秋末寒潮大风作用下南黄海西部流场及温、盐度变动特征分析

1983年11月中美首次在南黄海西部开展水文和地质联合调查,该调查共设5个浮标站和54个CTD站,其中CTD站所获的温、盐度和溶解氧、透光度资料早已有过一些报道,并获得了一些有益的结论(丁宗信等,1986;熊庆成等,1986;赵保仁等,1986)。但对这次调查所取得的浮标测流资料尚未有人进行认真的分析研究,也未曾报道过。这次测流还是比较成功的,所揭示的现象使人感到振奋,而且这也是迄今在南黄海西部使用浮标最多、时间最长的一次浮标阵测流工作。 本文试图结合1983年11月调查时的海上风速和沿岸水位变化进行综合分析,并对那里的环流状态提出一些初步看法,以利于对南黄海西部水域的海流变动特征和生成机制进行更深入的研究。     

LA‐ICP‐MS Analysis of Small Samples: Carbonate Reference Materials and Larval Fish Otoliths

This article proposes a methodology to analyse the composition of very small carbonate samples such as larval fish otoliths. The chemical composition of otoliths, which are carbonate structures in the inner ear, is often used to explore population dynamics in fishes. Recent advances in laser ablation‐inductively coupled plasma‐mass spectrometry have suggested its potential application to this field. In this study, analyses were performed using a 193 nm ArF Resonetics LA system, coupled to an Agilent 7700X‐ICP‐MS, with the following ablation parameters: a beam diameter of 5 μm, energy of 3 mJ, 2.7 J cm^?2, laser repetition rate of 10 Hz and translation speed of 2.5 μm s^?1. NIST SRM 610 glass was used as the primary calibration material. Performing this protocol, characterisation of a USGS GP‐4 reference material was achieved with suitable precision and accuracy, but the USGS MACS‐3 reference material appeared more heterogeneous under the ablation conditions tested. Calibration was performed using two different beam diameters (5 and 11 μm). Capelin (Mallotus villosus) otoliths measuring between 10 and 20 μm in diameter were tested. Even though a smaller beam diameter and lower energy were used compared with those normally employed to analyse larger otoliths, the method was successful.     

Detection of petroleum contamination in river sediments from Quebec City region using GC–IRMS

Isotopic analysis by compound specific gas chromatography–isotope ratio mass spectrometry (GC–IRMS) is used to detect and characterize petroleum pollution in surficial sediments along the St Lawrence River, near Quebec City. Unusually mature n-alkane distributions have been found in some recent intertidal sediments in the region. GC–IRMS results suggest that the n-alkanes are not derived from indigenous organic sources because they carry δ¹³C values between −30.0 and −27.0‰, as well as very small isotopic differences between odd and even numbered n-alkanes, which are both typically associated with petroleum products. Comparison of these sediments with bunker fuel, an oil used in the shipping industry, has shown a close isotopic correlation in some sites, which is further supported by biomarkers. Overall, the contamination has been dispersed along the river but is generally localized around the industrial region where hydrocarbon transfer from shore storage to ships takes place. This study illustrates how GC–IRMS can be used effectively in the detection and characterization of petroleum pollutants in sediments.     

Jurassic Amber in Lebanon

<正>Reports of amber predating the Lower Cretaceous are unusual and scarce;they mostly refer to amber pieces of millimetric dimension.In the present study,we report the discovery of 10 new outcrops of Jurassic amber in Lebanon.Some of these had large centimetric-sized pieces of amber.The new localities are described,amber is characterized,and its infrared spectra given.Although the new Jurassic amber yielded to date no more than fungal inclusions,this material is significant and promising.The discovery of several Jurassic outcrops provides crucial information on the prevailing paleoenvironment of that time.     

A distribution function based bandwidth selection method for kernel quantile estimation

The key problem in nonparametric frequency analysis of flood and droughts is the estimation of the bandwidth parameter which defines the degree of smoothing. Most of the proposed bandwidth estimators have been based on the density function rather than the cumulative distribution function or the quantile that are the primary interest in frequency analysis. We propose a new bandwidth estimator derived from properties of quantile estimators. The estimator builds on work by Altman and Léger (1995). The estimator is compared to the well-known method of least squares cross-validation (LSCV) using synthetic data generated from various parametric distributions used in hydrologic frequency analysis. Simulations suggest that our estimator performs at least as well as, and in many cases better than, the method of LSCV. In particular, the use of the proposed plug-in estimator reduces bias in the estimation as compared to LSCV. When applied to data sets containing observations with identical values, typically the result of rounding or truncation, the LSCV and most other techniques generally underestimates the bandwidth. The proposed technique performs very well in such situations.     

