A new versatile constitutive law for modelling the monotonic response of soft rocks and structured fine-grained soils

This paper deals with a new critical state–based constitutive model for soft rocks and fine-grained soils. The model, formulated in the single-surface plasticity framework, is characterised by the following main features: (i) a generalised three-invariant yield surface capable of reproducing a wide set of well-known criteria, (ii) the dependency of the elastic stiffness on the current stress state by means of a hyperelastic formulation, (iii) the ability of simulating the plastic strain–driven structure degradation processes by a set of appropriate isotropic hardening laws, and (iv) a nonassociate flow rule in the meridian plane. The adopted formulation is hierarchical, such that the various features of the model can be activated or excluded depending on the specific kind of geomaterial to be modelled and on the quality and quantity of the related available experimental results. The constitutive model was implemented in a commercial finite element code by means of an explicit modified Euler scheme with automatic substepping and error control. The procedure does not require any form of stress correction to prevent drift from the yield surface. The performance of the model is first analysed by means of a wide set of parametric analyses, in order to highlight the main features and to evaluate the sensitivity of the formulation with reference to the input parameters. The model is then adopted to simulate the experimental response observed on three different geomaterials, ranging from soft clays to soft rocks.     

Magnetic record associated with tree ring density: Possible climate proxy

A magnetic signature of tree rings was tested as a potential paleo-climatic indicator. We examined wood from sequoia tree, located in Mountain Home State Forest, California, whose tree ring record spans over the period 600 – 1700 A.D. We measured low and high-field magnetic susceptibility, the natural remanent magnetization (NRM), saturation isothermal remanent magnetization (SIRM), and stability against thermal and alternating field (AF) demagnetization. Magnetic investigation of the 200 mm long sequoia material suggests that magnetic efficiency of natural remanence may be a sensitive paleoclimate indicator because it is substantially higher (in average >1%) during the Medieval Warm Epoch (700–1300 A.D.) than during the Little Ice Age (1300–1850 A.D.) where it is <1%. Diamagnetic behavior has been noted to be prevalent in regions with higher tree ring density. The mineralogical nature of the remanence carrier was not directly detected but maghemite is suggested due to low coercivity and absence of Verwey transition. Tree ring density, along with the wood's magnetic remanence efficiency, records the Little Ice Age (LIA) well documented in Europe. Such a record suggests that the European LIA was a global phenomenon. Magnetic analysis of the thermal stability reveals the blocking temperatures near 200 degree C. This phenomenon suggests that the remanent component in this tree may be thermal in origin and was controlled by local thermal condition.     

New insights into aggregation and conformational behaviour of humic substances: Application of high resolution ultrasonic spectroscopy

The potential of high resolution ultrasonic analysis (HRUS) in humic acid colloidal properties research has been demonstrated. Sodium salts of humic acids from soil and lignite showed similar behaviour, supporting the hypothesis that, at both neutral and alkaline pH, they aggregate from very low concentration. The same conclusion can be reached for solutions at high ionic strength. We tried to apply the same procedure as used for the study of micellization and determination of critical micelle concentration of common surfactants. As expected, our experiments did not show the same break as demonstrated on the HRUS records for sodium dodecyl sulfate, at least in the range of measured concentration (i.e. from 0.001 up to 10 g L⁻¹). The colloidal state of humic acids in aqueous solution is very sensitive to the presence of other, both charged and neutral, molecules. Aggregation of humic acids can be disturbed or promoted, depending on the concentration, by electrostatic or other weak interactions with extraneous molecules. Structures of varying mechanical strength (rigidity) can be formed in solutions of the same components but at different concentration. Such behaviour reflects mechanisms which occur during the sequestration of hydrophobic organic compounds and has several implications for the protection/transportation of labile structures and contaminants which are hypothesized to be encapsulated within hydrophobic pockets of soluble humic aggregates.     

Circulation in a Southern Italy coastal basin: Modelling and field measurements

The purpose of the present work is to study the hydrodynamic aspects in the Mar Piccolo, a coastal basin located on the northern side of the Gulf of Taranto in the Ionian Sea (Italy), by means of mathematical modelling and field measurements. The latter were assessed during three surveys carried out in the spring–summer of 2002. Collected data have been utilized as input by the 3-D Princeton Ocean Model, which is a sigma coordinate, free surface ocean model which was developed in the late 1970s by Blumberg and Mellor. Simulations in baroclinic condition were forced by a homogeneous and stationary wind field, a simple tidal wave, a constant outflow and vertical stratification of temperature and salinity. A comparison was made between the mathematical modelling results and the field measurements collected during the surveys, in terms of velocity. It was observed that during small tides, when the wind effect prevails over the stratification effect, the best model results were obtained for the most superficial layer and that superficial patterns reproduced by the model are more sensitive to wind direction than to stratification. On the contrary, when the wind effect decreases or the thermohaline effect rises, best results occurred in deeper layers.     

