Channel processes as a factor controlling accumulation of heavy metals in river bottom sediments: consequences for pollution monitoring (Upper Silesia, Poland)

 An evaluation of the influence of channel processes (erosion, accumulation, processing of channel sediments) on the dispersal of heavy metals in bottom sediments was carried out in the channels of the Sztoła and Biała Przemsza rivers in Upper Silesia, Poland. These rivers receive waters from a Zn and Pb mine. Mine waters transport a large amount of fine-grained sediments contaminated with heavy metals. The polluted material is accumulated in these stream courses and mixed with nearly homogeneous sandy sediment derived from erosion of the river banks and bed. Because these alluvia are easily set in motion, the distribution of heavy metal concentration in the channel in fraction <1 mm reflects differences in physical processes of sedimentation in its cross-section. The minimal values in active channel and maximal in the near-bank zone are typical for those channel sections where heavy metals, present in a solid state, are transported as a suspended load (normally the largest part of a polluted river course). In short sections heavy metals associated with the grains of a large mass which has accumulated in the active channel are transported as a bed load and the typical distribution pattern is reversed (in fractions both <1 mm and <0.063 mm). Such regularities can be disturbed in localities where strong, turbulent flow or frequent eddying occur and Mn oxides and hydrooxides and associated elements precipitate. The smallest variation in heavy metal concentration in the homogenous, fine-grained bank sediments which are trapped by plants below water level is a feature which recommends these localities as being the most suitable for monitoring of river pollution. Received: 11 November 1997 · Accepted: 12 March 1998     

Analysis of floodplain inundation using 2D nonlinear diffusive wave equation solved with splitting technique

In the paper a solution of two-dimensional (2D) nonlinear diffusive wave equation in a partially dry and wet domain is considered. The splitting technique which allows to reduce 2D problem into the sequence of one-dimensional (1D) problems is applied. The obtained 1D equations with regard to x and y are spatially discretized using the modified finite element method with the linear shape functions. The applied modification referring to the procedure of spatial integration leads to a more general algorithm involving a weighting parameter. Time integration is carried out using a two-level difference scheme with the weighting parameter as well. The resulting tri-diagonal systems of nonlinear algebraic equations are solved using the Picard iterative method. For particular sets of the weighting parameters, the proposed method takes the form of a standard finite element method and various schemes of the finite difference method. On the other hand, for the linear version of the governing equation, the proper values of the weighting parameters ensure an approximation of 3rd order. Since the diffusive wave equation can be solved no matter whether the area is dry or wet, the numerical computations can be carried out over entire domain of solution without distinguishing a current position of the shoreline which is obtained as a result of solution.     

Advances in understanding calcite varve formation: new insights from a dual lake monitoring approach in the southern Baltic lowlands

We revise the conceptual model of calcite varves and present, for the first time, a dual lake monitoring study in two alkaline lakes providing new insights into the seasonal sedimentation processes forming these varves. The study lakes, Tiefer See in NE Germany and Czechowskie in N Poland, have distinct morphology and bathymetry, and therefore, they are ideal to decipher local effects on seasonal deposition. The monitoring setup in both lakes is largely identical and includes instrumental observation of (i) meteorological parameters, (ii) chemical profiling of the lake water column including water sampling, and (iii) sediment trapping at both bi-weekly and monthly intervals. We then compare our monitoring data with varve micro-facies in the sediment record. One main finding is that calcite varves form complex laminae triplets rather than simple couplets as commonly thought. Sedimentation of varve sub-layers in both lakes is largely dependent on the lake mixing dynamics and results from the same seasonality, commencing with diatom blooms in spring turning into a pulse of calcite precipitation in summer and terminating with a re-suspension layer in autumn and winter, composed of calcite patches, plant fragments and benthic diatoms. Despite the common seasonal cycle, the share of each of these depositional phases in the total annual sediment yield is different between the lakes. In Lake Tiefer See calcite sedimentation has the highest yields, whereas in Lake Czechowskie, the so far underestimated re-suspension sub-layer dominates the sediment accumulation. Even in undisturbed varved sediments, re-suspended material becomes integrated in the sediment fabric and makes up an important share of calcite varves. Thus, while the biogeochemical lake cycle defines the varves’ autochthonous components and micro-facies, the physical setting plays an important role in determining the varve sub-layers’ proportion.     

