Lensing, reddening and extinction effects of Mg ii absorbers from z= 0.4 to 2

Using a sample of almost 7000 strong Mg  ii absorbers with   W ₀ > 1 Å  and  0.4 < z < 2.2  detected in the SDSS DR4 data set, we investigate the gravitational lensing and dust extinction effects they induce on background quasars. After carefully quantifying several selection biases, we isolate the reddening effects as a function of redshift and absorber rest equivalent width, W ₀. We find the amount of dust to increase with cosmic time as  τ( z ) ∝ (1 + z )^−1.1±0.4  , following the evolution of cosmic star density or integrated star formation rate. We measure the reddening effects over a factor of 30 in E ( B − V ) and we find that  τ∝ ( W ₀)^1.9±0.1  , providing us with an important scaling for theoretical modelling of metal absorbers. We also measure the dust-to-metal ratio and find it similar to that of the Milky Way. In contrast to previous studies, we do not detect any gravitational magnification by Mg  ii systems. We measure the upper limit  μ < 1.10  and discuss the origin of the discrepancy. Finally, we estimate the fraction of absorbers missed due to extinction effects and show that it rises from 1 to 50 per cent in the range  1 < W ₀ < 6 Å  . We parametrize this effect and provide a correction for recovering the intrinsic  ∂ N /∂ W ₀  distribution.     

Rotational dynamics of a solar system body under solar radiation torques

The rotational dynamics of a small solar system body subject to solar radiation torques is investigated. A set of averaged evolutionary equations are derived as an analytic function of a set of spherical harmonic coefficients that describe the torque acting on the body due to solar radiation. The analysis also includes the effect of thermal inertia. The resulting equations are studied and a set of possible dynamical outcomes for the rotation rate and obliquity of a small body are found and characterized.     

A multi-proxy record of the Last Glacial Maximum and last 14,500?years of paleoenvironmental change at Lone Spruce Pond, southwestern Alaska

Sediment cores from Lone Spruce Pond (60.007°N, 159.143°W), southwestern Alaska, record paleoenvironmental changes during the global Last Glacial Maximum (LGM), and during the last 14,500 calendar years BP (14.5?cal?ka). We analyzed the abundance of organic matter, biogenic silica, carbon, and nitrogen, and the isotope ratios of C and N, magnetic susceptibility, and grain-size distribution of bulk sediment, abundance of alder shrub (Alnus) pollen, and midge (Chironomidae and Chaoboridae) assemblages in a 4.7-m-long sediment sequence from the depocenter at 22?m water depth. The basal unit contains macrofossils dating to 25?C21?cal?ka (the global LGM), and is interpreted as glacial-lacustrine sediment. The open water requires that the outlet of the Ahklun Mountain ice cap had retreated to within 6?km of the range crest. In addition to cladocerans and diatoms, the glacial-lacustrine mud contains chironomids consistent with deep, oligotrophic conditions; several taxa associated with relatively warm conditions are present, suggestive of relative warmth during the global LGM. The glacial-lacustrine unit is separated from the overlying non-glacial lake sediment by a possible disconformity, which might record a readvance of glacier ice. Non-glacial sediment began accumulating around 14.5?cal?ka, with high flux of mineral matter and fluctuating physical and biological properties through the global deglacial period, including a reversal in biogenic-silica (BSi) content during the Younger Dryas (YD). During the global deglacial interval, the ??¹³C values of lake sediment were higher relative to other periods, consistent with low C:N ratios (8), and suggesting a dominant atmospheric CO₂ source of C for phytoplankton. Concentrations of aquatic faunal remains (chironomids and Cladocera) were low throughout the deglacial interval, diversity was low and warm-indicator taxa were absent. Higher production and air temperatures are inferred following the YD, when bulk organic-matter (OM) content (LOI 550?°C) increased substantially and permanently, from 10 to 30?%, a trend paralleled by an increase in C and N abundance, an increase in C:N ratio (to about 12), and a decrease in ??¹³C of sediment. Post-YD warming is marked by a rapid shift in the midge assemblage. Between 8.9 and 8.5?cal?ka, Alnus pollen tripled (25?C75?%), followed by the near-tripling of BSi (7?C19?%) by 8.2?cal?ka, and ??¹⁵N began a steady rise, reflecting the buildup of N and an increase in denitrification in soils. Several chironomid taxa indicative of relatively warm conditions were present throughout the Holocene. Quantitative chironomid-based temperature inferences are complicated by the expansion of Alnus and resulting changes in lake nutrient status and production; these changes were associated with an abrupt increase in cladoceran abundance and persistent shift in the chironomid assemblage. During the last 2,000?years, chironomid-assemblage changes suggest cooler temperatures, and BSi and OM values were generally lower than their maximum Holocene values, with minima during the seventh and eighth centuries, and again during the eighteenth century.     

