Zircon texture and chemical composition as a guide to magmatic processes and mixing in a granitic environment and coeval volcanic system

This study documents the chemical and textural responses of zircon in the Elba igneous complex, with particular reference to the 7- to 7.8-Ma-old Monte Capanne pluton in relation to its coeval volcanic counterpart (Capraia), using BSE imaging and quantitative electron microprobe analyses. The Monte Capanne pluton displays multiple field and geochemical evidence for magma mixing. The samples we have investigated (including monzogranitic, mafic enclave and dyke samples) display similar zircon textures and are associated with an extremely large range of trace and minor element (Hf, Y, HREE, Th, U) compositions, which contrast with relatively simple textures and zoning patterns in zircons from a Capraia dacite. We have used a relatively simple textural classification (patchy zoning, homogenous cores, oscillatory zoning and unzoned zircon) as the basis for discussing the chemical composition and chemical variation within zircons from the Monte Capanne pluton. Based on these data and other works (Dini et al. 2004 in Lithos 78:101–118, 2004) , it is inferred that mixing between metaluminous and peraluminous melts occurred early in the evolution of the Monte Capanne magma chamber. In particular, mixing was responsible for the development of the patchy-zoning texture in the zircon cores, which was associated with reactions between other accessory phases (including monazite, apatite, allanite), which we infer to have significantly affected the Th distribution in zircon. Zircons from the MC pluton displaying “homogeneous cores” have chemical affinities with zircons in the coeval Capraia volcanic system, consistent with the participation of a Capraia-like mantle end-member during mixing. Further zircon growth in the MC pluton produced the oscillatory zoning texture, which records both long-term (crystal fractionation) and transient (recharge with both silicic and mafic magmas) events in a hybrid magma chamber. It is inferred that Hf and the Th/U ratio cannot be used alone to infer magmatic processes due to their dependency on temperature, nor are they a diagnostic feature of xenocrystic grains. This study shows that zircon chemistry coupled with detailed textural analysis can provide a powerful tool to elucidate the complex evolution of a magma system.     

Electrochemical gold precipitation to explain extensive vertical and lateral mineralization in the world‐class Poderosa‐Pataz district,Peru

The world‐class Poderosa‐Pataz district is famous for its gold endowment in vertically and laterally extensive quartz‐sulphide veins. Precipitating mechanisms are investigated to determine why gold is so laterally and vertically distributed. Micro‐XRF and LA‐ICP‐MS element mapping of pyrites surrounding gold grains reveals systematic enrichment of As around or near visible gold accumulations. These As‐enriched zones define discordant rims and corridors overprinting pyrites. LA‐ICP‐MS spot analyses performed within and outside the As enrichment zones indicate that As is enriched on average by two orders of magnitude in association with gold. Secondary pyrite transformation by hydrothermal fluids with elevated As‐Au induced a change in the semiconducting properties of pyrite grains, resulting in the precipitation of visible gold particles at the interfaces of As‐enriched zones. The electrochemical precipitation mechanism acted as a filter to extract gold in solution regardless of variations in pressure and temperature, hence explaining the vertically and laterally extensive gold mineralization.     

Structural control of sinkholes and subsidence hazards along the Jordanian Dead Sea coast

For about four decades, the Dead Sea (DS) level and the surrounding water table has been dropping dramatically. At least from the eighties, the direct vicinity of the Lisan Peninsula (LP), Jordan, has been facing high rates of subsidence and sinkhole hazards. Between 2000 and 2002, the Arab Potash Company (APC) lost two salt evaporation ponds resulting in a loss of $70 million. In the fertile plain of Ghor al Haditha (GAH), three deep and wide bowl-shaped subsidence areas threaten human activities and infrastructures. Over the part of the Lisan Peninsula that emerged before the 1960s, relict fossil sinkholes occurred everywhere, whereas new collapses constantly appear in the southern area only. In this paper, we have integrated 15 years of field observations related to sinkholes and subsidence with interpretation of space borne radar interferometric outputs, aerial photographs and satellite images. This has helped to place hazardous areas in their geological context and to clarify them within the framework of the general tectonic setting of the area.     

