On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

Water Quality Estimation Based on Histological Investigations of Fish: Case Study of Kenozero Lake

Specific hydrological and hydrochemical conditions in Kenozero Lake have led to changes in the morphology of fishes at a cellular level. The abnormalities in the function of the respiratory, digestive, and excretory systems were recorded. The degree of pathology depended on the ecological features of the fish. The pathological changes were most pronounced in the gills of the fish species (orfe, perch, and roach) characterized by active mode of life and sensible to oxygen deficiency. The changes in the epithelium of gill filaments had a compensatory significance and were aimed at increasing the area of the functional surface of the gills under the conditions of hypoxia.     

Long-Term Variations in the Vertical Thermohaline Structure in Deep-Water Zones of the Caspian Sea

Long-term variability in water temperature and salinity in August has been determined for deep-water segments of standard profiles in the Central and Southern Caspian Sea based on data of on-board observations carried out in 1956–2000. Estimates of parameters of the vertical thermohaline structure of waters were obtained for four time intervals. These estimates have been compared to the variability in the main external factors governing the formation of thermohaline regime. Appreciable long-term variations in the vertical thermohaline structure of waters, caused by a nonperiodic alternation of two main types of hydrological processes in the Caspian Sea are revealed. Qualitative characteristics of these two types are presented.     

An automated seamless mosaicing system of multi-charge coupled devices of panchromatic data

Panchromatic data of pixel resolution 5.8 m obtained from IRS-1C and IRS-1D satellites proved to be very useful for mapping purposes. One of the popular data product is the 70 km swath mosaic which is covered by a combination of 3 CCD line sensors, each with 4096 pixels. Each CCD-line sensor with different imaging times causes geometric problems of mosaicing three strips data together. In this paper, we propose the details of the design elements of system that caters to the need for accurate and automatic multi strip image registration without any second resampling of the data. The systematic geometric correction grid mapping is improved to facilitate accurate mosaicing by automatic image registration task that makes use of the overlap data within image strips and image registration is achieved up to sub-pixel level.     

New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.     

A vibrational spectroscopic study of the oxidation of pyrite by molecular oxygen

In situ flow-through attenuated total reflectance (ATR) Fourier transform infrared (FTIR) spectroscopy has been used to investigate the formation, and step-wise oxidation, of sulfoxyanions at the pyrite surface during oxidation by molecular oxygen. The surface was studied under two different pH regimes (pH 2.5 and pH 5.6) and under two light conditions (dark and ultraviolet light). It was experimentally observed that multiple sulfoxyanions were present at the pyrite surface during oxidation by molecular oxygen, spectroscopically illustrating the concept of sulfur step-wise oxidation. The results from photochemical experiments were complex and suggest a dependence on both pH and surface speciation.     

Reversibility of radiocaesium sorption on illite

Adsorption of trace amounts of radiocaesium on NH₄-, K-, and Na-saturated Fithian illite and subsequent desorption by 1 M NH₄ showed that a substantial amount of radiocaesium (44%, 46%, and 91% for NH₄-, K-, and Na-illite, respectively) cannot be desorbed after only 5 min of adsorption. Our results suggest that this instantaneous fixation is caused by the collapse of the frayed edges of the clay mineral and the relatively high concentration of radiocaesium building up in solution in the batch desorption experiments. Consequently, commonly applied high-NH₄ extractions underestimate truly exchangeable amounts of radiocaesium in soils and sediments containing illitic clay minerals. The rate of desorption of trace amounts of radiocaesium from the solids using high NH₄ or Cs concentrations has a half-life of about 2 yr, reflecting radiocaesium desorption from (partially) collapsed interlayers. Extraction of radiocaesium from illite after 5 min of contact time with a Cs-selective adsorbent or a 1 × 10^-6 M CsCl solution shows that 100% of the bound radiocaesium is readily available. The desorption rate in the presence of a Cs-selective adsorbent has a half-life of about 0.2 yr. Desorption of radiocaesium from illite using different ammonium concentrations shows that radiocaesium partitioning follows reversible ion-exchange theory if the NH₄ concentration is below 1 × 10^-4 M, and sufficient time (weeks) is allowed for the reaction to proceed. Thus, radiocaesium sorption reversibility in the natural environment is much higher than generally assumed, and equilibrium solid/liquid partitioning may be assumed for the long-term modelling of radiocaesium mobility in the natural environment. In the particular case of anoxic freshwater sediments with very high NH₄ concentrations in the pore waters (up to several mmol.L^-1), collapse of the frayed edges of illite may occur, influencing radiocaesium partitioning. If collapse occurs before radiocaesium adsorbs to illite, high caesium sorption reversibility as measured by high-NH₄ extraction can be expected because further collapse of the frayed edges during the extraction procedure will be limited. This effect has indeed been observed earlier in the extraction of radiocaesium from anoxic freshwater sediments with high-NH₄ solutions and was as yet unexplained.     

