Review: The Yucat��n Peninsula karst aquifer, Mexico

The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000? km² in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located in the vicinity of the North American/Caribbean plate boundary and has been reshaped by a series of tectonic events over its long geologic history. At the end of the Cretaceous period, the Yucatán Peninsula was hit by a large asteroid, which formed the Chicxulub impact crater. The Yucatán Peninsula karst aquifer hosts large amounts of groundwater resources which maintain highly diverse groundwater-dependent ecosystems. Large parts of the aquifer are affected by seawater intrusion. Anthropogenic pollution of the aquifer has been increasing over the past few decades, owing to relentless economic development and population growth on the Peninsula. This review summarizes the state of knowledge on the Yucatán Peninsula karst aquifer and outlines the main challenges for hydrologic research and practical groundwater-resources management on the Peninsula.     

Late Devonian OIB alkaline gabbro in the Yarlung Zangbo Suture Zone: Remnants of the Paleo-Tethys?

The Yarlung Zangbo Suture Zone (YZSZ) is believed to be composed of material largely derived from the destruction of the Neo-Tethys that occurred from early Mesozoic to early Cenozoic. We report here geochronological and petrological data obtained for newly discovered alkaline gabbro blocks embedded in a mélange zone of the western YZSZ. Single zircon U–Pb analyses from one representative gabbro sample by SIMS (Secondary Ion Mass Spectrometry) yielded a combined crystallization age of about 363.7 ± 1.7 Ma (1σ). In situ Hf isotopic analyses yielded ε_Hf(t) values of + 2.6 to + 5.5, suggesting an enriched mantle source. All of the gabbro samples show typical Ocean Island Basalt (OIB) affinity with little or no continental crust contamination. They also display strong geochemical similarities with the Hawaii basalts and the Xigaze seamount basalts suggestive of their intra-oceanic setting. These observations, in combination with the Early Carboniferous layered gabbros reported at Luobusa, indicate that these rocks could represent remnants of the Paleo-Tethys. We propose that a branch ocean separating the Western Qiangtang terrane and the Lhasa terrane from the Gondwana continent might have been present during the Late Devonian and the Early Carboniferous, providing new constrains on the configuration of Paleo-Tethys in Tibetan Plateau during early Late Paleozoic.     

Tracing sediment redistribution across a break in slope using rare earth elements

Experimentally determined spatial patterns of soil redistribution across a break in slope derived using 10 rare earth element (REE) oxides as sediment tracers are presented. An erosion experiment was conducted using simulated rainfall within a laboratory slope model measuring 2·5 m wide by 6 m long with a gradient of 15° declining to 2°. Soil was tagged with multiple REE and placed in different locations over the slope and at the end of the experiment REE concentrations were measured in samples collected spatially. A new method was developed to quantify the erosion and deposition depths spatially, the relative source contributions to deposited sediment and the sediment transport distances. Particle‐size selectivity over an area of net deposition was also investigated, by combining downslope changes in particle‐size distributions with changes in sediment REE composition within a flow pathway. During the experiment, the surface morphology evolved through upslope propagation of rill headcuts, which gradually incised the different REE‐tagged zones and led to sediment deposition at the break in slope and the development of a fan extending over the shallow slope segment. The spatial patterns in REE concentrations, the derived erosion and deposition depths, the relative source contributions to deposition zones and the sediment transport distances, corroborate the morphological observations and demonstrate the potential of using REE for quantifying sediment transport processes. Copyright © 2010 John Wiley & Sons, Ltd.     

