion rates in New Zealand and increased sedimentation in streams and lakes. Sediment-bound phosphorus (P) makes up 71–79% of the 17–19 t P y⁻¹ delivered from anthropogenic sources to Lake Rotorua in New Zealand. Detainment bunds (DBs) were first implemented in the Lake Rotorua catchment in 2010 as a strategy to address P losses from pastoral agriculture. The bunds are 1.5–2 m high earthen stormwater retention structures constructed across the flow path of targeted low-order ephemeral streams with the purpose of temporarily ponding runoff on productive pastures. The current DB design protocol recommends a minimum pond volume of 120 m³ ha⁻¹ of contributing catchment with a maximum pond storage capacity of 10 000 m³. No previous study has investigated the ability of DBs to decrease annual suspended sediment (SS) loads leaving pastoral catchments. Annual SS yields delivered to two DBs with 20 ha and 55 ha catchments were 109 and 28 kg SS ha⁻¹, respectively, during this 12-month study. The DBs retained 1280 kg (59%) and 789 kg (51%) of annual SS loads delivered from the catchments as a result of the bunds' ability to impede stormflow and facilitate soil infiltration and sediment deposition. The results of this study highlight the ability of DBs to decrease SS loads transported from pastures in surface runoff, even during large storm events, and suggests DBs are able to reduce P loading in Lake Rotorua.     

Antiquity and long-term morphological stasis in a group of rove beetles (Coleoptera: Staphylinidae): Description of the oldest Octavius species from Cretaceous Burmese amber and a review of the “Euaesthetine subgroup” fossil record

The Staphylinine group of rove beetle subfamilies is a significant animal radiation, and one subordinate monophyletic clade – the ‘Euaesthetine subgroup’ – includes around 3000 species in subfamilies Euaesthetinae and Steninae and has a fossil record dating to the Early Cretaceous. Detailed morphological study of a new well-preserved Cretaceous Burmese amber fossil revealed strong evidence consistent with its taxonomic placement in the euaesthetine genus Octavius. We thus describe Octavius electrospinosus sp. nov., the first Cretaceous record of the genus and of the tribe Euaesthetini. Previously, the oldest records of Octavius and Euaesthetini were from the Eocene (Baltic amber) and discovery of O. electrospinosus sp. nov. therefore nearly doubles the minimum lineage age of Octavius, increasing it by 50 million years. We also briefly review the known Euaesthetine subgroup fossil record and tabulate summary data for all previously described fossils. All are placed in extant genera, and have visible diagnostic generic-level characters including some putative synapomorphies as judged by recent phylogenetic work. Including O. electrospinosus sp. nov., there are now four known Cretaceous species, all of which belong to either Octavius, Nordenskioldia, or Stenus. To explain the long-term morphological stasis in this group of rove beetles, we suggest that the continuous presence of mesic habitats may have buffered these lineages from strong selection for morphological change. Considering the fossils along with phylogenetic hypotheses we suggest the Euaesthetine subgroup originated in the Late Jurassic– Early Cretaceous and the Staphylinine group in the Early Jurassic. We emphasize the derived status of Cretaceous fossils in assessing possible divergence times and the significance of the pre-Cretaceous taphonomic bias for restricting more robust estimates. Further detailed morphological study of available fossils in a phylogenetic framework is badly needed to clarify the phylogenetic positions of these taxa.     

A depositional model for deep‐lacustrine,partially confined,turbidite fans: Early Cretaceous,North Falkland Basin

