Using solver to determine vertical groundwater velocities by temperature variations, Purdue University, Indiana, USA

Vertical groundwater velocities can be estimated based on directions of groundwater thermal gradients. Temperature-depth profiles were obtained from 12 monitoring wells at 3 different times of the year (Fall, Winter, and Spring) in West Lafayette, Indiana (USA) mainly on the Purdue University campus. Microsoft Excel Solver was used to match plots of groundwater temperature distribution in the wells with published type curves in order to find a dimensionless parameter β, from which vertical groundwater velocities were obtained. The vertical groundwater velocities found in the monitoring wells ranged from 0.92 to 4.53 cm/yr. Clay-rich aquitards presented greater vertical groundwater velocities than outwash aquifers. The highest groundwater velocities occurred in the Spring while the lowest were during the Winter. This method was found to be especially useful in glacially-derived materials with varying hydraulic conductivities for estimating vertical groundwater velocities in-situ.     

Fluorite solubility equilibria in selected geothermal waters

Calculation of chemical equilibria in 351 hot springs and surface waters from selected geothermal areas in the western United States indicate that the solubility of the mineral fluorite, CaF₂, provides an equilibrium control on dissolved fluoride activity. Waters that are undersaturated have undergone dilution by non-thermal waters as shown by decreased conductivity and temperature values, and only 2% of the samples are supersaturated by more than the expected error. Calculations also demonstrate that simultaneous chemical equilibria between the thermal waters and calcite as well as fluorite minerals exist under a variety of conditions.Testing for fluorite solubility required a critical review of the thermodynamic data for fluorite. By applying multiple regression of a mathematical model to selected published data we have obtained revised estimates of the pK (10,96), ΔG^o_f (?280.08 kcal/mole), ΔH^o_f (?292.59 kcal/mole), S° (16.39 cal/deg/mole) and C^o_P (16.16 cal/deg/mole) for CaF₂ at 25°C and 1 atm. Association constants and reaction enthalpies for fluoride complexes with boron, calcium and iron are included in this review. The excellent agreement between the computer-based activity products and the revised pK suggests that the chemistry of geothermal waters may also be a guide to evaluating mineral solubility data where major discrepancies are evident.     

Machine learning classifiers for attributing tephra to source volcanoes: an evaluation of methods for Alaska tephras

Glass composition-based correlations of volcanic ash (tephra) traditionally rely on extensive manual plotting. Many previous statistical methods for testing correlations are limited by using geochemical means, masking diagnostic variability. We suggest that machine learning classifiers can expedite correlation, quickly narrowing the list of likely candidates using well-trained models. Eruptives from Alaska's Aleutian Arc-Alaska Peninsula and Wrangell volcanic field were used as a test environment for 11 supervised classification algorithms, trained on nearly 2000 electron probe microanalysis measurements of glass major oxides, representing 10 volcanic sources. Artificial neural networks and random forests were consistently among the top-performing learners (accuracy and kappa > 0.96). Their combination as an average ensemble effectively improves their performance. Using this combined model on tephras from Eklutna Lake, south-central Alaska, showed that predictions match traditional methods and can speed correlation. Although classifiers are useful tools, they should aid expert analysis, not replace it. The Eklutna Lake tephras are mostly from Redoubt Volcano. Besides tephras from known Holocene-active sources, Holocene tephra geochemically consistent with Pleistocene Emmons Lake Volcanic Center (Dawson tephra), but from a yet unknown source, is evident. These tephras are mostly anchored by a highly resolved varved chronology and represent new important regional stratigraphic markers.     

Phosphorus Availability and Salinity Control Productivity and Demography of the Seagrass <Emphasis Type="Italic">Thalassia testudinum</Emphasis> in Florida Bay

Biomass, net primary productivity (NPP), foliar elemental content, and demography of Thalassia testudinum were monitored in populations from five sites across Florida Bay beginning in January 2001. Sites were selected to take advantage of the spatial variability in phosphorus (P) availability and salinity climates across the bay. Aboveground biomass and NPP of T. testudinum were determined five to six times annually. Short-shoot demography, belowground biomass, and belowground NPP were assessed from a single destructive harvest at each site and short-shoot cohorts were estimated from leaf scar counts multiplied by site-specific leaf production rates. Biomass, relative growth rate (RGR), and overall NPP were positively correlated with P availability. Additionally, a positive correlation between P availability and the ratio of photosynthetic to non-photosynthetic biomass suggests that T. testudinum increases allocation to aboveground biomass as P availability increases. Population turnover increased with P availability, evident in positive correlations of recruitment and mortality rates with P availability. Departures from seasonally modeled estimates of RGR were found to be influenced by salinity, which depressed RGR when below 20 psu or above 40 psu. Freshwater management in the headwaters of Florida Bay will alter salinity and nutrient climates. It is becoming clear that such changes will affect T. testudinum, with likely feedbacks on ecosystem structure, function, and habitat quality.     

Constrains on gravity wave induced diffusion in the middle atmosphere

A review of the important constraints on gravity wave induced diffusion of chemical tracers, heat, and momentum is given. Ground-based microwave spectroscopy measurements of H₂O and CO and rocket-based mass spectrometer measurements of Ar constrain the eddy diffusion coefficient for constituent transport (K _zz ) to be (1–3)×10⁵ cm²s^–1 in the upper mesosphere. Atomic oxygen data also limitsK _zz to a comparable value at the mesopause. From the energy balance of the upper mesosphere the eddy diffusion coefficient for heat transport (D _H ) is, at most 6×10⁵ cm²s^–1 at the mesopause and decreasing substantially with decreasing altitude. The available evidence for mean wind deceleration and the corresponding eddy diffusion coefficient for momentum stresses (D _M ) suggests that it is at least 1×10⁶ cm²s^–1, in the upper mesosphere. Consequently the eddy Prandtl number for macroscopic scale lengths is >3.     

