Solar x-ray spectrometer (SOXS) mission – Low energy payload – First results

We present the first results from the ‘Low Energy Detector’ pay-load of ‘Solar X-ray Spectrometer (SOXS)’ mission, which was launched onboard GSAT-2 Indian spacecraft on 08 May 2003 by GSLV-D2 rocket to study the solar flares. The SOXS Low Energy Detector (SLD) payload was designed, developed and fabricated by Physical Research Laboratory (PRL) in collaboration with Space Application Centre (SAC), Ahmedabad and ISRO Satellite Centre (ISAC), Bangalore of the Indian Space Research Organization (ISRO). The SLD payload employs the state-of-the-art solid state detectors viz., Si PIN and Cadmium-Zinc-Telluride (CZT) devices that operate at near room temperature (-20°C). The dynamic energy range of Si PIN and CZT detectors are 4–25 keV and 4–56 keV respectively. The Si PIN provides sub-keV energy resolution while CZT reveals ∼1.7keV energy resolution throughout the dynamic range. The high sensitivity and sub-keV energy resolution of Si PIN detector allows the measuring of the intensity, peak energy and equivalent width of the Fe-line complex at approximately 6.7 keV as a function of time in all 8 M-class flares studied in this investigation. The peak energy (E _p) of Fe-line feature varies between 6.4 and 6.8 keV with increase in temperature from 9 to 34 MK. We found that the equivalent width (ω) of Fe-line feature increases exponentially with temperature up to 20 MK but later it increases very slowly up to 28 MK and then it remains uniform around 1.55 keV up to 34 MK. We compare our measurements ofw with calculations made earlier by various investigators and propose that these measurements may improve theoretical models. We interpret the variation of both E_pand ω with temperature as the changes in the ionization and recombination conditions in the plasma during the flare interval and as a consequence the contribution from different ionic emission lines also varies.     

Exposure of sticklebacks (Gasterosteus aculeatus) to cadmium sulfide nanoparticles: biological effects and the importance of experimental design.

Effects of nanoparticles on aquatic organisms have been little studied to date and toxicological data are urgently needed for development of regulatory frameworks for these substances. Here, we report the findings of a study exposing sticklebacks to cadmium sulfide (CdS) as bulk material and quantum dots. Fish were exposed for 21 d in a flow through test system to 5, 50 or 500 microg l(-1) CdS nanoparticles (nCdS) coated in thiol terminated methyl polyethylene glycol (MPEG), bulk CdS or MPEG at 500 microg l(-1) (nominal concentrations). With the exception of the highest nCdS exposure, measured concentrations were approximately one order of magnitude below nominal. A single fish from each group (excluding MPEG) was examined using energy dispersive X-ray analysis (EDX) to localise cadmium, however, cadmium could not be detected in whole body sections. Elevated levels of oxidized glutathione were measured in the gills of fish exposed to 50 and 500 microg l(-1) nCdS. Induction of vitellogenin synthesis was not detected in any of the treatment groups. The number of males engaged in nest-building behaviour following exposure to 500 microg l(-1) nCdS was reduced and livers of 4/6 fish in the same treatment displayed hepatocellular nuclear pleomorphism. The results are discussed emphasising the fundamental importance of experimental design and the need to understand the behaviour of nanoparticles in the aqueous phase.     

Internal catchment process simulation in a snow‐dominated basin: performance evaluation with spatiotemporally variable runoff generation and groundwater dynamics

Hydrologic models have increasingly been used in forest hydrology to overcome the limitations of paired watershed experiments, where vegetative recovery and natural variability obscure the inferences and conclusions that can be drawn from such studies. Models are also plagued by uncertainty, however, and parameter equifinality is a common concern. Physically‐based, spatially‐distributed hydrologic models must therefore be tested with high‐quality experimental data describing a multitude of concurrent internal catchment processes under a range of hydrologic regimes. This study takes a novel approach by not only examining the ability of a pre‐calibrated model to realistically simulate watershed outlet flows over a four year period, but a multitude of spatially‐extensive, internal catchment process observations not previously evaluated, including: continuous groundwater dynamics, instantaneous stream and road network flows, and accumulation and melt period spatial snow distributions. Many hydrologic model evaluations are only on the comparison of predicted and observed discharge at a catchment outlet and remain in the ‘infant stage’ in terms of model testing. This study, on the other hand, tests the internal spatial predictions of a distributed model with a range of field observations over a wide range of hydroclimatic conditions. Nash‐Sutcliffe model efficiency was improved over prior evaluations due to continuing efforts in improving the quality of meteorological data collection. Road and stream network flows were generally well simulated for a range of hydrologic conditions, and snowpack spatial distributions were well simulated for one of two years examined. The spatial variability of groundwater dynamics was effectively simulated, except at locations where strong stream–groundwater interactions exist. Model simulations overall were quite successful in realistically simulating the spatiotemporal variability of internal catchment processes in the watershed, but the premature onset of simulated snowmelt for one of the simulation years has prompted further work in model development. Copyright © 2011 John Wiley & Sons, Ltd.     

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation, and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka Marine Terrace Chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized [White A. F., Schulz M. S., Vivit D. V., Blum A., Stonestrom D. A. and Anderson S. P. (2008) Chemical weathering of a Marine Terrace Chronosequence, Santa Cruz, California. I: interpreting the long-term controls on chemical weathering based on spatial and temporal element and mineral distributions. Geochim. Cosmochim. Acta72 (1), 36-68] and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisserand [Hellmann R. and Tisserand D. (2006) Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar. Geochim. Cosmochim. Acta70 (2), 364-383] or the aluminum inhibition model proposed by Oelkers et al. [Oelkers E. H., Schott J. and Devidal J. L. (1994) The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim. Cosmochim. Acta58 (9), 2011-2024], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site.Additionally, observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO₂(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws.     