The impact and rotational light curves of Comet 9P/Tempel 1

UVES and HIRES high-resolution spectra of Comet 9P/Tempel 1 are used to investigate the impact and rotational light curves of various species with a view toward building a simple model of the distribution and activity of the sources. The emission by OH, NH, CN, C₃, CH, C₂, NH₂, and OI, are analyzed, as well as the light scattered by the dust. It is found that a simple model reproduces fairly well the impact light curves of all species combining the production of the observed molecules and the expansion of the material throughout the slit. The impact light curves are consistent with velocities of 400-600 m/s. Their modeling requires a three-step dissociation sequence “Grand-Parent → Parent → Daughter” to produce the observed molecules. The rotational light curve for each species is explained in terms of a single model with three sources. The dust component can however not easily be explained that way.     

Holocene fire regime changes from multiple-site sedimentary charcoal analyses in the Lourdes basin (Pyrenees,France)

One lake and three peat bogs from the Lourdes glacial basin (France) were used for macrocharcoal analyses and fire frequency reconstruction over the entire Holocene (11700 years). The chronology was based upon thirty-three 14C AMS dates. Comparison of the distribution of both CHarcoal Accumulation Rate (CHAR) and fire return intervals showed that charcoal accumulation significantly differs between the lake and the peat bogs, but that frequency calculation overcomes the disparity between these site types. A composite frequency was built from the four individual records to assess regional versus local variability and fire regime controls by comparisons with regional fire activity, Holocene climatic oscillations and vegetation history. The millennial variability can be depicted as follows: relatively high frequency between 8000 and 5000 cal a BP (up to 5 fires/500 yrs), relatively low frequency between 5000 and 3000 cal a BP (down to 0 fires/500 yrs), and an increase between 3000 and 500 cal a BP (up to 4 fires/500 yrs). From 8000 to 5000 cal a BP, fire frequency displays strong synchrony between sites and appears to be mostly driven by increased summer temperature characterizing the Holocene Thermal Maximum (HTM). On the contrary, during the last 3000 years fire frequency was heterogeneous between sites and most probably human-driven. However, higher frequency at the millennial scale during the mid-Holocene strongly suggests that the perception of human-driven fire regime depends on the strength of natural controls.     

Tracking past mining activity using trace metals,lead isotopes and compositional data analysis of a sediment core from Longemer Lake,Vosges Mountains,France

A 157-cm-long sediment core from Longemer Lake in the Vosges Mountains of France spans the past two millennia and was analyzed for trace metal content and lead isotope composition. Trace metal accumulation rates highlight three main input phases: Roman Times (cal. 100 BC–AD 400), the Middle Ages (cal. AD 1000–1500), and the twentieth century. Atmospheric contamination displays a pattern that is similar to that seen in peat bogs from the region, at least until the eighteenth century. Thereafter, the lake sediment record is more precise than peat records. Some regional mining activity, such as that in archaeologically identified eighteenth-century mining districts, was detected from the lead isotope composition of sediment samples. Compositional data analysis, using six trace metals (silver, arsenic, cadmium, copper, lead and zinc), enabled us to distinguish between background conditions, periods of mining, and of other anthropogenic trace metal emissions, such as the recent use of leaded gasoline.     

Interpretation of dilatometer tests in a heavy oil reservoir

This paper presents a prospective study for identifying selected parameters of the modified Cam‐Clay model representing the behaviour of heavy oil reservoirs. The first part shows that the plastic compressibility, which controls the main recovery mechanism of such reservoirs, can be accurately determined, simultaneously with other parameters, by an inverse analysis of pressure–strain curves. The conditions of the identification procedure mainly involve two tests conducted under different drainage conditions or at different strain rates. The numerical study also establishes the sequence of an original in situ experimental program, in which three dilatometer tests at a relatively great depth (several hundreds of metres) were carried out. The comparison of the experimental data with the numerical computations reveals a significant over‐consolidation ratio which does not allow the plastic compressibility to be determined but supports the findings regarding the geological erosion of the site. Copyright © 2006 John Wiley & Sons, Ltd.     

