A Late Jurassic fossil assemblage in Gondwana: Biostratigraphy and correlations of the Tacuarembó Formation, Parana Basin, Uruguay

The Tacuarembó Formation has yielded a fossil assemblage that includes the best known body fossils, consisting of isolated scales, teeth, spines, and molds of bones, recovered from thin and patchy bonebeds, from the Botucatu Desert, Parana Basin, South America. The remains are preserved in the sandstones widespread around the city of Tacuarembó. We propose a new formalized nomenclature for the Tacuarembó Formation, naming its “Lower” and “Upper” members as the Batoví (new name) and Rivera (new rank) members, respectively. An assemblage zone is defined for the Batoví Member (fluviolacustrine and aeolian deposits). In this unit, the freshwater hybodontid shark Priohybodus arambourgi D’Erasmo is well represented. This species was previously recorded in Late Jurassic–Early Cretaceous units of the Sahara and the southern Arabian Peninsula. Globally considered, the fossil assemblage of this member (P. arambourgi, dipnoan fishes, Ceratosaurus-like theropods, and conchostracans) is indicative of a Kimmeridgian–Tithonian age, which in combination with the stratigraphic relationships of the Tacuarembó Formation with the overlying basalts of the Arapey Formation (132 My average absolute age) implies that the latter was deposited during the Kimmeridgian–Hauterivian interval.     

Evolution of the Peak Hill high-sulfidation epithermal Au–Cu deposit,eastern Australia

The early Palaeozoic Macquarie Arc, southeastern Australia, hosts a variety of major late Ordovician to earliest Silurian subduction-related deposits (e.g., Cadia East, Ridgeway, Cadia Hill, Cowal and Northparkes). However, there is uncertainty about whether coeval high-sulfidation epithermal deposits, which occur in intra-oceanic metallogenic belts elsewhere in the West Pacific, (e.g., Lepanto and Chinkuashih), are also present in the Macquarie Arc. This has led to suggestions that their absence may be due to the poor preservation potential of deposits that form at relatively shallow crustal levels in ancient rocks. We present here an interpretation for evolution of the Peak Hill Au–Cu deposit based on the distribution of alteration facies, sulfur isotope data from several textural forms of pyrite and barite, and an assessment of the regional volcanic and sedimentary facies architecture. These data show that the Peak Hill deposit displays a distinct sub-vertical zoning with a pyrophyllite and vuggy-quartz core, that today extends about 350 m east–west and at least 550 m north–south, which grades out through paragonite+muscovite, kaolinite to a chlorite+epidote alteration zone at the margin. The alteration zoning reflects both lower temperatures and neutralisation of acid fluids with increasing distance from the core, which represents the conduit along which hot acidic hydrothermal fluids were channelled. Several temporally overlapping events of silicification, bladed-quartz-pyrite veining, brecciation and pyrite veining occurred during the last stages of hydrothermal alteration, although most appear to predate mineralisation. Au–Cu mineralisation was associated with late quartz-pyrite-barite veins, and the highest gold grades occur mainly in microcrystalline-quartz-altered rocks in the paragonite+muscovite alteration zone, generally within 50 m outward from the boundary of the pyrophyllite and vuggy-quartz core. Sulfur- and lead-isotope data, and the characteristic zoning of ore minerals and alteration assemblages support a magmatic source for the hydrothermal fluids. Similarities in many of the isotopic signatures between Peak Hill and deposits such as Northparkes support generation of the high-sulfidation mineralisation during the Late Ordovician to earliest Silurian (possibly ca. 440 Ma) metallogenic event. The Late Ordovician to Early Silurian volcanic and sedimentary facies associations at Peak Hill are consistent with alteration and mineralisation occurring in rocks deposited in a submarine setting.     

On the use of linear stability model to characterize the morphological behaviour of a double bar system. Application to Truc Vert beach (France)

Sandy barred beaches are often characterized by the presence of rhythmic patterns such as crescentic bars. In this article, a linear stability analysis (LSA) model is used to characterize the morphological behaviour of the double bar system of Truc Vert beach. Using a limited number of combinations of representative bathymetries, wave classes and water levels, the morphodynamic response of the system is analysed, focussing on the geometrical characteristics of 3D patterns generated with the model. These characteristics are described and then compared with available observations. The shapes and the wavelengths of the instabilities predicted by the model compare well with field observations. Thus, the use of the linear stability model, with representative hydrodynamic conditions and bathymetries of the considered site, allows a characterization of the global morphodynamic behaviour of a double-barred system.     