Molecular hydrogen in Titan’s atmosphere: Implications of the measured tropospheric and thermospheric mole fractions

The third most abundant species in Titan’s atmosphere is molecular hydrogen with a tropospheric/lower stratospheric mole fraction of 0.001 derived from Voyager and Cassini infrared measurements. The globally averaged thermospheric H₂ mole fraction profile from the Cassini Ion Neutral Mass Spectrometer (INMS) measurements implies a small positive gradient in the H₂ mixing ratio from the tropopause region to the lower thermosphere (∼950-1000 km), which drives a downward H₂ flux into Titan’s surface comparable to the H₂ escape flux out of the atmosphere (∼2 × 10¹⁰ cm⁻² s⁻¹ referenced to the surface) and requires larger photochemical production rates of H₂ than obtained by previous photochemical models. From detailed model calculations based on known photochemistry with eddy, molecular, and thermal diffusion, the tropospheric and thermospheric H₂ mole fractions are incompatible by a factor of ∼2. The measurements imply that the downward H₂ surface flux is in substantial excess of the speculative threshold value for methanogenic life consumption of H₂ (McKay, C.P., Smith, H.D. [2005], Icarus 178, 274-276. doi:10.1016/j.icarus.2005.05.018), but without the extreme reduction in the surface H₂ mixing ratio.     

Near-shore swell estimation from a global wind-wave model: Spectral process,linear, and artificial neural network models

Estimation of swell conditions in coastal regions is important for a variety of public, government, and research applications. Driving a model of the near-shore wave transformation from an offshore global swell model such as NOAA WaveWatch3 is an economical means to arrive at swell size estimates at particular locations of interest. Recently, some work (e.g. Browne et al. [Browne, M., Strauss, D., Castelle, B., Blumenstein, M., Tomlinson, R., 2006. Local swell estimation and prediction from a global wind-wave model. IEEE Geoscience and Remote Sensing Letters 3 (4), 462–466.]) has examined an artificial neural network (ANN) based, empirical approach to wave estimation. Here, we provide a comprehensive evaluation of two data driven approaches to estimating waves near-shore (linear and ANN), and also contrast these with a more traditional spectral wave simulation model (SWAN). Performance was assessed on data gathered from a total of 17 near-shore locations, with heterogenous geography and bathymetry, around the continent of Australia over a 7 month period. It was found that the ANNs out-performed SWAN and the non-linear architecture consistently out-performed the linear method. Variability in performance and differential performance with regard to geographical location could largely be explained in terms of the underlying complexity of the local wave transformation.     

Dynamics of a wave-dominated tidal inlet and influence on adjacent beaches,Currumbin Creek,Gold Coast,Australia

Currumbin Creek on the Australian Gold Coast is a wave-dominated tidal inlet which exhibits a particularly active morphology. The recent history of Currumbin Creek entrance has seen rapid growth of the entrance for access to the ocean by fishermen, as a world class surfing site, and as a recreational area. Before the construction of two groynes in the 70's, Currumbin Creek entrance was highly variable in terms of inlet location and sand bar characteristics due to a cyclical behaviour of spit migration. Nowadays, the entrance is stabilised. However, natural processes continue with the entrance infilling causing flood and navigation issues, resulting in a regular dredging program to maintain an open entrance and for regular beach nourishment plans.     

On the maintenance of thermal wind balance and equatorial superrotation in Titan's stratosphere

Titan's atmospheric winds, like those on Venus, exhibit superrotation at high altitudes. Titan general circulation models have yielded conflicting results on whether prograde winds in excess of 100 m s⁻¹ at the 1 mbar level are possible based on known physical processes that drive wind systems. A comprehensive two-dimensional (2D) model for Titan's stratosphere was constructed to systematically explore the physical mechanisms that produce and maintain stratospheric wind systems. To ensure conservation of angular momentum in the limit of no net exchange of atmospheric angular momentum with the solid satellite and no external sources and sinks, the zonal momentum equation was solved in flux form for total angular momentum. The relationships among thermal wind balance, meridional circulation, and zonal wind were examined with numerical experiments over a range of values for fundamental input parameters, including planetary rotation rate, radius, internal friction due to wave stresses, and net radiative drive. The magnitude of mid-latitude jets is most sensitive to a single parameter, the planetary rotation rate and results from the conversion of planetary angular momentum to relative angular momentum by the meridional circulation, whereas the strength of meridional circulation is mainly determined by the magnitude of the radiative drive. For Titan's slowly rotating atmosphere, the meridional temperature gradient is vanishingly small, even when the radiative drive is enhanced beyond reasonable magnitudes, and can be inferred from zonal winds in gradient/thermal wind balance. In our 2D model large equatorial superrotation in Titan's stratosphere can be only produced through internal drag forcing by eddy momentum fluxes, which redistribute angular momentum within the atmosphere, while still conserving the total angular momentum of the atmosphere with time. We cannot identify any waves, such as gravitational or thermal tides, that are sufficiently capable of generating the required eddy forcing of >50 m s⁻¹ Titan-day⁻¹ to maintain peak prograde winds in excess of 100 m s⁻¹ at the 1 mbar level.