Crystal field stabilization energies of almandine-pyrope and almandine-spessartine garnets determined by FTIR near infrared measurements

The band positions of three partially overlapping Fe²⁺ spin-allowed transitions located between 4000 and 9000 cm^–1 in almandine-pyrope and almandinespessartine garnets solid solutions were measured using near-infrared (NIR) spectroscopy. The crystal field stabilization energies (CFSE) along both binaries were calculated assuming a splitting of 1100 cm^–1 for the lower orbitals. The CFSE show a slight increase along the almandine-spessartine binary from 3730 to 3810 cm^–1 and a larger increase from 3730 to 3970 cm^–1 for the almandine-pyrope binary. Dodecahedral Fe²⁺-site distortion increases with an increase in spessartine component and decreases with increasing pyrope component, in agreement with average dodecahedral site distortions determined from diffraction experiments. The excess CFSE's along both joins are negative. For the almandinespessartine binary they are small, but are about 3.5 times larger in magnitude along the join almandine-pyrope, where an interaction parameter of W= -2.9 KJ/mole has been derived from a symmetric mixing model. The excess CFSE are relatively small compared to the magnitudes of the excess enthalpies of mixing that have been assigned to garnet solid solutions. Moreover, they give no indication which could support the positive and asymmetric excess enthalpies of mixing that have been proposed for almandine-pyrope solid solutions.     

High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

Airborne gravimetry used in precise geoid computations by ring integration

Two detailed geoids have been computed in the region of North Jutland. The first computation used marine data in the offshore areas. For the second computation the marine data set was replaced by the sparser airborne gravity data resulting from the AGMASCO campaign of September 1996. The results of comparisons of the geoid heights at on-shore geometric control showed that the geoid heights computed from the airborne gravity data matched in precision those computed using the marine data, supporting the view that airborne techniques have enormous potential for mapping those unsurveyed areas between the land-based data and the off-shore marine or altimetrically derived data. Received: 7 July 1997 / Accepted: 22 April 1998     

MINQUE for block diagonal bordered systems such as those encountered in VLBI data analysis

A sparse matrix method is developed for computing variance factors for block-diagonal, bordered systems of equations using MINQUE (Minimum Norm Quadratic Unbiased Estimation). This method greatly reduces the computational effort required to apply MINQUE, thus making it practical to compute variance factors for some very large systems of equations. The computer implementation of the method is described and applied to the computation of variance factors for a combination of 1609 VLBI (Very Long Baseline Interferometry) observing sessions. The purpose of this test was to compute a variance factor for each of the data sets and, perhaps, to obtain more realistic variance estimates to replace those in common use for the analysis of VLBI data. It was found that the method is satisfactory for use with such large problems, and the test served to verify that the variances in current use in VLBI data adjustments are adequate. Received: 26 November 1996 / Accepted: 12 December 1997     

Geospatial Technologies for National Geomorphology and Lineament Mapping Project – A Case Study of Goa State

A three level classification system, based on the genesis of landforms, was used to map the geomorphology of the Goa state. The first level corresponds to the process that was responsible for landform generation, the second level or the intermediate level was assigned based on the morphography, and the third level corresponds to the individual landforms units identified based on the morphostructure. The mapping was carried out using IRS-P6 LISS-III (23.5 m) satellite image as the primary data source. Ancillary data such as geological map, topographic map, digital elevation model (DEM), field data collected by global positioning system (GPS) and web portals for image visualisation, were also used for the mapping purpose. A new software designed for mapping landforms based on the genesis, was used in this study to create a seamless geomorphology and lineament database of the Goa state in a GIS environment. A total of 58 landforms within six types of genetic classes were mapped in this area. Similarly, structural and geomorphic lineaments were also delineated using the satellite data. The database created has multi-purpose usability such as environmental studies, mining activity assessment, coastal zone management and wasteland development, since the classification system used is focused on processes, not theme specific.     

Understanding the Spatial Variability of Chlorophyll a and Total Suspended Matter Distribution Along the Southwest Bay of Bengal Using In-Situ and OCM-2 & MODIS-Aqua Measurements

Spatial and temporal distribution of chlorophyll a (chl a) and Total Suspended Matter (TSM) and inter comparison of Ocean Color Monitor-2 (OCM-2) and Moderate Resolution Imaging Spectro-radiometer (MODIS-Aqua) derived chlorophyll a and TSM was made along the southwest Bay of Bengal (BoB). The in-situ chl a and TSM concentration measured during different seasons were ranged from 0.09 to 10.63 μgl^?1 and 11.04–43.75 mgl^?1 respectively. OCM-2 and MODIS derived chl a showed the maximum (6–8 μgl^?1) at nearshore waters and the minimum (0–1 μgl^?1) along the offshore waters. OCM-2 derived TSM imageries showed the maximum (50–60 mgl^?1) along the nearshore waters of Palk Strait and the moderate concentration (2–5 mgl^?1) was observed in the offshore waters. MODIS derived minimum TSM concentration (13.244 mgl^?1) was recorded along the offshore waters, while the maximum concentration of 15.78 mgl^?1 was found along the Kodiakarai region. The inter-comparison of OCM-2 and MODIS chl a data (R ² ?=?0.549, n?=?49, p?<?0.001, SEE?=?±0.117) indicate that MODIS data overestimates chl a concentration in the nearshore waters of the southern BoB compared to the OCM-2. The correlation between OCM-2 and MODIS-Aqua TSM data (R ² ?=?0.508, N?=?53, P?<?0.001 and SEE?=?±0.024) confirms that variation in the range of values measured by OCM-2 (2–60 mgl^?1) and the MODIS (13–16 mgl^?1) derived TSM values. Despite problems in range of measurements, persistent cloud cover etc., the launch of satellites like OCM-2 with relatively high spatial resolutions makes job easier and possible to monitor chl a distribution and sediment discharges on day to day basis in the southwest BoB.