Measurement of stress effects (scope for growth) and contaminant levels in mussels (Mytilus edulis) collected from the Irish Sea

The objective of this research was to quantify the impact of pollution along the coastlines of the Irish Sea. Pollution assessment was based on the combined measurement of scope for growth (SFG), and chemical contaminants in the tissues of mussels (Mytilus edulis) collected from 38 coastal sites around the Irish Sea during June-July in 1996 and 1997. On the UK mainland coast, the SFG showed a general trend with a significant decline in water quality in the Liverpool and Morecambe Bay region. High water quality was recorded along the west coast of Wales, as well as southwest England and northwest Scotland (clean reference sites outside the Irish Sea). Along the coast of Ireland there was a similar trend with reduced SFG within the Irish Sea region. SFG was generally low north of Duncannon and then improved north of Belfast. The poor water quality on both sides of the Irish Sea is consistent with the prevailing hydrodynamics and the spatial distribution of contaminants associated with urban/ industrial development. The decline in SFG of mussels on both sides of the Irish Sea was associated with a general increase in contaminant levels in the mussels. Certain contaminants, including PAHs, TBT, sigmaDDT, Dieldrin, gamma-HCH, PCBs, and a few of the metals (Cd, Se, Ag, Pb), showed elevated concentrations. Many of these contaminants were particularly elevated in the coastal margins of Liverpool Bay, Morecambe Bay and Dublin Bay. A quantitative toxicological interpretation (QTI) of the combined tissue residue chemistry and SFG measurements indicated that at the majority of coastal sites, c. 50 to > 80% of the observed decline in SFG was due to PAHs as a result of fossil fuel combustion and oil spills. TBT levels were highest at major ports and harbours, but these concentrations only made a minor contribution to the overall reduction in SFG. At no sites were individual metals accumulated to concentrations that could cause a significant effect on SFG. The study identified many sites where the observed reduction in SFG was far greater than predicted from the limited number of chemical contaminants analysed, thus indicating the presence of additional 'unknown toxicants'. Sewage (containing domestic, agricultural and industrial components) appears to be an important contributor to reduced SFG and linear alkylbenzenes (LABs) and As may provide suitable 'sewage markers'. There was a highly significant positive correlation between SFG and As (P < 0.001). This relationship may be due to reduced As uptake by algal food material and mussels at sites with elevated P04 concentrations (e.g. at sites with sewage inputs). Phosphate is a known competitive inhibitor of As accumulation, at least in algae. The results highlight that further research is required on 'sewage markers' in mussels. The SFG approach therefore provides a rapid, cost-effective and quantitative measure of pollution impact, as well as a means of identifying the causes through a QTI of tissue contaminants levels. It also serves to identify the presence of unidentified toxicants and areas that require further study.     

Anthropogenic relief changes in a long-lasting lignite mining area (‘Ville’, Germany) derived from historic maps and digital elevation models

Humans constitute one of the main geomorphological agents in modern times. As an example, post-mining regions represent a typical landscape of the Anthropocene. Strong relief modifications are particularly obvious with open pit mining. However, many existing mining areas are lacking detailed pre-mining information for the quantification of anthropogenic relief changes, which is a considerable challenge in regions with historic mining activities. Here, the Ville (Rhenish lignite district, Germany) is used to quantify surface mining induced relief changes in one of the oldest and currently largest lignite districts in Europe. Historical maps from first geodetic mapping in 1893 enabled construction of a historic digital elevation model to quantify the relief changes in comparison to elevation data from 2000 and 2015. The vertical accuracy of the historic data is remarkably high, with relief differences < 2 m in areas not affected by mining. In total, 49.2% of the investigated area (184 km²) shows a relief deficit and 14.5% has positive relief differences. Absolute changes account for more than 80 m heightening (dumpsites of overburden) and lowering of the natural relief (pits). Besides these altitudinal changes, overall steeper slopes are significant for the new topography, but levelling exists likewise. The spatial variabilities are discussed in the context of the regional geology and the mining techniques. Undoubtedly, such large-scale anthropogenic relief changes persist for a very long time and will last as a human legacy far into the future. Only the detailed reconstruction of the pre-mining relief offers the ability to clarify the dimension of humans as geomorphological agents and to understand landscape perception. Due to the fact that the impact of open pit mining has such a large vertical and horizontal extension, their consideration as part of anthropogeomorphology can significantly contribute to support future Critical Zone research in the Anthropocene.     

