Entanglement of Australian sea lions and New Zealand fur seals in lost fishing gear and other marine debris before and after Government and industry attempts to reduce the problem

In recent years, Australian governments and fishing industry associations have developed guiding principles aimed at reducing the impact of fishing on non-target species and the benthos and increasing community awareness of their efforts. To determine whether they reduced seal entanglement in lost fishing gear and other marine debris, we analysed Australian sea lion and New Zealand fur seal entanglement data collected from Kangaroo Island, South Australia. Contrary to our expectations, we found that entanglement rates did not decrease in recent years. The Australian sea lion entanglement rate (1.3% in 2002) and the New Zealand fur seal entanglement rate (0.9% in 2002) are the third and fourth highest reported for any seal species. Australian sea lions were most frequently entangled in monofilament gillnet that most likely originated from the shark fishery, which operates in the region where sea lions forage--south and east of Kangaroo Island. In contrast, New Zealand fur seals were most commonly entangled in loops of packing tape and trawl net fragments suspected to be from regional rock lobster and trawl fisheries. Based on recent entanglement studies, we estimate that 1478 seals die from entanglement each year in Australia. We discuss remedies such as education programs and government incentives that may reduce entanglements.     

Sustainable development in regional planning: The search for new tools and renewed legitimacy

This paper focuses on sustainability appraisal as a key technique for pursuing the political goal of ‘sustainable development’ within English planning. We conclude that unlike many planning tools of the past which have sought to depoliticise decision making by using more ‘scientific’ techniques, the early experience of sustainability appraisal has instead repoliticised them, by highlighting where tensions exist but without providing solutions.     

Compositional variability on the surface of 4 Vesta revealed through GRaND measurements of high‐energy gamma rays

Measurements of the high‐energy gamma‐ray flux emanating from asteroid 4 Vesta by the Dawn Gamma‐Ray and Neutron Detector (GRaND) have revealed variability in the near‐surface elemental composition of the Vestan surface. These observations are consistent with the presence of large (≥8 × 10⁴ km²) regions with distinct, HED‐like elemental compositions. The results agree broadly with other global measurements, such as the macroscopic neutron absorption cross section and spectral reflectance‐derived mineralogic maps. Two distinct regions with eucrite‐like elemental compositions have been identified, the first located primarily within the Lucaria and Marcia quadrangles and the second within Oppia quadrangle. The former region is collocated with some of the oldest, most heavily cratered terrain on Vesta. The interior of the 500 km diameter Rheasilvia impact basin is found to have a composition that is consistent with diogenite‐like material. Taken together, these observations support the hypothesis that Vesta's original crust was composed of basaltic outflows in the form of eucritic‐like material and that the Rheasilvia‐basin‐forming impact exposed lower‐crustal, diogenite‐like material. These measurements also constrain the maximum amount of mesosiderite‐like material to <10% for each 15 × 15° surface element.     

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation, and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka Marine Terrace Chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized [White A. F., Schulz M. S., Vivit D. V., Blum A., Stonestrom D. A. and Anderson S. P. (2008) Chemical weathering of a Marine Terrace Chronosequence, Santa Cruz, California. I: interpreting the long-term controls on chemical weathering based on spatial and temporal element and mineral distributions. Geochim. Cosmochim. Acta72 (1), 36-68] and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisserand [Hellmann R. and Tisserand D. (2006) Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar. Geochim. Cosmochim. Acta70 (2), 364-383] or the aluminum inhibition model proposed by Oelkers et al. [Oelkers E. H., Schott J. and Devidal J. L. (1994) The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim. Cosmochim. Acta58 (9), 2011-2024], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site.Additionally, observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO₂(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws.     

Evidence for high temperature and 18O‐enriched fluids in the Arab‐D of the Ghawar Field,Saudi Arabia

Using the clumped isotope method, the temperature of dolomite and calcite formation and the oxygen isotopic composition (δ¹⁸O_w) of the diagenetic fluids have been determined in a core taken from the Arab‐D of the Ghawar field, the largest oil reservoir in the world. These analyses show that while the dolomites and limestones throughout the major zones of the reservoir recrystallized at temperatures between ca 80°C and 100°C, the carbonates near the top of the reservoir formed at significantly lower temperatures (20 to 30°C). Although the δ¹⁸O values of the diagenetic fluids show large variations ranging from ca <0‰ to ca +8‰, the variations exhibit consistent downhole changes, with the highest values being associated with the portion of the reservoir with the highest permeability and porosity. Within the limestones, dolomites and dolomites associated with the zone of high permeability, there are statistically significant different trends between the δ¹⁸O_w values and recrystallization temperature. These relationships have different intercepts suggesting that fluids with varying δ¹⁸O_w values were involved in the formation of dolomite and limestone compared to the formation of dolomite associated with the zone of high permeability. These new data obtained using the clumped isotope technique show how dolomitization and recrystallization by deep‐seated brines with elevated δ¹⁸O_w values influence the δ¹⁸O values of carbonates, possibly leading to erroneous interpretations unless temperatures can be adequately constrained.     

Dynamic response characterization and simplified analysis methods for viscoelastic dampers considering heat transfer

Viscoelastic (VE) dampers are sensitive to temperature, excitation frequency, and strain level. As they dissipate the kinetic energy from earthquake or wind-induced structural vibrations, their temperature increases from the heat generated, consequently softening their VE materials and lowering their dynamic mechanical properties. Temperature increase can be significant for long-duration loading, but can be limited by heat conduction and convection which depend on damper configuration. The writers analytically explored such effect on the six different dampers by using their previously proposed three-dimensional finite-element analysis method. Results provided better understanding of how heat is generated within the VE material, conducted and stored in different damper parts, and dispersed to the surrounding air. These results also led to characterization of both local (e.g., temperatures, properties, and strain energy density) and global (e.g., hysteresis loops, and stiffness) behavior of VE dampers, and provided a framework for a new simplified one-dimensional (1D) modeling approach for time-history analysis. This new proposed 1D method greatly improves the computation time of the previously proposed long-duration method coupling fractional time-derivatives VE constitutive rule with 1D heat transfer analysis. Unlike the previous method, it idealizes uniform shear strain and VE material property distributions for computational efficiency, but still simulating non-uniform temperature distribution along the thickness direction of the VE material. Despite the approximations, it accurately predicts VE damper global responses.