Chemical and mineralogical characterization of the Mineo (Sicily,Italy) pallasite: A unique sample

The Mineo pallasite is characterized here for the first time. The only 42 g still available worldwide is part of the collection of the Department of Physics and Geology, University of Perugia. A multianalytical approach was used, joining field-emission scanning electron microscopy, Raman analysis, X-ray powder diffraction, electron-probe microanalysis, and laser ablation inductively coupled plasma mass spectrometry. Results highlighted that (1) the Mineo pallasite belongs to the Main Group pallasites; (2) the silicate component is essentially olivine, with no pyroxene component; (3) the olivine chemical composition varies in terms of both iron and trace elements; (4) the metal phase is essentially kamacite with the taenite mainly found in the plessite structure; (5) phosphide phases are present as schreibersite and barringerite. The observed compositional variability in olivines as well as their occurrence as both angular and rounded crystals suggest that the Mineo pallasite could have been derived from a large impact of a differentiated parent body with a larger solid body. The resulting pallasite conglomerate consists of the compositionally different olivines, likely coming from different areas of the same differentiated parent body, and the residual molten Fe-Ni.     

Seasonal temperatures for the past ∼400 years reconstructed from diatom and chironomid assemblages in a high-altitude lake (Lej da la Tscheppa,Switzerland)

We analysed a 42 cm long sediment record from Lej da la Tscheppa, a high-altitude lake (2,616 m a.s.l.) in the Upper Engadine valley (Switzerland) for subfossil diatoms, chironomids and pollen. The chronology of the top 21 cm of the record was established using ²¹⁰Pb analysis using a constant-rate-of-supply model, and validated with ¹³⁷Cs measurements and the content of spheroidal carbonaceous particles. A tentative chronology for the lower part of the core was obtained through extrapolation of the sedimentation rates in the uppermost part of the record. Pollen assemblages in the record reflect regional changes in forestation and land-use patterns in the Upper Engadine valley and show no evidence of significant local human activity in the lake’s catchment. Diatom assemblages record a distinct increase in planktonic taxa since the early 19th century, suggesting a decrease in the duration of ice-cover. In contrast, chironomid assemblages remained stable during a large part of the record. We applied an established chironomid-based July air temperature transfer function and a newly developed diatom-based spring air temperature transfer function to reconstruct past seasonal air temperature changes at Lej da la Tscheppa. The reconstructions indicate a diatom-inferred warming trend in spring temperatures during the past ca. 400 years, whereas chironomid-inferred summer temperatures suggest a slight cooling trend. These biota-based reconstructions are in good agreement with the centennial-scale temperature trend in an independent reconstruction of regional temperatures in the Upper Engadine region based on instrumental records and documentary proxy evidence from the Alps. Our results suggest that, in high-altitude lakes, independent chironomid- and diatom-based seasonal temperature reconstruction is possible and can be successfully used to track seasonal temperature trends.     

Earthen barriers to control lava flows in the 2001 eruption of Mt. Etna

Preceded by four days of intense seismicity and marked ground deformation, a new eruption of Mt. Etna started on 17 July and lasted until 9 August 2001. It produced lava emission and strombolian and phreatomagmatic activity from four different main vents located on a complex fracture system extending from the southeast summit cone for about 4.5 km southwards, from 3000 to 2100 m elevation (a.s.l.). The lava emitted from the lowest vent cut up an important road on the volcano and destroyed other rural roads and a few isolated country houses. Its front descended southwards to about 4 km distance from the villages of Nicolosi and Belpasso. A plan of intervention, including diversion and retaining barriers and possibly lava flow interruption, was prepared but not activated because the flow front stopped as a consequence of a decrease in the effusion rate. Extensive interventions were carried out in order to protect some important tourist facilities of the Sapienza and Mts. Silvestri zones (1900 m elevation) from being destroyed by the lava emitted from vents located at 2700 m and 2550 m elevation. Thirteen earthen barriers (with a maximum length of 370 m, height of 10–12 m, base width of 15 m and volume of 25 000 m³) were built to divert the lava flow away from the facilities towards a path implying considerably less damage. Most of the barriers were oriented diagonally (110–135°) to the direction of the flow. They were made of loose material excavated nearby and worked very nicely, resisting the thrust of the lava without any difficulty. After the interventions carried out on Mt. Etna in 1983 and in 1991–1992, those of 2001 confirm that earthen barriers can be very effective in controlling lava flows.     

The role of organic coatings in the enrichment of marine particles with selenium. The fixation of selenite on an adsorbed amino acid

The enrichment of marine particles with selenium cannot be explained as that with metals present in cationic form by complexation with anionic functional groups of adsorbed organic matter. Physicochemical data obtained using a model system are reported. The surface of the particles is modelized by a mercury electrode whose surface charge density can be easily changed, covered by a layer of adsorbed polymers. Studies with different kinds of macromolecules and salts show a specific interaction between adsorbed polyalanine and selenite. The results can be explained by the concordance of the distances between two oxygen atoms in this oxyanion and between two amine groups of the adsorbed polypeptide. A similar mechanism could occur in marine aggregates whatever their nature, as long as they contain amine groups at their surface which result in this concordance. Some prospects derived from the results are discussed.     

