Mercury content of mussels from the St. Lawrence Estuary and northwestern Gulf of St. Lawrence, Canada

A first survey of the mercury content of intertidal mussels in the St. Lawrence Estuary and part of the Gulf of St. Lawrence shows means values ranging from 0.160 to 0.629 ppm (dry weight). Highest values (grand mean 0.430 ppm) were found in the upper part of the lower estuary, lowest values (grand mean 0.172 ppm) on the north shore of the estuary and Gulf, and intermediate values along the Gaspé Peninsula. The results indicate a decreasing gradient in mercury levels from the mouth of the Saguenay Fjord seaward.     

Evolution de la structure de la couche limite planetaire sur des sites oceaniques et continentaux

We have studied the evolution of the planetary boundary layer using both oceanic and continental stations. This has been possible through the analysis of twice-daily temperature radiosondes at three different oceanic stations (Point A; Point K; and Azores) and also at three continental stations (Berlin, Trappes and Madrid) all situated in the Northern Hemisphere. We have studied the annual evolution of mixing layers and of temperature inversion levels; an annual evolution presenting a minimum in winter and a maximum in summer has been observed in the continental stations; the oceanic stations present a lesser variation and in the opposite sense. As for the elevated inversion layers, their maximum frequency can be observed in summer at the oceanic stations and in winter at the continental stations. We have shown that considering the studied stations, both the level and the frequency of the elevated inversion layers are similar at 00 h and at 12 h; such a result is important because these layers regulate the intensity of the exchanges between the ground and the free atmosphere. Using the equivalent coefficient, we have determined the annual variation of the vertical exchanges between the surface and different altitudes. At the continental stations, the vertical exchanges are more important in summer than they are in winter; the opposite behaviour occurs at the oceanic stations.     

Sulfur in peat-forming systems of the Okefenokee Swamp and Florida Everglades: origins of sulfur in coal

Six sulfur forms were investigated in profiles of freshwater- and marine-derived peat-forming systems of the Okefenokee Swamp, Georgia and Everglades Swamp, Florida. Total sulfur levels of 0.1–10% were found, thus indicating a major incorporation of sulfur in the very early stages of coal formation. The quantities of hydrogen sulfide and elemental sulfur observed appeared to be indicative of whether marine or freshwater conditions prevailed at the site of deposition. Carbon-bonded sulfur accounted for 70% of the total sulfur in the freshwater peat and 50% of the total sulfur in the marine peat. Over 15% of the total sulfur was in pyritic combination in the marine environment, while levels of pyrite in the freshwater peats were an order of magnitude lower. An ester-sulfate fraction represented 25% of the total sulfur in both freshwater and marine peats. The levels of sulfur forms in the peat profiles are compared to those observed in living plants and to various coals; levels of pyrite and organic sulfur in the peat are similar to those found by other investigators in freshwater-derived and marine-derived coals.     

Statistical analyses of the zeolites clinoptilolite and heulandite

Cluster analysis showed that at least five compositional subgroups exist within the heulandite family of zeolites. The two extreme members of these five groups are the traditional heulandites and clinoptilolites. At a coarser level of clustering, two subgroups, clinoptilolite and heulandite, are evident. As shown by discriminant analysis, the most important compositional variable distinguishing all these groups is calcium. From principal components analysis, it was found that the c cell dimensions of the heulandite family of zeolites varies directly with aluminum and inversely with silicon. The a cell dimension and the β angle seem to vary inversely with the iron content. The b cell dimension may vary inversely with iron and aluminum and directly with silicon.     

Generation of homologous porphyrins under simulated geochemical conditions

Crude oils generally contain at least one symmetrical homologous series of porphyrins, which is usually centered at m/e 476 (DPEP) or m/e 478 (etioporphyrin). Simulated geochemical conditions in the present study resulted in decarboxylations and alkylations which ultimately led to the synthesis of homologous porphyrins from a single porphyrin. In several series of closed tube experiments, mesoporphyrin IX dimethylester (MPDME) was mixed with a variety of constituents including benzene, acetic acid, propionic acid, water and clay; the experiments were performed at temperatures between 135°C and 400°C at time intervals up to 80 days. Dealkylation, alkylation, hydrolysis, decarboxylation and metallation products were observed. An unsymmetrical homologous series of porphyrins was produced from MPDME. The dominant mass was m/e 478 (corresponding to a double deoarboxylation). Dealkylation products in multiples of 14 amu below the m/e 478 peak comprised the other members of the series. Cu-MPDME also produced homologous porphyrins. These, however, exhibited symmetry about the dominant members, similar to the symmetry found for the porphyrins of most petroleums and oil shales.     

Novel photosensors for neutrino detectors and telescopes

The volume and the photosensitive area of next generation detectors of the numerous rarely occurring phenomena will greatly exceed the sizes of the current experiments. These phenomena include cosmic neutrinos, atmospheric neutrinos, long-baseline neutrino beams from accelerators, geo-neutrinos, geo-reactor neutrinos, and hypothetic proton decays. Similar requirements hold for a new type of a large scanning device for homeland security and nuclear proliferation control, and for the future widely accessible medical imaging devices. Photon detectors are the most important component of such detectors. Existing photosensors are based on vacuum tubes and dynode electron multipliers that are essentially hand-made, expensive and nearly impossible to produce in large enough quantities. Silicon detectors are too small for experiments requiring a very large photosensitive area. Our laboratory is developing novel detectors with a large photosensitive area that can be mass-produced, similar to large flat panel TV displays.     

