综合利用对虾扇贝育苗池常温育裙带菜苗试验

本试验是利用对虾(扇贝)育苗池进行室内常温培育裙带菜苗。试验证明,育苗数量完全可以达到生产上的要求,这样既可充分提高对虾(扇贝)育苗池的利用率,又可解决裙带菜苗源不足的问题,促进裙带菜养殖事业的发展。     

Position-domain integrity risk-based ambiguity validation for the integer bootstrap estimator

Integrity monitoring for ambiguity resolution is of significance for utilizing the high-precision carrier phase differential positioning for safety–critical navigational applications. The integer bootstrap estimator can provide an analytical probability density function, which enables the precise evaluation of the integrity risk for ambiguity validation. In order to monitor the effect of unknown ambiguity bias on the integer bootstrap estimator, the position-domain integrity risk of the integer bootstrapped baseline is evaluated under the complete failure modes by using the worst-case protection principle. Furthermore, a partial ambiguity resolution method is developed in order to satisfy the predefined integrity risk requirement. Static and kinematic experiments are carried out to test the proposed method by comparing with the traditional ratio test method and the protection level-based method. The static experimental result has shown that the proposed method can achieve a significant global availability improvement by 51% at most. The kinematic result reveals that the proposed method obtains the best balance between the positioning accuracy and the continuity performance.     

地震信息对薄砂岩储层特性的描述

近年来,以地震信息为主进行油气藏描述,这是当前对石油勘探的重点攻关课题.本文结合我国陆上和海域部分油田或含油气构造的实际资料,运用地震信息为主,结合测井、地质及钻井等资料,对储层进行综合解释。同时,提出了用多地震信息计算薄层厚度的基本公式,根据地区性岩性和地震资料的差异,使用了确定性地质统计和Coringing分析两种方法进行储层物性参数的预测,文中给出大量的实例说明各种储层参数描述方法和应用效果。     

Research on Autonomous Orbit Determination of Navigation Satellite Based on Crosslink Range and Orientation Parameters Constraining

Introduction Thepotentialvulnerabilityofsatellitenaviga tionsystemthatreliesongroundstationsisthat thesystemwouldbreakdownifgroundstations weredestroyed,whichcannotmeettherequire mentofnavigationwarfare[1].Withthedevelop mentofsuchspace basedsystemsasgrou…     

华南加里东期金矿床的基本特征

文章分析了安徽月山矿田夕卡岩型矿床形成过程中水岩作用的类型和特征。估算和讨论了水岩作用过程中的质量－体积变化和动力学问题。结论认为：水岩作用对流体成矿系统中夕卡岩和蚀变矿化作用的发生、发展，成矿流体的形成，成矿物质的富集，矿床定位等具有重要意义；水岩作用的水岩比值（W／R）小于0．1；夕卡岩和矿化蚀变分带是开放体系一系列溶解沉淀波反应前锋发生水岩反应后矿物和元素组合的时空分离的结果。     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

珠江口盆地流花碳酸盐台地灰岩坑的地震反射特征及成因探讨

早中新世东沙隆起带上发育了大规模的流花碳酸盐台地,上覆巨厚未固结-弱固结泥岩。基于三维地震数据,利用相干体及可视化等方法,在台地上发现了由溶蚀垮塌作用形成的数量众多的椭圆形的灰岩坑。灰岩坑直径一般为200~700 m,最大超过900 m,深度10~90 m;灰岩坑在地震反射上表现为碳酸盐岩顶部垮塌,并导致上覆泥岩地层塌陷;灰岩坑一般沿NWW向断层分布,这些NWW向断层切割中新世碳酸盐岩和上覆海相泥岩地层,绝大多数终止于T₁₀的不整合面。综合分析东沙海区构造和沉积过程认为：发生在晚中新世末期的东沙运动形成了NWW向张扭性断层,为酸性流体提供了运移通道和物质交换场所;东沙运动伴生的基底岩浆活动可能产生了酸性热液流体;东沙运动末期发生强烈的构造抬升和大规模海底暴露,造成地表水沿断层注入,加快了碳酸盐岩的溶蚀速率。在台地底部珠海组砂岩层的高压流体、地表水和岩浆活动可能产生的酸性热液流体的共同溶蚀作用下,碳酸盐岩地层内部产生溶洞,并且越来越大,最终顶部无法承载上覆巨厚泥岩而发生垮塌,形成灰岩坑。流花碳酸盐台地灰岩坑的形成不是简单的暴露溶蚀,而是构造活动影响下深埋藏溶蚀作用的产物。     

丝绸之路沿线的兰州城市空间演变及其影响因素

丝绸之路沿线的城市是丝绸之路文明演变的聚焦和投影, 研究历史时期丝绸之路沿线城市空间演变及影响因素是理解丝绸之路沿线城市发展的有效视角, 对解释丝绸之路沿线人地关系规律具有科学意义。本研究以兰州市作为丝绸之路沿线典型城市, 以历史文献资料为基础, 结合空间分析技术对历史时期兰州城市空间演变及其影响因素进行分析, 得出以下结论: 丝绸之路的兴衰与兰州城市空间演变的扩张呈现正相关性, 兰州的行政建制始于秦始皇三十三年(214 BC), 隋文帝开皇元年(581 A.D.)"兰州"首次见于诸史册, 兰州城市空间由隋唐时期(907 A.D.)的0.40 km2增加到2015年的132.67 km2。历史时期兰州城市空间演变包括4个主要阶段: 城市萌芽期的"缓慢发展", 军事职能主导下的"约束性"扩张, 王朝兴盛所带动的"年轮式"增长, 国家政策推动的"跨越式"扩展。影响兰州城市空间演化的因素涵盖丝绸之路兴衰、军事政治、交通贸易及自然环境等, 各种影响因素共同驱动着兰州城市由早期的黄河渡口、军事据点向西北地区政治、经济、文化、交通中心演变。     

Contents To Volume 88

Volume Contents

Contents To Volume 88     

改进的无网格法及其在冻土区桩基温度场中的应用

采用带权正交基函数对传统的无网格法中的基函数进行了改进,避免了计算过程中可能出现的矩阵不可逆情况,而且编程容易实现且计算效率高。并将其应用到冻土区桩基包括了热传导和相变潜热的温度场中,同时考虑了混凝土水化热释放对桩周冻土的影响,将计算结果和有限元计算结果及现场实测数据进行了比较分析,从趋势和最大数值看都反映了实测曲线的趋势,又把不同深度处桩侧和不同桩径处温度随时间的变化规律计算结果和有限元计算结果做了对比,都验证了该方法的可行性和优越性。