The DAV and Periadriatic fault systems in the Eastern Alps south of the Tauern window

Alpine deformation of Austroalpine units south of the Tauern window is dominated by two kinematic regimes. Prior to intrusion of the main Periadriatic plutons at ~30 Ma, the shear sense was sinistral in the current orientation, with a minor north-side-up component. Sinistral shearing locally overprints contact metamorphic porphyroblasts and early Periadriatic dykes. Direct Rb-Sr dating of microsampled synkinematic muscovite gave ages in the range 33-30 Ma, whereas pseudotachylyte locally crosscutting the mylonitic foliation gave an interpreted ⁴⁰Ar-³⁹Ar age of ~46 Ma. The transition from sinistral to dextral (transpressive) kinematics related to the Periadriatic fault occurred rapidly, between solidification of the earlier dykes and of the main plutons. Subsequent brittle-ductile to brittle faults are compatible with N-S to NNW-SSE shortening and orogen-parallel extension. Antithetic Riedel shears are distinguished from the previous sinistral fabric by their fine-grained quartz microstructures, with local pseudotachylyte formation. One such pseudotachylyte from Speikboden gave a ⁴⁰Ar-³⁹Ar age of 20 Ma, consistent with pseudotachylyte ages related to the Periadriatic fault. The magnitude of dextral offset on the Periadriatic fault cannot be directly estimated. However, the jump in zircon and apatite fission-track ages establishes that the relative vertical displacement was ~4-5 km since 24 Ma, and that movement continued until at least 13 Ma.     

Ab initio study of the high-pressure behavior of CaSiO3 perovskite

Using density functional simulations, within the generalized gradient approximation and projector-augmented wave method, we study structures and energetics of CaSiO₃ perovskite in the pressure range of the Earths lower mantle (0–150 GPa). At zero Kelvin temperature the cubic CaSiO₃ perovskite structure is unstable in the whole pressure range, at low pressures the orthorhombic (Pnam) structure is preferred. At 14.2 GPa there is a phase transition to the tetragonal (I4/mcm) phase. The CaIrO₃-type structure is not stable for CaSiO₃. Our results also rule out the possibility of decomposition into oxides.

Diversity and Habitat Distribution of Birds in Coastal Marshes and Comparisons with Surrounding Upland Habitats in Southeastern South America

We studied variation in bird assemblages with plant associations for three different coastal marshes from Southeastern South America (SESA) and assessed how marsh bird assemblages related to nearby upland bird assemblages. We surveyed bird species and plant structure along the tidal gradient of each locality from the low tide level to the upper habitats bordering coastal marshes. Twenty species frequently used coastal marshes, including relatively few migratory species. We found that birds occurring in SESA coastal marshes do not have distributions constrained to coastal marshes. Nonetheless, four bird assemblages were recognized in association with vegetation types and/or sites. Among the recorded coastal marsh species, the bay-capped wren-spinetail (Spartonoica maluroides) is both the most frequent and the most habitat constrained. Bird richness increases steadily along the tidal gradient associated with the increase in vegetation structure, suggesting that bird richness is directly explained by vegetation and indirectly by the physical conditions influencing vegetation structure. Results highlight the importance of SESA middle marshes as habitat for conservation of some threatened SESA grassland birds.     

The use of proxy chemical records in Coral skeletons to ascertain past environmental conditions in Florida Bay

This paper will discuss the use of chemical proxies in coral skeletons to reconstruct the history of salinity (from the δ¹⁸O of the skeleton) and nutrients in the water (from the δ¹³C) in Florida Bay between 1824 and 1994. Monthly salinity and water temperature data collected since 1989 were used to establish a correlation between salinity, temperature, and the δ¹⁸O of the skeleton of the coralSolenastrea bournoni from Lignumvitae Basin in Florida Bay. This relationship explains over 50% of the variance in the δ¹⁸O of the skeleton. Assuming that interannual variations in the temperature of the water are small, we have applied this relationship to the δ¹⁸O measured in the coral skeleton collected from Lignumvitae Basin which has a record between 1824 and 1993. These data provide a revised estimate of salinity variation in Lignumvitae Basin for the period when historical records for salinity were not available, and show that the highest salinity events occurred in the past 30 yr. Using the relationships between the salinity in Lignumvitate Basin and other basins, obtained using a modern dataset, we are able to estimate ranges in salinity for other portions of Florida Bay. Skeletons of specimens of the coral speciesSiderastrea radians collected from other areas of Florida Bay show similar patterns in the δ¹⁸O over the past 10 yr, indicating that corals in most portions of Florida Bay are recording salinity variations in their skeletons and therefore support the idea that salinity variations in different portions of Florida Bay can be related. Fluorescence analysis of the coral from Lignumvitae Basin shows a large change in the magnitude of the 10-yr signal coincident with the construction of the railway, confirming that this event had a significant impact upon Florida Bay. The δ¹³C of the coral skeletons reveals a long-term history of the oxidation of organic material, fixation of carbon by photosynthesis (algal blooms), and the intrusion of marine water into the bay. Since the construction of the railway from Miami to Key West there has been a long-term decrease in the δ¹³C of the coral skeleton from Lignumvitae Basin, suggesting the increased oxidation of organic material in this area. This decrease in δ¹³C appears to have reached a minimum value around 1984 and has increased since this time in the western portions of Florida Bay. The increase may be related to the algal blooms prevalent in the area or alternatively could result from intrusion of more marine water. In the eastern areas, a small increase in the δ¹⁸C between 1984 and 1988 was followed by further decline suggesting more oxidation of organic material. We have also attempted to use the concentration of barium in the coral skeleton as a proxy indicator of the nutrient status in Florida Bay.     