Human-induced geological hazards along the Dead Sea coast

The Dead Sea is a terminal lake whose level is currently dropping at a rate of about 1 m per year due to the over exploitation of all its tributaries. The lowering started about four decades ago but geological hazards appeared more and more frequently from the end of the 1980s. The water level lowering is matched by a parallel groundwater level drop, which results in an increasing intensity of underground and surface water flow. The diagonal interface between the Dead Sea brine and the fresh groundwater is pushed downwards and seawards. Nowadays, sinkholes, subsidence, landslides and reactivated salt-karsts affect wide coastal segments. Until now, mainly infrastructures were damaged and few people/animals were injured, but the ongoing development of tourism in this very attractive situation will increase the risk if precautionary measures are not included in the development plans. This paper discusses the main observations made all around the Dead Sea and shed a light on the differences between the geological hazards of the western shore (Israel, Palestinian Authority) and the eastern shore (Jordan). It is the first attempt to bring together an overview of the human-induced geological hazards encountered along the Dead Sea coast.     

Fe‐Mg interdiffusion profiles in rimmed forsterite grains in the Allende matrix: Time–temperature constraints for the parent body metamorphism

The Allende matrix is dominated by micron‐sized lath‐shaped fayalitic olivine grains with a narrow compositional range (Fa_40–50). Fayalitic olivines also occur as rims around forsterite grains in chondrules and isolated forsterite fragments in the matrix or as veins cross‐cutting the grains. Allende is a type 3 CV carbonaceous chondrite having experienced a moderate thermal metamorphism. There is therefore a strong chemical disequilibrium between the large forsterite grains and the fayalite‐rich fine‐grained matrix. Chemical gradients at interfaces are poorly developed and thus not accessible using conventional techniques. Here, we used analytical transmission electron microscopy to study the microstructure of the fayalite‐rich matrix grains and interfaces with forsterite fragments. We confirm that fayalitic grains in the matrix and fayalitic rims around forsterite fragments have the same properties, suggesting a common origin after the accretion of the parent body of Allende. Composition profiles at the rim/forsterite interfaces exhibit a plateau in the rim (typically Fa₄₅), a compositional jump of 10 Fa% at the interface, and a concentration gradient in the forsterite grain. Whatever the studied forsterite grain or whatever the nature of the interface, the Fe‐Mg profiles in forsterite grains have the same length of about 1.5 μm. This strongly suggests that the composition profiles were formed by solid‐state diffusion during the thermal metamorphism episode. Time–temperature couples associated with the diffusion process during thermal metamorphism are deduced from profile modeling. Considering the uncertainties on the diffusion coefficient value, we found that the peak temperature in Allende is ranging from 425 to 505 °C.     

Soil and bedrock distribution estimated from gully form and frequency: A GIS-based decision-tree model for Lebanon

Torrential rainfall and relatively sparse vegetation in the Mediterranean region result in the development of gully systems and land degradation, notably on lands with specific types of soil and bedrock. This paper proposes a decision-tree model to predict the distribution of soil and bedrock susceptible to gully erosion (white Rendzinas and marly rocks) from the form and frequency of gullies. The study area is located in Lebanon and the model is linked to GIS. V-fold cross-validation of the pruned model indicates that gully features including cross-section size and shape, network frequency, types of meandering, and catchment area can explain 80% of variance in soil/rock properties. The overall accuracy of the soil/rock map was estimated to be ca. 87%. The proposed model is relatively simple, and may also be applied to other areas. It is particularly useful when information about soil and rock obtained from conventional field surveys is limited.