Runoff and water erosion modelling using WEPP on a Mediterranean cultivated catchment

Soil erosion due to water is a major environmental problem in many parts of the world. Most of Mediterranean countries are concerned because of their specific climate and soils sensitivity, but also because of the recent intensification of human activities and agricultural practices. Accurate estimation of soil water erosion for various land-use and climate scenarios is so an important key to define sustainable management policies. In the last decades, several studies have been carried out to build models suitable for quantifying soil erosion. Among these models, the Water Erosion Prediction Project (WEPP, Flanagan, D.C., Nearing, M.A., 1995. USDA-Water Erosion Prediction Project: Hillslope profile and watershed model documentation. NSERL Report 10, USDA-ARS National Soil Erosion Research Laboratory, West Lafayette, IN, USA.) is a physically based, distributed-parameter model that has been developed and mainly validated in USA. Only few studies have investigated its applicability to environmental conditions that differs from those where the model was developed. The aim of this work is to test the efficiency of WEPP model to predict soil erosion at catchment scale in a Mediterranean semi-arid area. Continuous simulations have been conducted between 1995 and 2002 on an cultivated experimental catchment located upstream from a hill reservoir (Kamech catchment, 2.45 km², Cap Bon, Tunisia) where runoff and soil erosion measurements are available at the outlet. Comparison between predictions and measurements shows significant differences. Processes related to seasonal effects (as cracking soils) are pointed out as a weakness of WEPP model for Mediterranean conditions.     

Indirect unstructured hex-dominant mesh generation using tetrahedra recombination

Corner-point gridding is widely used in reservoir and basin modeling but generally yields approximations in the representation of geological interfaces. This paper introduces an indirect method to generate a hex-dominant mesh conformal to 3D geological surfaces and well paths suitable for finite-element and control-volume finite-element simulations. By indirect, we mean that the method first generates an unstructured tetrahedral mesh whose tetrahedra are then merged into primitives (hexahedra, prisms, and pyramids). More specifically, we focus on determining the optimal set of primitives that can be recombined from a given tetrahedral mesh. First, we detect in the tetrahedral mesh all the feasible volumetric primitives using a pattern-matching algorithm (Meshkat and Talmor Int. J. Numer. Meth. Eng. 49(1-2), 17–30 2000) that we re-visit and extend with configurations that account for degenerated tetrahedra (slivers). Then, we observe that selecting the optimal set of primitives among the feasible ones can be formalized as a maximum weighted independent set problem (Bomze et al. 1999), known to be \(\mathcal {N}\mathcal {P}\)-Complete. We propose several heuristic optimizations to find a reasonable set of primitives in a practical time. All the tetrahedra of each selected primitive are then merged to build the final unstructured hex-dominant mesh. This method is demonstrated on 3D geological models including a faulted and folded model and a discrete fracture network.     

Mobility of metals in nickel mine spoil materials

An understanding of the biogeochemical behaviour of metals in mine spoil materials is a prerequisite to rehabilitate Ni mining sites. The objective of this study was to characterize the fate of metals in different Ni ore spoil materials as influenced by hydrological conditions and fertilisation practices. In tropical ultramafic complexes, the different stages of lateritic weathering lead to two types of ores, and therefore, to two spoil types. They are mainly either a clay-rich saprolite, so-called “garnierite”, enriched in phyllosilicates, or a limonitic material, enriched in Fe oxides. Lysimeter columns were designed to monitor leaching waters through both spoil materials. The garnieritic spoil released higher concentrations of Mg (mean = 2.25 mg L⁻¹), Ni (0.39 mg L⁻¹) and Cr (1.19 mg L⁻¹) than the limonitic spoil (Mg = 0.5 mg L⁻¹; Ni = 0.03 mg L⁻¹ and Cr = 0.25 mg L⁻¹). Chromium was mainly in an anionic form in leaching solutions. As exchangeable pools of Cr(VI) in limonite (980 mg kg⁻¹ of KH₂PO₄-extractable Cr) are considerable its release in water may still occur in the case of a pH increase. In mixed spoil, metal concentrations were almost as low as in the limonitic one. The effect of mineral-N fertilisation was a strong release of cations (Ni, Mg) into the leachate. Phosphate amendment did not affect the soil solution composition under experimental conditions.