The clustered nucleation and growth processes of garnet in regional metamorphic rocks from north-west Connecticut,USA

Serial sectioning and imaging with a flatbed scanner yielded the three-dimensional size and spatial distribution of garnet porphyroblasts in two garnet schists and one staurolite-bearing schist from the Everett Formation, north-west Connecticut. The dominant garnet-producing reaction in all samples was chlorite+quartz=garnet+H₂O. The appearance of staurolite, and additional garnet growth in the staurolite-bearing sample, was due to the reaction chloritoid=garnet+staurolite+chlorite. Statistical measures of garnet spatial distributions, using the pair correlation function (PCF), indicate that garnet crystals are weakly to strongly clustered at length scales between 2 and 10 mm. Such clustered nucleation may reflect minor bulk compositional variations. Covariance measures between garnet size and nearest-neighbour distance, using the mark covariance function (MCF), suggest a very weak correlation between crystal size and nearest-neighbour distance for length scales of 2 mm or less. These statistical data suggest that if diffusional gradients were present around growing garnet crystals, they did not influence nucleation and growth patterns at length scales greater than c. 2 mm. Compositional maps, through the garnet centres, show that the smaller crystals have lower Mn core compositions relative to larger crystals, consistent with progressive nucleation during pro-grade metamorphism. Radius-rate plots calculated from compositional X-ray maps show similar growth rates for garnet crystals of different size, consistent with an interface-controlled growth model for garnet. The presence of minor diffusional gradients around growing garnet cannot be entirely dismissed, but the lack of observable reaction rims, the clustered spatial distribution and the radius-rate data are most consistent with an interface-controlled garnet growth model.     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

A meta-analysis of global crop water productivity of three leading world crops (wheat,corn, and rice) in the irrigated areas over three decades

ABSTRACT

The overarching goal of this study was to perform a comprehensive meta-analysis of irrigated agricultural Crop Water Productivity (CWP) of the world’s three leading crops: wheat, corn, and rice based on three decades of remote sensing and non-remote sensing-based studies. Overall, CWP data from 148 crop growing study sites (60 wheat, 43 corn, and 45 rice) spread across the world were gathered from published articles spanning 31 different countries. There was overwhelming evidence of a significant increase in CWP with an increase in latitude for predominately northern hemisphere datasets. For example, corn grown in latitude 40–50° had much higher mean CWP (2.45?kg/m³) compared to mean CWP of corn grown in other latitudes such as 30–40° (1.67?kg/m³) or 20–30° (0.94?kg/m³). The same trend existed for wheat and rice as well. For soils, none of the CWP values, for any of the three crops, were statistically different. However, mean CWP in higher latitudes for the same soil was significantly higher than the mean CWP for the same soil in lower latitudes. This applied for all three crops studied. For wheat, the global CWP categories were low (≤0.75?kg/m³), medium (>0.75 to <1.10?kg/m³), and high CWP (≥1.10?kg/m³). For corn the global CWP categories were low (≤1.25?kg/m³), medium (>1.25 to ≤1.75?kg/m³), and high (>1.75?kg/m³). For rice the global CWP categories were low (≤0.70?kg/m³), medium (>0.70 to ≤1.25?kg/m³), and high (>1.25?kg/m³). USA and China are the only two countries that have consistently high CWP for wheat, corn, and rice. Australia and India have medium CWP for wheat and rice. India’s corn, however, has low CWP. Egypt, Turkey, Netherlands, Mexico, and Israel have high CWP for wheat. Romania, Argentina, and Hungary have high CWP for corn, and Philippines has high CWP for rice. All other countries have either low or medium CWP for all three crops. Based on data in this study, the highest consumers of water for crop production also have the most potential for water savings. These countries are USA, India, and China for wheat; USA, China, and Brazil for corn; India, China, and Pakistan for rice. For example, even just a 10% increase in CWP of wheat grown in India can save 6974 billion liters of water. This is equivalent to creating 6974 lakes each of 100?m³ in volume that leads to many benefits such as acting as ‘water banks’ for lean season, recreation, and numerous ecological services. This study establishes the volume of water that can be saved for each crop in each country when there is an increase in CWP by 10%, 20%, and 30%.