A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance

This report describes a new form of arsenian pyrite, called As³⁺-pyrite, in which As substitutes for Fe [(Fe,As)S₂], in contrast to the more common form of arsenian pyrite, As¹⁻-pyrite, in which As¹⁻ substitutes for S [Fe(As,S)₂]. As³⁺-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As³⁺-pyrite confirm that As is present largely as As³⁺. EMPA analyses show that As³⁺-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As³⁺ in the pyrite could be written like: As³⁺+yAu⁺+1-y(□)⇔2Fe²⁺; where Au⁺ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As³⁺-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As³⁺-pyrite on As-free pyrite. Overgrowths of As³⁺-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As³⁺-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As³⁺; in contrast, reducing conditions are typical of most environments that host As¹⁻-pyrite. As³⁺-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As³⁺ and toxic heavy metals in oxidizing natural systems.     

Groundwater Discharge as a Source of Dissolved Carbon and Greenhouse Gases in a Subtropical Estuary

Groundwater may be highly enriched in dissolved carbon species, but its role as a source of carbon to coastal waters is still poorly constrained. Exports of deep and shallow groundwater-derived dissolved carbon species from a small subtropical estuary (Korogoro Creek, Australia, latitude ?31.0478°, longitude 153.0649°) were quantified using a radium isotope mass balance model (²³³Ra and ²²⁴Ra, natural groundwater tracers) under two hydrological conditions. In addition, air-water exchange of carbon dioxide and methane in the estuary was estimated. The highest carbon inputs to the estuary were from deep fresh groundwater in the wet season. Most of the dissolved carbon delivered by groundwater and exported from the estuary to the coastal ocean was in the form of dissolved inorganic carbon (DIC; 687 mmol m^?2 estuary day^?1; 20 mmol m^?2 catchment day^?1, respectively), with a large export of alkalinity (23 mmol m^?2 catchment day^?1). Average water to air flux of CO₂ (869 mmol m^?2 day^?1) and CH₄ (26 mmol m^?2 day^?1) were 5- and 43-fold higher, respectively, than the average global evasion in estuaries due to the large input of CO₂- and CH₄-enriched groundwater. The groundwater discharge contribution to carbon exports from the estuary for DIC, dissolved organic carbon (DOC), alkalinity, CO₂, and CH₄ was 22, 41, 3, 75, and 100 %, respectively. The results show that CO₂ and CH₄ evasion rates from small subtropical estuaries surrounded by wetlands can be extremely high and that groundwater discharge had a major role in carbon export and evasion from the estuary and therefore should be accounted for in coastal carbon budgets.     

Das Gebiet des Yangtze-Deltas mit den Nanking-Bergen

Ohne Zusammenfassung     

The Tamayo transform fault in the mouth of the Gulf of California

The Tamayo transform fault is located at the north end of the East Pacific Rise where it enters the Gulf of California. This paper presents bathymetric, seismic reflection, magnetic, and gravity data from a detailed survey of the transform fault. The dominant feature of the offset region is a bathymetric ridge trending 120°, parallel to the predicted transform plate boundary. This transform ridge is associated with a large (600 ) positive magnetic anomaly, and a very small positive free-air gravity anomaly. Magnetic and gravity models indicate either a basalt or serpentinite composition for the ridge, but cannot distinguish between these possibilities. At its eastern end, the modern zone of strike-slip motion is in a narrow valley south of the transform ridge. The transform plate margin appears to pass through a saddle in the transform ridge and meet the western spreading center segment in the trough north of the transform ridge. On the basis of this survey and previous work, the history of the Tamayo from continental breakup to the present has been reconstructed. Initial rifting occurred along a trend of 130° at approximately 3.5 m.y.b.p. Once the transform fault was free of the constraints imposed by continent-continent and continent-oceanic lithospheric interaction, the trend of the transform fault rotated counter-clockwise. This rotation resulted in a leaky transform fault and intrusion of a large continuous transform ridge. Further adjustments in the spreading center/transform fault plate boundary configuration have given rise to an incipient zone of rifting cutting across the transform ridge and emplacement of diapiric structures.Contribution of the Scripps Institution of Oceanography, new series.     