Probabilistic evaluation of tunnel face stability in spatially random soils using sparse polynomial chaos expansion with global sensitivity analysis

The sparse polynomial chaos expansion is employed to perform a probabilistic analysis of the tunnel face stability in the spatially random soils. A shield tunnel under compressed air is considered which implies that the applied pressure is uniformly distributed on the tunnel face. Two sets of failure mechanisms in the context of the limit analysis theory with respect to the frictional and the purely cohesive soils are used to calculate the required face pressure. In the case of the frictional soils, the cohesion and the friction angle are modeled as two anisotropic cross-correlated lognormal random fields; for the purely cohesive soils, the cohesion and the unit weight are modeled as two anisotropic independent lognormal random fields. The influences of the spatial variability and of the cross-correlation between the cohesion and the friction angle on the probability density function of the required face pressure, on the sensitivity index and on the failure probability are discussed. The obtained results show that the spatial variability has an important influence on the probability density function as well as the failure probability, but it has a negligible impact on the Sobol’s index.     

Valuing the non-CO2 climate impacts of aviation

The non-CO₂ climate impact of aviation (NO_x and contrails) is assessed and emissions weighting factors (EWFs) i.e., the factor by which aviation CO₂ emissions should be multiplied to get the CO₂-equivalent emissions for annual fleet average conditions are estimated. The EWFs are estimated using two economic metrics. One is based on the relative damage cost between non-CO₂ forcers and CO₂. The other is based on the cost-effective valuation between the non-CO₂ forcers and CO₂ given an upper ceiling on the global annual average surface temperature (set at 2?K above pre-industrial levels). We also estimate EWFs using three physical metrics, Global Warming Potential (GWP), Global Temperature change Potential (GTP) and Sustained GTP (SGTP) and compare our results with the economics based metrics. Given best estimates on the forcing contributions from CO₂, contrails and NO_x from aviation and by using a discount rate of 3%/year, the RDC based metric gives an EWF equal to 1.4 (slightly higher than EWFs based on GWP and SGTP using a 100?year time horizon). EWF using the cost-effective approach depends on the time that remains before stabilization occurs. It is roughly equal to unity until a few years before the temperature reaches its ceiling, and approximately 2 when stabilization has taken place. EWFs based on GTP resemble those based on CETO when the time left to when stabilization occurs is sufficiently large. Once stabilization has occurred CETO values resemble RDC based values. If aviation-induced cirrus clouds are included, uncertainties increase and the EWFs for GWP, SGTP and RDC based metrics end up in the range 1.3–2.9, while EWFs for GTP and CETO remain close to unity in the near term.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Optimal design of pumping tests in leaky aquifers for stream depletion analysis

We analyze the optimal design of a pumping test for estimating hydrogeologic parameters that are subsequently used to predict stream depletion caused by groundwater pumping in a leaky aquifer. A global optimization method is used to identify the test’s optimal duration and the number and locations of observation wells. The objective is to minimize predictive uncertainty (variance) of the estimated stream depletion, which depends on the sensitivities of depletion and drawdown to relevant hydrogeologic parameters. The sensitivities are computed analytically from the solutions of Zlotnik and Tartakovsky [Zlotnik, V.A., Tartakovsky, D.M., 2008. Stream depletion by groundwater pumping in leaky aquifers. ASCE Journal of Hydrologic Engineering 13, 43–50] and the results are presented in a dimensionless form, facilitating their use for planning of pumping test at a variety of sites with similar hydrogeological settings. We show that stream depletion is generally very sensitive to aquitard’s leakage coefficient and stream-bed’s conductance. The optimal number of observation wells is two, their optimal locations are one close to the stream and the other close to the pumping well. We also provide guidelines on the test’s optimal duration and demonstrate that under certain conditions estimation of aquitard’s leakage coefficient and stream-bed’s conductance requires unrealistic test duration and/or signal-to-noise ratio.     

Fluoride Biomonitoring around a Large Aluminium Smelter Using Foliage from Different Tree Species

In order to study the pollution gradient in the vicinity of a large aluminium production facility in Patagonia (Argentina), a passive biomonitoring was performed employing foliage from three tree species. Primary scope was to identify pollution gradients and to select suitable tree species which can be used as biomonitor plants in the study area. Therefore, leaves of Eucalyptus rostrata, Populus hybridus and different needle ages of Pinus radiata were collected at different distances from the industry and the fluoride concentration was analysed in washed and unwashed samples in order to determine the amount of external fluoride. Washing reduced the F‐concentrations by 24, 39 and 51% on average in E. rostrata, P. hybridus and P. radiata, respectively, indicating that species‐specific characteristics determine the accumulation and wash‐off of dust‐associated fluorine. F‐concentrations varied from 6 to 3652 ppm F in unwashed samples indicating a steep pollution gradient in the study area. The influence of F‐emissions was discernible in all samples up to a distance of 3500 m from the smelter. E. rostrata accumulated more fluorine than the other species at equal distance from the emission source. The present study confirms that aluminium smelting results in high F deposition in the study area. Establishing a biomonitor network around large emitters is suitable and feasible to evaluate the efficiency of air control measures.