Entanglement of Australian sea lions and New Zealand fur seals in lost fishing gear and other marine debris before and after Government and industry attempts to reduce the problem

In recent years, Australian governments and fishing industry associations have developed guiding principles aimed at reducing the impact of fishing on non-target species and the benthos and increasing community awareness of their efforts. To determine whether they reduced seal entanglement in lost fishing gear and other marine debris, we analysed Australian sea lion and New Zealand fur seal entanglement data collected from Kangaroo Island, South Australia. Contrary to our expectations, we found that entanglement rates did not decrease in recent years. The Australian sea lion entanglement rate (1.3% in 2002) and the New Zealand fur seal entanglement rate (0.9% in 2002) are the third and fourth highest reported for any seal species. Australian sea lions were most frequently entangled in monofilament gillnet that most likely originated from the shark fishery, which operates in the region where sea lions forage--south and east of Kangaroo Island. In contrast, New Zealand fur seals were most commonly entangled in loops of packing tape and trawl net fragments suspected to be from regional rock lobster and trawl fisheries. Based on recent entanglement studies, we estimate that 1478 seals die from entanglement each year in Australia. We discuss remedies such as education programs and government incentives that may reduce entanglements.     

Opportunistic Feeding in Mediterranean Blennioid Fishes (Blenniidae and Tripterygion) as Revealed by Experimental Food Provisioning in the Field

Abstract. Consistent differences were found in trophic opportunism between species and between sexes by food provisioning experiments in an assemblage of 15 species of Mediterranean blennioid fishes. The degree of trophic opportunism in the different species was significantly and positively correlated with body size and two features indicative for intensity of male parental care. The degree of trophic opportunism correlated neither with trophic level, depth distribution, or relative abundance. Females of all species in which sex could be distinguished visited the feeding stations at higher frequencies than conspecific males.     

SPIRE point source photometry: within the Herschel interactive processing environment (HIPE)

The different algorithms appropriate for point source photometry on data from the SPIRE instrument on-board the Herschel Space Observatory, within the Herschel Interactive Processing Environment (HIPE) are compared. Point source photometry of a large ensemble of standard calibration stars and dark sky observations is carried out using the 4 major methods within HIPE: SUSSEXtractor, DAOphot, the SPIRE Timeline Fitter and simple Aperture Photometry. Colour corrections and effective beam areas as a function of the assumed source spectral index are also included to produce a large number of photometric measurements per individual target, in each of the 3 SPIRE bands (250, 350, 500μm), to examine both the accuracy and repeatability of each of the 4 algorithms. It is concluded that for flux densities down to the level of 30mJy that the SPIRE Timeline Fitter is the method of choice. However, at least in the 250 and 350μm bands, all 4 methods provide photometric repeatability better than a few percent down to at approximately 100mJy. The DAOphot method appears in many cases to have a systematic offset of ～8 % in all SPIRE bands which may be indicative of a sub-optimal aperture correction. In general, aperture photometry is the least reliable method, i.e. largest scatter between observations, especially in the longest wavelength band. At the faintest fluxes, <30mJy, SUSSEXtractor or DAOphot provide a better alternative to the Timeline Fitter.     

Effective precipitation in southern Spain ( 266 to 46 ka) based on a speleothem stable carbon isotope record

We present the longest-duration directly dated terrestrial palaeoclimate record from the western Mediterranean region: a flowstone speleothem from Gitana Cave, southeast Spain. The main phase of growth was 274 to 58 ka, dated by multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) U-series methods. Effective precipitation, which we consider primarily responsible for flowstone calcite δ¹³C variations, measured at 300 μm resolution, was higher during interglacials associated with marine oxygen isotope stages (MIS) 7 and 5, and lower during glacial MIS 6. There is a close correspondence between speleothem δ¹³C and sea surface temperature (SST) estimates from adjacent Atlantic Ocean cores during MIS 6, which implies that oceanic conditions are critical in controlling the western Mediterranean terrestrial moisture balance during glacial periods. Other features of our record, such as the sequence of termination II warming/moistening between approximately 133 and 127 ka, including a “pause” around 130–128 ka, and the lagged termination of MIS 5 warm intervals (5e, 5c and 5a) are similar to other terrestrial records within the Mediterranean basin, indicating climate synchroneity along the northern Mediterranean coast. The Gitana cave region also may have been a refugium for temperate species during short-lived cold/arid periods during MIS 5.     

Lithological controls on biological activity and groundwater chemistry in Quaternary sediments

Depth profiles of solute chemistry and sulfate isotopic compositions are presented for groundwater and pore water in a sequence of Quaternary glacial outwash sediments. Sand units show evidence for hydraulic connection to the surface and thus modern sources of solutes. Finer‐grained sediments show a general pattern of increasing solute concentrations with depth, with sulfate derived from ancient rainwater and pyrite oxidation in the soil/drift. In these sediments sulfate has undergone bacterial sulfate reduction (BSR) to produce biogenic sulfide. In clay sediments, with d₁₀ ≤ 1·6 µm, high concentrations of sulfate and acetate now co‐exist, implying that BSR is inhibited. The correlation with smaller sediment grain size indicates that this is due to pore size exclusion of the sulfate reducing bacteria. Mechanical restriction of microbial function thus provides a fundamental limitation on microbial respiration in buried clay‐rich sediments, which acts as a control on the chemical evolution of their pore waters. Copyright © 2009 John Wiley & Sons, Ltd.