Enhancing RUSLE to include runoff‐driven phenomena

RUSLE2 (Revised Universal Soil Loss Equation) is the most recent in the family of Universal Soil Loss Equation (USLE)/RUSLE/RUSLE2 models proven to provide robust estimates of average annual sheet and rill erosion from a wide range of land use, soil, and climatic conditions. RUSLE2's capabilities have been expanded over earlier versions using methods of estimating time‐varying runoff and process‐based sediment transport routines so that it can estimate sediment transport/deposition/delivery on complex hillslopes. In this report we propose and evaluate a method of predicting a series of representative runoff events whose sizes, durations, and timings are estimated from information already in the RUSLE2 database. The methods were derived from analysis of 30‐year simulations using a widely accepted climate generator and runoff model and were validated against additional independent simulations not used in developing the index events, as well as against long‐term measured monthly rainfall/runoff sets. Comparison of measured and RUSLE2‐predicted monthly runoff suggested that the procedures outlined may underestimate plot‐scale runoff during periods of the year with greater than average rainfall intensity, and a modification to improve predictions was developed. In order to illustrate the potential of coupling RUSLE2 with a process‐based channel erosion model, the resulting set of representative storms was used as an input to the channel routines used in Chemicals, Runoff, and Erosion from Agricultural Management Systems (CREAMS) to calculate ephemeral gully erosion. The method was applied to a hypothetical 5‐ha field cropped to cotton in Marshall County, MS, bisected by a potential ephemeral gully having channel slopes ranging from 0·5 to 5% and with hillslopes on both sides of the channel with 5% steepness and 22·1 m length. Results showed the representative storm sequence produced reasonable results in CREAMS indicating that ephemeral gully erosion may be of the same order of magnitude as sheet and rill erosion. Copyright © 2010 John Wiley & Sons, Ltd.     

Snow accumulation distribution inferred from time‐lapse photography and simple modelling

The spatial and temporal distribution of snow accumulation is complex and significantly influences the hydrological characteristics of mountain catchments. Many snow redistribution processes, such as avalanching, slushflow or wind drift, are controlled by topography, but their modelling remains challenging. In situ measurements of snow accumulation are laborious and generally have a coarse spatial or temporal resolution. In this respect, time‐lapse photography shows itself as a powerful tool for collecting information at relatively low cost and without the need for direct field access. In this paper, the snow accumulation distribution of an Alpine catchment is inferred by adjusting a simple snow accumulation model combined with a temperature index melt model to match the modelled melt‐out pattern evolution to the pattern monitored during an ablation season through terrestrial oblique photography. The comparison of the resulting end‐of‐winter snow water equivalent distribution with direct measurements shows that the achieved accuracy is comparable with that obtained with an inverse distance interpolation of the point measurements. On average over the ablation season, the observed melt‐out pattern can be reproduced correctly in 93% of the area visible from the fixed camera. The relations between inferred snow accumulation distribution and topographic variables indicate large scatter. However, a significant correlation with local slope is found and terrain curvature is detected as a factor limiting the maximal snow accumulation. Copyright © 2010 John Wiley & Sons, Ltd.     

Footwall mineralization during Late Miocene extension along the West Cycladic Detachment System,Lavrion, Greece

The West Cycladic Detachment System (WCDS) has been mapped from the western Cycladic islands to Lavrion (mainland Greece), where several top‐to‐SSW low‐angle normal faults at different structural levels are observed. Near the detachment horizon, hydrothermal fluid flow originating from Miocene intrusions lead to high‐temperature carbonate strata‐bound Pb–Ag–Zn ore deposits. Zircon (U–Th)/He cooling ages from the mineralized footwall are 7.1 ± 0.6 to 7.9 ± 0.6 Ma. Carbon‐ and O‐isotope analyses of the carbonate host indicate high water‐to‐rock ratios during brittle deformation‐induced metasomatism, and that this interaction, unrelated to proximity of the intrusions, plays the dominant role in the mineralization. The Late Miocene geology of Lavrion is strikingly similar to Serifos island on the SE termination of the WCDS, both characterized by strong localization of detachment faulting and the interaction of brittle deformation with the injection of fluids related to granitoid intrusions.     

Impact of road‐generated storm runoff on a small catchment response

The impact of road‐generated runoff on the hydrological response of a zero‐order basin was monitored for a sequence of 24 storm events. The study was conducted in a zero‐order basin (C1; 0·5ha) with an unpaved mountain road; an adjacent unroaded zero‐order basin (C2; 0·2 ha) with similar topography and lithology was used to evaluate the hydrological behaviour of the affected zero‐order basin prior to construction of the road. The impact of the road at the zero‐order basin scale was highly dependent on the antecedent soil‐moisture conditions, total storm precipitation, and to some extent rainfall intensity. At the beginning of the monitoring period, during dry antecedent conditions, road runoff contributed 50% of the total runoff and 70% of the peak flow from the affected catchment (C1). The response from the unroaded catchment was almost insignificant during dry antecedent conditions. As soil moisture increased, the road exerted less influence on the total runoff from the roaded catchment. For very wet conditions, the influence of road‐generated runoff on total outflow from the roaded catchment diminished to only 5·4%. Both catchments, roaded and unroaded, produced equivalent amount of outflow during very wet antecedent conditions on a unit area basis. The lag time between the rainfall and runoff peaks observed in the unroaded catchment during the monitoring period ranged from 0 to 4 h depending on the amount of precipitation and antecedent conditions, owing mainly to much slower subsurface flow pathways in the unroaded zero‐order basin. In contrast, the lag time in the roaded zero‐order basin was virtually nil during all storms. Copyright © 2009 John Wiley & Sons, Ltd.