The measurement of sulfate mineral solubilities in the Na-K-Ca-Cl-SO4-H2O system at temperatures of 100, 150 and 200°C

At T > 100°C development of thermodynamic models suffers from missing experimental data, particularly for solubilities of sulfate minerals in mixed solutions. Solubilities in Na⁺-K⁺-Ca²⁺-Cl⁻-SO₄²⁻/H₂O subsystems were investigated at 150, 200°C and at selected compositions at 100°C. The apparatus used to examine solid-liquid phase equilibria under hydrothermal conditions has been described.In the system NaCl-CaSO₄-H₂O the missing anhydrite (CaSO₄) solubilities at high NaCl concentrations up to halite saturation have been determined. In the system Na₂SO₄-CaSO₄-H₂O the observed glauberite (Na₂SO₄ · CaSO₄) solubility is higher than that predicted by the high temperature model of Greenberg and Møller (1989), especially at 200°C. At high salt concentrations, solubilities of both anhydrite and glauberite increase with increasing temperature. Stability fields of the minerals syngenite (K₂SO₄ · CaSO₄ · H₂O) and goergeyite (K₂SO₄ · 5 CaSO₄ · H₂O) were determined, and a new phase was found at 200°C in the K₂SO₄-CaSO₄-H₂O system. Chemical and single crystal structure analysis give the formula K₂SO₄ · CaSO₄. The structure is isostructural with palmierite (K₂SO₄ · PbSO₄). The glaserite (“3 K₂SO₄ · Na₂SO₄”) appears as solid solution in the system Na₂SO₄-K₂SO₄-H₂O. Its solubility and stoichiometry was determined as a function of solution composition.     

Time and space dependency in impact damage evaluation of a sub-Plinian eruption at Mount Vesuvius

The volcanic eruptions have produced death and devastation along the ages; the victims caused by the documented events are about 260,000. Today, people subjected to volcanic risk are 500 million. They live predominantly in large conurbations, such as Tokyo, Mexico City, Seattle and Naples, which are located in the proximity of volcanoes with a high probability to erupt. Further, cause of concern is the elevated growth rates of the urban populations in the developing countries, seeing that many cities are located just above the tectonic belts where are predominantly situated the World’s most explosive volcanoes. Therefore, the volcanic risk mitigation of these areas requires a careful territorial planning together with an adequate knowledge of the behaviour of constructions under the eruption effects. The problem is very complex considering that a several number of actions (such as lavas, earthquakes, ash fall, pyroclastic flows, ballistics, landslides, tsunami and lahars) with a peculiar time–space distribution are produced by an eruptive event. Moreover, for the impact evaluation of a volcanic eruption, the time–space effect acquires a great importance, differently by the case of single catastrophic event (such as tectonic earthquakes, debris flows, etc.), since the sequence of the several exceptional actions which occur during an eruptive event, that modify the resistance characteristics of the struck constructions, in consequence, the impact damage evaluation requires analyses, step by step, of the eruptive process, the damage accumulated on the buildings and the distribution of the damage on the territory. All these aspects are examined in this paper which furnishes a useful compendium relating to the impact damage assessment produced on buildings by an explosive volcanic eruption, through the time–space variability analysis. This document organically summarizes the results of about 15 years of researches conducted by the PLINIVS Study Centre (Study Centre for the Hydrogeological, Volcanic and Seismic Engineering) with reference to the volcanic risk assessment, in the framework of the scientific literature on the topic. The paper analyses the probabilistic approaches used these days to treat Hazard, Vulnerability and Exposure in risk and impact evaluation of volcanic eruptions. Reliability of the model available is discussed; open problems and future improvement of the research in progress are highlighted. In conclusion, recommendations to follow for impact estimation studies in volcanology are reported.     

Depth- and current-induced effects on wave propagation into the Altamaha River Estuary, Georgia

A study of sea surface wave propagation and its energy deformation was carried out using field observations and numerical experiments over a region spanning the midshelf of the South Atlantic Bight (SAB) to the Altamaha River Estuary, GA. Wave heights on the shelf region correlate with the wind observations and directional observations show that most of the wave energy is incident from the easterly direction. Comparing midshelf and inner shelf wave heights during a time when there was no wind and hence no wave development led to an estimation of wave energy dissipation due to bottom friction with corresponding wave dissipation factor of 0.07 for the gently sloping continental shelf of the SAB. After interacting with the shoaling region of the Altamaha River, the wave energy within the estuary becomes periodic in time showing wave energy during flood to high water phase of the tide and very little wave energy during ebb to low water. This periodic modulation inside the estuary is a direct result of enhanced depth and current-induced wave breaking that occurs at the ebb shoaling region surrounding the Altamaha River mouth at longitude 81.23°W. Modelling results with STWAVE showed that depth-induced wave breaking is more important during the low water phase of the tide than current-induced wave breaking during the ebb phase of the tide. During the flood to high water phase of the tide, wave energy propagates into the estuary. Measurements of the significant wave height within the estuary showed a maximum wave height difference of 0.4 m between the slack high water (SHW) and slack low water (SLW). In this shallow environment these wave–current interactions lead to an apparent bottom roughness that is increased from typical hydraulic roughness values, leading to an enhanced bottom friction coefficient.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