Fractionation change of hydrogen isotopes in trees due to atmospheric pollutants

Atmospheric pollution effects on hydrogen fractionation in trees are demonstrated for the first time in this study. The δ²H ring-cellulose series obtained for black spruce trees at a site near a SO₂-emitting smelter display short-term fluctuations superimposed on a first order −11‰ shift coincident with the onset of smelter operations. The isotopic depletion in trees exposed to various levels of SO₂ diminish with increasing distance relative to the location of the smelter, and it is not detected at the most distant selected stand, 116 km downwind from the point source. Both the spatial and temporal isotopic trends likely result from the combined effects of leaf transpiration, biochemical processes and water uptake by the root system. The spatial and temporal trends of δ²H values are the reverse of the δ¹³C trends previously obtained for the same tree ring series. These coupled isotopic fractionations underline an important response of trees to pollution stresses likely generated by ambient atmospheric SO₂ concentrations. The degradation of global air quality during the last 150 yr likely generated large scale modifications in the way terrestrial vegetation grows. In this respect, hydrogen dendrogeochemistry combined with other tracers such as C isotope ratios constitutes a new tool to evaluate the past behavior of forest ecosystems in terms of C uptake and acclimation to various types of atmospheric pollution.     

Total Sulfur Concentration in Geological Reference Materials by Elemental Infrared Analyser

Total sulfur is an analyte for which there are few determinations published, despite the fact that it is a very important element (e.g., a major element in most ores, an important gas constituent in global warming, an active participant in acid drainage). Most geological reference materials have very poor quality sulfur results, that is with relative standard deviations (RSD) in the range of 30–50%, even for concentrations over 100 μg g⁻¹ S, which compromises their use as calibrators. In order to provide modern results with low RSD, sulfur was determined in twenty-nine geological reference materials with a state-of-the-art elemental S/C analyser using metal chips (certified reference materials with a traceability link) and analytical grade sulfur for high concentration samples. Analytical parameters (sample mass, crucible degassing, calibration strategy, etc.) were optimised by testing. Our results agreed with reference material values provided by issuing bodies. Results for CCRMP SY-2 (129 ± 13 μg g⁻¹ S), which has been proposed as a sulfur reference material, were in agreement with the proposed modern value of 122 ± 3.7 μg g⁻¹ S.     

Cooling of Accretion-Heated Neutron Stars

We present a brief, observational review about the study of the cooling behaviour of accretion-heated neutron stars and the inferences about the neutron-star crust and core that have been obtained from these studies. Accretion of matter during outbursts can heat the crust out of thermal equilibrium with the core and after the accretion episodes are over, the crust will cool down until crust-core equilibrium is restored. We discuss the observed properties of the crust cooling sources and what has been learned about the physics of neutron-star crusts. We also briefly discuss those systems that have been observed long after their outbursts were over, i.e, during times when the crust and core are expected to be in thermal equilibrium. The surface temperature is then a direct probe for the core temperature. By comparing the expected temperatures based on estimates of the accretion history of the targets with the observed ones, the physics of neutron-star cores can be investigated. Finally, we discuss similar studies performed for strongly magnetized neutron stars in which the magnetic field might play an important role in the heating and cooling of the neutron stars.     

Palynological Analysis of Amber-Bearing Clay from the Lower Cretaceous of Central Lebanon

An amber-bearing lignitic layer of sandy clay from the Lower Cretaceous of Central Lebanon (Mderej-Hammana)yielded a well-preserved,moderately variegated palynoflora,which origin is mixed between land plants and marine microflora.Its detailed analysis led to fulfill its inventory,to propose a paleoenvironmental reconstruction,and to draw the paleoclimate which prevailed over the region:an estuarian area under a rather humid,temperate climate;a variety of ferns grew near the shore-side and in the inward l...