TropFlux wind stresses over the tropical oceans: evaluation and comparison with other products

In this paper, we present TropFlux wind stresses and evaluate them against observations along with other widely used daily air-sea momentum flux products (NCEP, NCEP2, ERA-I and QuikSCAT). TropFlux wind stresses are computed from the COARE v3.0 algorithm, using bias and amplitude corrected ERA-I input data and an additional climatological gustiness correction. The wind stress products are evaluated against dependent data from the TAO/TRITON, PIRATA and RAMA arrays and independent data from the OceanSITES mooring networks. Wind stress products are more consistent amongst each other than surface heat fluxes, suggesting that 10 m-winds are better constrained than near-surface thermodynamical parameters (2 m-humidity and temperature) and surface downward radiative fluxes. QuikSCAT overestimates wind stresses away from the equator, while NCEP and NCEP2 underestimate wind stresses, especially in the equatorial Pacific. QuikSCAT wind stress quality is strongly affected by rain under the Inter Tropical Convergence Zones. ERA-I and TropFlux display the best agreement with in situ data, with correlations >0.93 and rms-differences <0.012 Nm^?2. TropFlux wind stresses exhibit a small, but consistent improvement (at all timescales and most locations) over ERA-I, with an overall 17 % reduction in root mean square error. ERA-I and TropFlux agree best with long-term mean zonal wind stress observations at equatorial latitudes. All products tend to underestimate the zonal wind stress seasonal cycle by ~20 % in the western and central equatorial Pacific. TropFlux and ERA-I equatorial zonal wind stresses have clearly the best phase agreement with mooring data at intraseasonal and interannual timescales (correlation of ~0.9 versus ~0.8 at best for any other product), with TropFlux correcting the ~13 % underestimation of ERA-I variance at both timescales. For example, TropFlux was the best at reproducing westerly wind bursts that played a key role in the 1997–1998 El Niño onset. Hence, we recommend the use of TropFlux for studies of equatorial ocean dynamics.     

Circumstellar dust and circumstellar extinction curves

We have calculated the circumstellar extinction curves produced by dust grains which absorb and scatter the stellar radiation in the shells of pre-main-sequence stars. A Monte Carlo method was used to model the radiative transfer in non-spherical shells. The dependence on the particle size distribution and the dust shell parameters has been examined.The application of the theoretical results to explain the extinction and polarization of the Herbig Be star HD 45677 shows that the dust shell is not disk-like and that very small grains are absent in it.     

Field Placement and Evaluation of Stabilized Dredged Material (SDM) from the New York/New Jersey Harbor

Since the 1997 local ban on ocean dumping of dredged sediments, the States of New York and New Jersey have pursued a policy of environmentally sound solutions to the management of dredged material, including beneficial use of stabilized dredged material (SDM) in transportation applications. A pilot study was initiated in 1998 to evaluate the use of SDM in the construction of highway embankments. Utilizing 80,000 cubic yards of dredged material, two embankments were constructed from SDM on a commercial development area adjacent to the Harbor. Geotechnical properties and handling of SDM were evaluated both during and one year post - construction. This article presents the evaluation of the embankments themselves, including constructability and performance. The results demonstrate that SDM satisfies most of the geotechnical criteria for fill construction, except those for durability, requiring proper coverage and protection similar to that provided for fills constructed on cohesive soils. This same characteristic precludes long term stockpiling of SDM prior to final placement, limiting applications to those that have schedules overlapping with dredging projects. Increased costs for the use of SDM can be as high as $8 per cubic yard over traditional fills; however, this cost may be recouped through management fees collected from dredging projects.     

The OSIRIS‐REx target asteroid (101955) Bennu: Constraints on its physical,geological, and dynamical nature from astronomical observations

We review the results of an extensive campaign to determine the physical, geological, and dynamical properties of asteroid (101955) Bennu. This investigation provides information on the orbit, shape, mass, rotation state, radar response, photometric, spectroscopic, thermal, regolith, and environmental properties of Bennu. We combine these data with cosmochemical and dynamical models to develop a hypothetical timeline for Bennu's formation and evolution. We infer that Bennu is an ancient object that has witnessed over 4.5 Gyr of solar system history. Its chemistry and mineralogy were established within the first 10 Myr of the solar system. It likely originated as a discrete asteroid in the inner Main Belt approximately 0.7–2 Gyr ago as a fragment from the catastrophic disruption of a large (approximately 100‐km), carbonaceous asteroid. It was delivered to near‐Earth space via a combination of Yarkovsky‐induced drift and interaction with giant‐planet resonances. During its journey, YORP processes and planetary close encounters modified Bennu's spin state, potentially reshaping and resurfacing the asteroid. We also review work on Bennu's future dynamical evolution and constrain its ultimate fate. It is one of the most Potentially Hazardous Asteroids with an approximately 1‐in‐2700 chance of impacting the Earth in the late 22nd century. It will most likely end its dynamical life by falling into the Sun. The highest probability for a planetary impact is with Venus, followed by the Earth. There is a chance that Bennu will be ejected from the inner solar system after a close encounter with Jupiter. OSIRIS‐REx will return samples from the surface of this intriguing asteroid in September 2023.