Gradient in the climate change signal of European discharge predicted by a multi-model ensemble

In order to perform hydrological studies on the PRUDENCE regional climate model (RCM) simulations, a special focus was put on the discharge from large river catchments located in northern and central Europe. The discharge was simulated with a simplified land surface (SL) scheme and the Hydrological Discharge (HD) model. The daily fields of precipitation, 2 m temperature and evapotranspiration from the RCM simulations were used as forcing. Therefore the total catchment water balances are constrained by the hydrological cycle of the different RCMs. The validation of the simulated hydrological cycle from the control simulations shows that the multi-model ensemble mean is closer to the observations than each of the models, especially if different catchments and hydrological variables are considered. Therefore, the multi-model ensemble mean can be used to largely reduce the uncertainty that is introduced by a single RCM. This also provides more confidence in the future projections for the multi-model ensemble means. The scenario simulations predict a gradient in the climate change signal over Northern and Central Europe. Common features are the overall warming and the general increase of evapotranspiration. But while in the northern parts the warming will enhance the hydrological cycle leading to an increased discharge, the large warming, especially in the summer, will slow down the hydrological cycle caused by a drying in the central parts of Europe which is accompanied by a reduction of discharge. The comparison of the changes predicted by the multi-model ensemble mean to the changes predicted by the driving GCM indicates that the RCMs can compensate problems that a driving GCM may have with local scale processes or parameterizations.     

Susceptibility to oxidative stress of mussels (Mytilus galloprovincialis) in the Venice Lagoon (Italy)

The aim of this study was to evaluate the susceptibility to pollutant mediated oxidative stress of the Mediterranean mussel Mytilus galloprovincialis in the Venice lagoon (Italy).

In June 2003, mussels from a farm were transplanted to eight sites in the lagoon for five weeks. Oxidative stress responses were measured by: (i) total oxyradical scavenging capacity (TOSC) assay, for an overall evaluation of the oxidative stress response capability; (ii) catalase (CAT), as a key enzyme involved in the antioxidant defence system; (iii) malondialdehyde (MDA), as an indicator of lipid peroxidation, to evaluate an oxidative damage; (iv) metallothioneins (MTs), as they play a role in the antioxidant defence.

The TOSC analysis revealed a reduced capability to eliminate: (i) peroxyl radical in mussels transplanted at Palude della Rosa, Valle Millecampi and Chioggia; (ii) hydroxyl radical at Campalto and Valle Millecampi; (iii) peroxynitrite at Valle Millecampi.

Inhibition in CAT activity, observed in all the monitored sites, confirms the presence of an oxidative pressure in transplanted mussels.

In addition, Pearson correlation analysis was performed in order to observe possible links between the various parameters. The PCA was a powerful tool to discriminate impacted sites, suggesting that the mussels transplanted throughout the Venice lagoon were subjected to different levels of oxidative pressure. Furthermore, it provided an easy and useful tool to summarize the obtained results.     

An estimation of the probable maximum precipitation for river basins in the Czech Republic

The hydro-meteorological evaluation of a flood event in July 1997 (the Odra flood in Central Europe) demonstrated that new procedures to estimate design floods for the reservoir outflow structures in the Czech Republic (CR) were needed. Therefore, the techniques of the estimation of Probable Maximum Precipitation (PMP) were developed in a national research project (1998–2000), and the activity focused on the improvement of the area related PMP estimates was going on within a present national project. In the frame of the evaluation of the next extreme precipitation event in August 2002 (the Labe flood in the CR and Germany), we compared the catchments related precipitation with the PMP estimates. In this paper, an outline of the PMP estimation techniques is given and the use of data from the Czech gauges is described, the aim being the statistical derivation of the point and area PMP estimates for precipitation duration of 1 to 5 days. The use of radar data in assessing the maximized area reduction factor is discussed and the relationship resulting from the radar measurements over the CR territory is presented. An evaluation of the radar-based area rainfall enabled us to transform the point PMP to the area PMP estimate designed for the river basins in CR. In the last part of the paper, the results obtained by comparing the rainfalls in 1997 and 2002 flood events with the PMP estimates are presented. The comparison showed that the maximum area rainfalls over small Czech catchments (the 3rd order river basins) did not exceed 63% of the corresponding PMP values.     

A comparison of the flood precipitation episode in August 2002 with historic extreme precipitation events on the Czech territory

The hydro-meteorological characteristics of the flood from August 2002, which affected a great part of the Czech territory, particularly the Vltava and Labe river basin, were compared with corresponding conditions during similar flood events in the summer seasons of 1997, 1890, 1897 and 1903. The comparison shows analogies in synoptic conditions and causal precipitation heights. The heaviest precipitation fell in the area of a considerable horizontal pressure gradient on the rearward side of the cyclone which advanced very slowly to the north-east across Central Europe and created conditions for the transport of moist air as well as for an organized long-term updraft enhanced in orographically exposed regions. The varying features of the individual events were based on the spatial–temporal distribution of causal precipitation and also on the very different saturation of the catchments. It was chiefly the extraordinary time concentration of precipitation together with the highest catchment saturation that made the flood in 2002 the most extreme.The extremeness of meteorological fields during two episodes in July 1997 was compared with two episodes in August 2002 with the aid of the reanalysis data from ECMWF. The first episode in 1997 and the second episode in 2002 were the most similar and more extreme in terms of the large-scale fields of basic meteorological quantities. The similar features of these episodes are specifically an intensive influx of moisture into Central Europe and intensive upward motions in the precipitation area. The extremeness of upper- and low-level potential vorticity fields was evaluated to diagnose the behavior of the cyclone and frontal precipitation bands accompanying it. The suitable spatial configuration of positive upper- and low-level potential vorticity anomalies induced an additional amplification of upward motions in the precipitation area that apparently contributed to triggering the heavy precipitation over Central Europe. On the whole, quantities reached more extreme values during the second episode in 2002.