Volcanic stratigraphy of DSDP/ODP Hole 395A: An interpretation using well-logging data

Deep Sea Drilling Project/Ocean Drilling Program Hole 395A was drilled approximately 500 m deep into young oceanic crust west of the Mid-Atlantic Ridge. Core recovery is very poor in this hole and therefore continuous downhole measurements are important to understand the drilled lithology. Geophysical downhole measurements were carried out during several cruises. A new set of logs was recorded during Leg 174B in summer 1997. The new logging data show a significant improvement in data quality compared to older measurements from Leg 109. The lithostratigraphy established from cores gives only limited information because of the poor core recovery in this hole. The gaps in the core lithostratigraphy are filled by reconstructing a synthetic lithological profile using the standard well-logging data. Three types of lava morphologies, massive basalts, altered lava flows, and pillow basalts, may be distinguished using the logs because the lava morphologies show differences in their physical properties due to differences in fracturing and alteration. The synthetic lithological profile gives a more detailed and precise vertical definition of single layers than the core profile. The integration of further logging and core data enables a detailed reconstruction of the accretion history at the drill site. Cyclic, upward decreasing trends in the resistivity logs were already observed during earlier cruises and were referred to magmatic cycles. Similar trends occur in the density log and, inversely, in the total gamma ray log. The trends reflect gradual changes in fracturing, porosity, permeability, and alteration and cover depth intervals of several tens of meters. Boundaries between cycles are interpreted to correspond to periods of volcanic quiescence. Two types of boundaries may be identified. Boundaries correlating with reversals in the magnetic field and/or changes in the geochemical composition of the basalts are interpreted as long pauses. Basalts separated by these boundaries were probably fed by separate magma reservoirs. Boundaries identified only by changes in alteration but not in geochemistry are interpreted to represent shorter pauses. They separate basalts that were probably fed by the same magma chamber. This revised version was published online in November 2006 with corrections to the Cover Date.     

The contact binary AE phoenicis — An analysis from deconvoluted spectra

A method is described for an analysis of deconvoluted stellar spectra, and applied to new spectroscopic observations of the close eclipsing system AE Phuenicis, obtained with the 1.52 m telescope of the Southern European Observatory at La Silla, Chile, Results are presented for the rotational velocities of this variable, together with a proposed model of the system.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia, 3–7 June, 1983.     

The Wide Field Spectrograph (WiFeS)

This paper describes the Wide Field Spectrograph (WiFeS) under construction at the Research School of Astronomy and Astrophysics (RSAA) of the Australian National University (ANU) for the ANU 2.3 m telescope at the Siding Spring Observatory. WiFeS is a powerful integral field, double-beam, concentric, image-slicing spectrograph designed to deliver excellent throughput, wavelength stability, spectrophotometric performance and superb image quality along with wide spectral coverage throughout the 320–950 nm wavelength region. It provides a 25×38 arcsec field with 0.5 arcsec sampling along each of twenty five 38×1 arcsec slitlets. The output format is optimized to match the 4096×4096 pixel CCD detectors in each of two cameras individually optimized for the blue and the red ends of the spectrum, respectively. A process of “interleaved nod-and-shuffle” will be applied to permit quantum noise-limited sky subtraction. Using VPH gratings, spectral resolutions of 3000 and 7000 are provided. The full spectral range is covered in a single exposure at R=3000, and in two exposures in the R=7000 mode. The use of transmissive coated optics, VPH gratings and optimized mirror coatings ensures a throughput (including telescope atmosphere and detector) >30% over a wide spectral range. The concentric image-slicer design ensures an excellent and uniform image quality across the full field. To maximize scientific return, the whole instrument is configured for remote observing, pipeline data reduction, and the accumulation of calibration image libraries.