The Rio de la Plata craton and the adjoining Pan-African/brasiliano terranes: Their origins and incorporation into south-west Gondwana

The Neoproterozoic to Early Cambrian amalgamation of SW Gondwana through the Brasiliano/Pan-African orogeny is reviewed with emphasis on the role of the Río de la Plata craton of South America in the light of new evidence from a borehole at the eastern end of the Tandilia belt (38°S). U–Pb, Hf and O isotope data on zircon indicate that this un-reworked Palaeoproterozoic craton abuts against a distinct continental terrane to the east (Mar del Plata terrane). The craton is bounded everywhere by transcurrent faults and there is no evidence to relate it to the Neoproterozoic mobile belts now seen on either side. The Punta Mogotes Formation at the bottom of the borehole contains 740–840 Ma detrital zircons that are assigned to a widespread Neoproterozoic rifting event. The data suggest that the Mar del Plata terrane rifted away from the southwestern corner of the Angola block at c. 780 Ma. Negative εHf_t values and δ¹⁸O > 6.5‰ suggest derivation by melting of old crust during a protracted extensional episode. Other continental terranes may have formed in a similar way in Uruguay (Nico Pérez) and southeastern Brazil, where the Schist Belt of the Dom Feliciano orogenic belt is probably a correlative of the Punta Mogotes sequence, implying that the Dom Feliciano belt must extend at least as far as 38°S. A new geodynamic scenario for West Gondwana assembly includes at least two major oblique collisional orogenies: Kaoko–Dom Feliciano (580–680 Ma) and Gariep–Saldania (480–580 Ma), the latter resulting from oblique impingement of the Rio de la Plata craton against the Kalahari craton. Assembly of this part of South-West Gondwana was accomplished before the Ordovician (to Silurian?) siliciclastic platform sediments of the Balcarce Formation in the Tandilia Belt covered the southern sector of Río de la Plata craton.     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Effect of temperature and illumination on pyrite oxidation between pH 2 and 6

The effect of heat and illumination with visible light on the oxidation of pyrite with dissolved molecular oxygen in solutions between pH 2 and 6 has been investigated using a combination of surface science experiments and batch oxidation experiments. The rate of the oxidation of pyrite is strongly dependent on temperature. It is, however, not possible to cast the temperature dependence in a simple Arrhenius equation because the magnitude of the activation energy depends on the progress variable chosen. Activation energies based on proton release rate, sulfate release rate, and total iron release rate vary by as much as 40 kJ mol^-1, suggesting that the oxidation mechanism of the sulfur and iron component of pyrite are largely independent of each other. This difference in mechanism can also explain why the reaction rates on the basis of these three different progress variables do not show the same pH dependence. Exposed to visible light, the rate of pyrite oxidation is under most conditions accelerated by less than a factor of two. Some of this acceleration may be accounted for by a light-induced heating of the pyrite surface. Surface science experiments employing photoelectron spectroscopy show no evidence for significant changes in the chemical composition of the surface as a function of exposure to visible light. The batch sorption experiments show, however, that the reaction stoichiometry changes somewhat, which indicates that there might be a change in reaction mechanism as a result of exposure to visible light.     

3-D crustal-scale gravity model of the San Rafael Block and Payenia volcanic province in Mendoza,Argentina

The San Rafael Block(SRB)is part of one of the main retroarc volcanic provinces in southern Central Andes in Mendoza,Argentina.This block is located in the Andean foothills between the orogenic front and foreland basement uplifts of late Miocene age.In order to analyze the geochronological evolution of the Quaternary volcanism in the region,several geologic and geophysical studies have been conducted.Nevertheless,the crust,where the SRB is located,has not been well characterized yet.Based on gravimetric and magnetic data,together with isostatic and elastic thickness analyses,we modeled the crustal structure of the area.Information obtained has allowed us to understand the crust where the SRB and the Payenia volcanic province are located.Bouguer anomalies indicate that the SRB presents higher densities to the North of Cerro Nevado and Moho calculations suggest depths for this block between 40 and 50 km.Determinations of elastic thickness would indicate that the crust supporting the San Rafael Block presents values of approximately 10 km,being enough to support the block loading.However,in the Payenia region,elastic thickness values are close to zero due to the regional temperature increase.     

Palygorskite as a sediment dispersal tracer in the eastern Mediterranean

Palygorskite is a clay mineral widely distributed in late Quaternary deposits of the eastern Mediterranean, where, locally, it proves an ideal tracer of sediment dispersal. This study shows that the origin of this mineral is not limited to African sources. Cores containing late Pleistocene to recent sediment record the transport of palygorskite from the Plain of Helos on the Peloponnesus to specific deep basins along the Hellenic Arc. Palygorskite, commonly concentrated in the silt size fraction, may be overlooked in studies that focus only on the <2 μm fraction. In this region we find that the detrial palygorskite distribution is partially controlled by size-sorting effects related to gravity-induced transport processes. In consequence, comprehensive compositional analyses should be made both on the silt and clay fractions.