Storage of sediment‐associated heavy metals along the channelized Odra River,Poland

The importance of long‐term storage of heavy metals in groyne fields, functioning over 150 years, is investigated for the River Odra (Oder), western Poland. Construction of groynes along the Odra preceded rapid development of heavy industrialization in the largest coal mine districts in Poland and the Czech Republic that resulted in persistent riverine pollution. The 187 km long Middle Odra reach was repeatedly channelized from the first half of the eighteenth century to the turn of the twentieth century, during which time partially filled groyne fields were dissected by new bank lines and groyne systems, with older groyne fields partially keyed into the floodplain. Consequently, concentrations of zinc, lead, cadmium, and copper within historically deposited groyne field sediments exceed local geochemical background levels by more than 60, 40, 15 and 10 times, respectively. Sediments contaminated with heavy metals occur within three distinctive geomorphic zones: zone I is up to 250 m wide and furthest from the present channel, comprising decimeter‐thick polluted sediments, overlying eighteenth century sand and gravel bars; zone II represents the former nineteenth century groyne fields, with widths between 10 and 100 m, filled with as much as 3 m of polluted sediments; zone III represents the twentieth century groyne fields, which are several to a dozen metres wide and filled with polluted sediments averaging depths of more than 2 m. This investigation indicates that large and extensive sediment quantities of moderately polluted sediments are stored immediately along the banks of the River Odra. These sediments could be a significant secondary pollution source and therefore careful maintenance of contemporary bank protection structures is required. Copyright © 2009 John Wiley & Sons, Ltd.     

SH waves in a layer with temperature dependent properties

The paper deals with the problem of SH harmonic wave propagation in an elastic layer with temperature dependent properties. The shear modulus and mass density are linearly dependent on temperature. The layer is rested on a rigid foundation and the upper boundary is free of loadings. The boundary planes are kept at different constant temperatures. The wave velocity and amplitude of stresses are analysed.     

Application of Ground Penetrating Radar Surveys and GPS Surveys for Monitoring the Condition of Levees and Dykes

This paper analyses the possibility of using integrated GPS (Global Positioning System) surveys and ground penetrating radar surveys to precisely locate damages to levees, particularly due to the activity of small fossorial mammals. The technology of intercommunication between ground penetrating radar (GPR) and an RTK (Real-Time Kinematic) survey unit, and the method of data combination, are presented. The errors which may appear during the survey work are also characterized. The procedure for processing the data so that the final results have a spatial character and are ready to be implemented in digital maps and geographic information systems (GIS) is also described.     

The Chemical Diversity of Comets: Synergies Between Space Exploration and Ground-based Radio Observations

A fundamental question in cometary science is whether the different dynamical classes of comets have different chemical compositions, which would reflect different initial conditions. From the ground or Earth orbit, radio and infrared spectroscopic observations of a now significant sample of comets indeed reveal deep differences in the relative abundances of cometary ices. However, no obvious correlation with dynamical classes is found. Further results come, or are expected, from space exploration. Such investigations, by nature limited to a small number of objects, are unfortunately focussed on short-period comets (mainly Jupiter-family). But these in situ studies provide “ground truth” for remote sensing. We discuss the chemical differences in comets from our database of spectroscopic radio observations, which has been recently enriched by several Jupiter-family and Halley-type comets.     

The 1995–2002 Long-Term Monitoring of Comet C/1995 O1 (HALE–BOPP) at Radio Wavelength

The bright comet Hale–Bopp provided the first opportunity to follow the outgassing rates of a number of molecular species over a large range of heliocentric distances. We present the results of our observing campaign at radio wavelengths which began in August 1995 and ended in January 2002. The observations were carried out with the telescopes of Nançay, IRAM, JCMT, CSO and, since September 1997, SEST. The lines of nine molecules (OH, CO, HCN, CH₃OH, H₂CO, H₂S, CS, CH₃CN and HNC) were monitored. CS, H₂S, H₂CO, CH₃CN were detected up to r_h= 3–4 AU from the Sun, while HCN and CH₃OH were detected up to 6 AU. CO, which is the main driver of cometary activity at heliocentric distances larger than 3–4 AU, was last detected in August 2001, at r_h= 14 AU. The gas production rates obtained from this programme contain important information on the nature of cometary ices, their thermal properties and sublimation mechanisms.Line shapes allow to measure gas expansion velocities, which, at large heliocentric distances, might be directly connected to the temperature of the nucleus surface. Inferred expansion velocity of the gas varied as r_h ^-0.4 within 7 AU from the Sun, but remained close to 0.4 km s^-1 further away. The CO spectra obtained at large r_hare strongly blueshifted and indicative of an important day-to-night asymmetry in outgassing and expansion velocity. The kinetic temperature of the coma, estimated from the relative intensities of the CH₃OH and CO lines, increased with decreasing r_h, from about 10 K at 7 AU to 110 K around perihelion.