Mercury resolved spectroscopy from NTT

Mercury has been observed in June 2006 with the SofI instrument at NTT. Resolved spectroscopy was performed in the range. The observations were acquired close to a favorable quadrature with maximum elongation, and span mostly the southern hemisphere in the 235–315°E longitude area.In contrast to recent observations from IRTF, the present study does not indicate any pyroxene absorption in the near-infrared range, neither in the region nor at . Detailed spectral analysis allows to derive an upper limit of 1.5% type-A pyroxene (hedenbergite) or 1.1% enstatite (assuming minimum lunar iron content) in the regions observed, at the 700 km scale. Assuming lunar-like maturity effects on band depth, this corresponds to an upper limit of 0.15 and 0.6 wt.% FeO content in silicates, an order of magnitude less than previous estimates.     

Do extrusion ages reflect magma generation processes at depth? An example from the Neogene Volcanic Province of SE Spain

The high-K calc-alkaline volcanic rocks along the Neogene Volcanic Province of SE Spain represent crustal anatectic melts mixed with mantle components during the opening of the Alborán Sea. Partially melted metapelitic enclaves, along with the geochemical signature, provide evidence of their crustal source. U–Pb SHRIMP geochronology on monazite and zircon from enclaves and their hosting lavas in the localities of El Hoyazo, Mazarrón and Mar Menor reveals variable delays between the melting at depth and the eruption of the volcanics. These data indicate that: (1) the most important event of anatexis in the Neogene spanned at least the 3 m.y. interval between 12 and 9 Ma; (2) there is no trend in age of crustal melting; and (3) the delay between magma generation and extrusion varies from more than 3 m.y. at El Hoyazo to ~0.5 m.y. and possibly 2.5 m.y. at Mar Menor, with no significant delay measurable at Mazarrón. The variable time delay between anatexis and lava extrusion indicates that radiometric ages of volcanics may provide misleading information on the timing of magma genesis occurring at depth. This highlights the pitfall of basing detailed geodynamic models on volcanic extrusion ages alone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Paleolimnological significance of spinose and non-spinose morphs of Pyrgophorus hibbardi (Leonard and Franzen, 1944)

The basal portion of the Ogallala Formation (=Laverne Formation) (Lower Pliocene) Beaver County, Oklahoma, contains an interesting assemblage of non-marine fossil molluscs that include both spinose and non-spinose forms of the aquatic gastropod species Pyrgophorus hibbardi. The origin and paleolimnological significance of the spinose morph has been a source of much conjecture that has influenced environmental reconstructions of this assemblage. In one hypothesis the spinose forms of P. hibbardi are assumed to be associated with brackish water conditions by analogy with some populations of a related hydrobiid Potamopyrgus jenkinsi. To test the hypothesis that the spinose forms lived under different water conditions than the non-spinose morphs, we analyzed 10 specimens each of the two varieties for stable oxygen and carbon isotope ratios in the shell aragonite.The mean isotope ratios for the smooth and spinose morphs show no significant difference (oxygen: t = 0.28, df = 18, P (T t) 0.78 n.s.; carbon: t = 0.96, df = 18, P (T t) 0.35 n.s). We conclude that the lack of a statistically significant difference between the means of the oxygen and carbon isotope values for the smooth and spinose morphs suggests that the two forms lived in waters having similar isotope signatures. The considerable range in oxygen isotope values recorded by both morphs of P. hibbardi, including values as high as 5–6, suggest that both morphs were associated with waters which were periodically evaporatively enriched in ¹⁸O.     

A new method for the determination of the specific kinetic energy (SKE) released to pyroclastic particles at magmatic fragmentation: theory and first experimental results

Brittle magmatic fragmentation plays a crucial role in explosive eruptions. It represents the starting point of hazardous explosive events that can affect large areas surrounding erupting volcanoes. Knowing the initial energy released during this fragmentation process is fundamental for the understanding of the subsequent dynamics of the eruptive gas-particle mixture and consequently for the forecasting of the erupting column’s behavior. The specific kinetic energy (SKE) of the particles quantifies the initial velocity shortly after the fragmentation and is therefore a necessary variable to model the gas-particle conduit flow and eruptive column regime. In this paper, we present a new method for its determination based on fragmentation experiments and identification of the timings of energy release. The results obtained on compositions representative for basaltic and phonolitic melts show a direct dependence on magma material properties: poorly vesiculated basaltic melts from Stromboli show the highest SKE values ranging from 7.3 to 11.8 kJ/kg, while experiments with highly vesiculated samples from Stromboli and Vesuvius result in lower SKE values (3.1 to 3.8 kJ/kg). The described methodology presents a useful tool for quantitative estimation of the kinetic energy release of magmatic fragmentation processes, which can contribute to the improvement of hazard assessment.