This paper presents a model of facies distribution within a set of early Cretaceous, deep‐lacustrine, partially confined turbidite fans (Sea Lion Fan, Sea Lion North Fan and Otter Fan) in the North Falkland Basin, South Atlantic. As a whole, ancient deep‐lacustrine turbidite systems are under‐represented in the literature when compared with those documented in marine basins. Lacustrine turbidite systems can form extensive, good quality hydrocarbon reservoirs, making the understanding of such systems crucial to exploration within lacustrine basins. An integrated analysis of seismic cross‐sections, seismic amplitude extraction maps and 455 m of core has enabled the identification of a series of turbidite fans. The deposits of these fans have been separated into lobe axis, lobe fringe and lobe distal fringe settings. Seismic architectures, observed in the seismic amplitude extraction maps, are interpreted to represent geologically associated heterogeneities, including: feeder systems, terminal mouth lobes, flow deflection, sinuous lobe axis deposits, flow constriction and stranded lobe fringe areas. When found in combination, these architectures suggest ‘partial confinement’ of a system, something that appears to be a key feature in the lacustrine turbidite setting of the North Falkland Basin. Partial confinement of a system occurs when depositionally generated topography controls the flow‐pathway and deposition of subsequent turbidite fan deposits. The term ‘partial confinement’ provides an expression for categorising a system whose depositional boundaries are unconfined by the margins of the basin, yet exhibit evidence of internal confinement, primarily controlled by depositional topography. Understanding the controls that dictate partial confinement; and the resultant distribution of sand‐prone facies within deep‐lacustrine turbidite fans, is important, particularly considering their recent rise as hydrocarbon reservoirs in rift and failed‐rift settings.     

Geochemical changes during neutralisation of acid mine drainage in a dynamic mountain stream, New Zealand

The Mangatini Stream drains a coal mining area in the mountains of northwestern South Island of New Zealand. Abundant rainfall on pyritic rocks yields acid mine drainage (AMD) to the stream, which flows through a steep gorge at discharges that rapidly increase from <1 to >100 m³/s during frequent rain events. The AMD is treated with finely ground limestone, which is discharged as a slurry at a point in the middle of the gorge. The limestone slurry mixes and reacts with the AMD during flow ∼4 km downstream over ∼12 h. Neutralisation reactions increase stream pH from near 3 (untreated Mangatini Stream water impacted by AMD) to 5–6 in the first 250 m downstream, although mixing is commonly incomplete in this zone. Large stream discharge volumes in rain events dilute the neutralising material input, thus driving the pH back towards 4 downstream of treatment. More complete neutralisation is achieved 4 km downstream, even in major rain events, and pH can rise to >7. Partial neutralisation is sufficient to remove most of the dissolved Fe(III) (typically ∼30 mg/L) from the Mangatini Stream in the first 10 m, and remaining dissolved Fe is essentially all Fe(II), which decreases over time as it oxidises and precipitates. Dissolved Al in the Mangatini Stream (typically ∼50 mg/L) decreases steadily downstream over ∼100 m in the limestone mixing zone. Precipitated Fe and Al form amorphous oxyhydroxides that are transported as suspended solids and deposited on the stream bed with excess limestone in zones of low flow velocity. Dissolved Zn is removed from solution by adsorption to Fe oxyhydroxide when pH reaches ∼5, but dissolved Ni remains in solution despite the neutralisation process. Gypsum precipitation occurs throughout the limestone mixing zone, resulting in at least 30% decrease in dissolved . Minor ettringite forms in the first 100 m, but then probably redissolves. The limestone dosing system is an effective method of neutralising the effects of AMD and removing most dissolved metals in a steep mountain stream with frequent rain events where this dynamic environment places many constraints on treatment options.     

Increasing the usability and accessibility of geodynamic modelling tools to the geoscience community: UnderworldGUI

Geoscientists are faced with a number of complexities that represent obstacles to the development of realistic simulation of deep earth processes. Realistic 4D thermo-mechanical simulation using software packages like Underworld and Gale, when combined appropriately with geoscientific expertise, can lead to novel insights into the deformation of geological structures at a wide range of time and spatial scales. The challenge for end-user geoscientists lies in applying their knowledge within the framework of the software’s input specification, including initial, internal, and boundary conditions and output visualization parameters. We have built a Graphical User Interface (GUI) to remove many of the difficulties related to editing the Extensible Markup Language (XML) encoded input files of Underworld/Gale geomodels and therefore, to greatly broaden the user base of these software packages. By helping Underworld/Gale to meet a large audience, we provide a tool to the geoscience community that helps to move from untested conceptual models to physically valid, properly scaled modelling. Furthermore, the UnderworldGUI offers a mechanism for storing and retrieving experimental models in a centralised database, thus providing the geoscience community with a means to share the outcomes of its experimental research. Further details of the UnderworldGUI are available at the web site .