Distribution of Indus born mica along Gulf of Kachchh coast: Implications in understanding current dynamics

Indus is one of the major sources of sediments to the Gulf of Kachchh. Yet only its <63 micron fraction is studied in detail with regards to the offshore current dynamics. Hence here we present our study on characteristic signature of the Indus sediment load (i.e. mica minerals) in >63 micron size fraction along the coast of Gulf of Kachchh. The spatial distribution of mica minerals along the Gulf of Kachchh coast was studied which showed in general decreasing trend as we move along the northern and southern coast of the Gulf of Kachchh but, an increase in amount near the southern mouth at Okha. The study shows that the earlier proposed tidal barrier is ineffective in restricting movement of mica across the mouth of the gulf due to its characteristic transport mechanism. Also the presence of mudflats along the gulf of Kachchh coast plays a vital role as sediment receptors in the active sediment transport processes and mica minerals prove to be a promising simple tracer in studying the Indus born sediments in the region.     

Estimating coseismic deformations from near source strong motion records: methods and case studies

Digital strong-motion accelerographs have opened up the possibility of extracting ground motion characteristics at much lower frequencies than was offered by analogue instruments. High-quality digital data obtained close to the faults have tempted several efforts to retrieve permanent ground displacements after an earthquake. Such attempts have been partly successful, and somewhat subjective, the main reason being the presence of baseline offsets in the accelerometric data. We review existing methods for such applications, discuss their limitations and propose a more objective and improved scheme to make baseline adjustments and obtain permanent displacements. The proposed technique is applied to 26 digital recordings from the 29 May 2008 Ölfus Earthquake in South Iceland and 9 recordings from the 1999 Chi-Chi, Taiwan, Earthquake, and the permanent displacements obtained are compared with published results and GPS measurements from nearby stations. Our case studies show that the proposed technique, in addition to being simple and objective, is effective in making adjustments for baseline errors in accelerometric data.     

Late Quaternary paleoclimate of western Alaska inferred from fossil chironomids and its relation to vegetation histories

Fossil Chironomidae assemblages (with a few Chaoboridae and Ceratopogonidae) from Zagoskin and Burial Lakes in western Alaska provide quantitative reconstructions of mean July air temperatures for periods of the late-middle Wisconsin (～39,000–34,000 cal yr B.P.) to the present. Inferred temperatures are compared with previously analyzed pollen data from each site summarized here by indirect ordination. Paleotemperature trends reveal substantial differences in the timing of climatic warming following the late Wisconsin at each site, although chronological uncertainty exists. Zagoskin Lake shows early warming beginning at about 21,000 cal yr B.P., whereas warming at Burial Lake begins ～4000 years later. Summer climates during the last glacial maximum (LGM) were on average ～3.5 °C below the modern temperatures at each site. Major shifts in vegetation occurred from ～19,000 to 10,000 cal yr B.P. at Zagoskin Lake and from ～17,000 to 10,000 cal yr B.P. at Burial Lake. Vegetation shifts followed climatic warming, when temperatures neared modern values. Both sites provide evidence of an early postglacial thermal maximum at ～12,300 cal yr B.P. These chironomid records, combined with other insect-based climatic reconstructions from Beringia, indicate that during the LGM: (1) greater continentality likely influenced regions adjacent to the Bering Land Bridge and (2) summer climates were, at times, not dominated by severe cold.     

Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Mesoscale and macroscale aspects of the morning Urban Heat Island around Athens,Greece

Summary This paper examines the characteristics of the morning Urban Heat Island (UHI) in Athens basin, Greece. The study is performed by using and analyzing mesoscale and synoptic data covering the period 1990–2001. The UHI was estimated using the 0600 Local Time (LT) minimum temperature differences between rural and urban areas of the city. The analysis results in 7 UHI classes. A strong UHI was found for the 1/3 of days. The specific meteorological characteristics (surface and upper air, cooling rate) of each UHI class were revealed and examined. The spatial and temporal characteristics of the UHI were also identified. The UHI is largest on nights with clear skies and low relative humidity. In all seasons the UHI switches on rapidly in afternoon. During spring and summer, sea breeze commonly reduces and delays the UHI. Cases documenting the sensitivity and rapidity of changes of the UHI to changes in classes (cloud cover, wind) are also presented. The cooling rate is higher in the urban area under negative and lower under positive UHI conditions. Mesoscale and macroscale phenomena were examined during the different UHI classes through a weather type scheme. It was emerged that high UHI classes are associated with anticyclonic conditions or advection in the lower troposphere, while low UHI classes are associated with strong northeasterly winds. Anticyclonic conditions which frequently occur in spring and early summer, reduce or reverse the UHI to Urban Cooling Island.     

Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.