Assessing scleractinian corals as recorders for paleo-pH: Empirical calibration and vital effects

Laboratory experiments on the branching, symbiont-bearing coral genus Porites and Acropora have been carried out to determine the dependence of the skeletal boron isotopic composition (δ¹¹B) on the pH of seawater. The results show a clear relationship similar to previously established empirical calibrations for planktonic foraminifera and inorganic calcite. A −0.6‰ offset exists between P. cylindrica and A. nobilis which is systematic over the pH range of 7.7-8.2. To test whether the δ¹¹B of coral skeletons changes with physiological processes such as photosynthesis and respiration, corals were grown along a depth transect in their natural environment and under controlled conditions in the laboratory at varying light intensities and food supply. Although we also observe an isotopic offset between P. compressa and Montipora verrucosa, neither experimental treatment systematically changed the δ¹¹B of the two species. These findings are encouraging for using the boron isotope paleo-pH proxy in corals, because it appears that seawater pH is the dominant control on the boron isotopic composition in corals.     

Quasi-simultaneous VLBI and RATAN-600 observations of active galactic nuclei

VLBI observations of several quasars and BL Lacertae objects were carried out at 1.66 GHz in November–December 1999 using six antennas (Medvezh'i Ozera, Svetloe, Pushchino, Noto, HartRAO, and Shanghai). Maps of six sources (0420+022, 0420-014, 1308+326, 1345+125, 1803+784, and DA 193) obtained with milliarcsecond resolution are presented and discussed, together with their broad-band (1–22 GHz) spectra obtained on the RATAN-600 radio telescope at epochs close to those of the VLBI observations. Comparison of the VLBI maps with maps of these sources obtained on standard VLBI networks and with the RATAN-600 quasisimultaneous total-flux measurements indicates the reliability of the results obtained on this Low Frequency VLBI Network and the good efficiency of this network.     

Pulsating evershed flows and propagating waves in a sunspot

A comparative analysis of oscillatory spectra based on 66 time series for 14 active regions observed in 2001 shows that, although the chromospheric and photospheric oscillations in the Evershed flow zone possess many common features, there is no firm evidence that the direct and inverse flows have the same physical origin. The interactions between the various oscillation modes and stationary flows results in a complex pattern of wave motions in a sunspot. We studied the Doppler-velocity variations in the sunspot NOAA 0051 during its motion over the disk. The spatial-temporal distribution of the line-of-sight velocity in the chromospheric umbra displays a chevron structure, clearly indicating the presence of propagating waves. These waves move from the center of the umbra to outer regions with a phase speed of 45–60 km/s, a period of 2.8 min, and a measured Doppler speed of 2 km/s. The amplitude of these oscillations decreases abruptly at the boundary between the umbra and penumbra, and the observed waves are not directly related to propagating penumbral waves. Furthermore, the observed pattern of the photospheric velocities shows periodic motions (with a period of 5 min) directed from the inner boundary of the penumbra and superpenumbra toward the line of maximum Evershed velocity.