Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System

The Lippmann diagram for the system(Ba, Sr)SO₄-H₂O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO₄ due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO₄) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa²⁺ = 0.000446 ) at the peritectic point.     

Emplacement of the Ardara pluton (Ireland): new constraints from magnetic fabrics, rock fabrics and age dating

The Ardara pluton as part of the Donegal batholith was intruded into Neoproterozoic metasediments and metadolerites at mid-crustal levels. The emplacement mechanism of the Ardara granite is very controversial, and mechanisms ranging from diapirism, ballooning and stoping followed by nested diapirism have been proposed. Magnetic fabrics, rock fabrics and K/Ar dating of micas are used here to constrain the emplacement history. The compositional zoning of the Ardara pluton is clearly reflected in the different bulk magnetic susceptibilities between the outer quartz monzodiorite and the central granodiorite, whereas the intervening tonalite is of intermediate nature. The magnetic carriers are characterized by the anisotropy of the magnetic susceptibility (AMS), thermomagnetic measurements and through high field analyses (HFA). The separation of the ferrimagnetic and paramagnetic contributions revealed that biotite and magnetite control the AMS in the quartz monzodiorite. Both minerals are oriented in such a way that their summed contribution is constructive and originates from the shape fabric of magnetite and the texture of biotite. Biotite is responsible mainly for the AMS in the tonalite and granodiorite. The magnetic foliation can be directly related to the macroscopic foliation and also to the D4 structures in the country rocks. The foliation is consistent with the geometry of the roughly circular shape and has a mostly steep to vertical dip. Towards the central granodiorite the magnetic foliation dies out, although plagioclase texture measurements indicate a weak magmatic shape fabric. With the exception of the tail, the K_max axes (magnetic lineation) vary from steeply to gently plunging. The so-called lineation factor is approximately 1.01 and therefore points to a less significant axial symmetry. These observations coincide with strain estimates on mafic enclaves that show a very consistent pattern of K ∼0 flattening strain. Texture analyses of biotite and quartz additionally support the observations made by the strain analyses and the magnetic fabric data. Microstructural investigations give evidence that the fabrics are associated with the emplacement over a range of temperatures from truly magmatic to high-temperature solid-state conditions. The age of the intrusion is still under discussion, but a new cooling age was determined by K/Ar dating of biotite at 403.7±8 Ma corresponding to a temperature range between 450 and 300°C. For a mylonite along the southern contact between the Ardara pluton and the country rock a K/Ar muscovite age of 378.8±7 Ma indicates a minimum age for the shear zone when the Ardara pluton must have already been cooled down below 350±50°C. Received: 28 January 1999 / Accepted: 28 December 1999     

Correction to: Projection of Iron Ore Production

Natural Resources Research - The original version of this article unfortunately contained an error in Equation 3.     

New variable stars from the photographic archive: semi-automated discoveries,attempts at automatic classification and the new field 104 Her

Using 172 plates taken with the 40-cm astrograph of the Sternberg Astronomical Institute(Lomonosov Moscow University) in 1976–1994 and digitized with a resolution of 2400 dpi, we discovered and studied 275 new variable stars. We present the list of our new variables with all necessary information concerning their brightness variations. As in our earlier studies, the new discoveries show a rather large number of high-amplitude Delta Scuti variables, predicting that many stars of this type remain not detected in the whole sky. We also performed automated classification of the newly discovered variable stars based on the Random Forest algorithm. The results of the automated classification were compared to traditional classification and showed that automated classification was possible even with noisy photographic data. However, further improvement of automated techniques is needed, which is especially important when considering the very large numbers of new discoveries expected from all-sky surveys.     

Performance results of HESP physical model

As a continuation to the published work on model based calibration technique with HESP(Hanle Echelle Spectrograph) as a case study, in this paper we present the performance results of the technique. We also describe how the open parameters were chosen in the model for optimization, the glass data accuracy and handling the discrepancies. It is observed through simulations that the discrepancies in glass data can be identified but not quantifiable. So having an accurate glass data is important which is possible to obtain from the glass manufacturers. The model’s performance in various aspects is presented using the ThAr calibration frames from HESP during its pre-shipment tests. Accuracy of model predictions and its wave length calibration comparison with conventional empirical fitting, the behaviour of open parameters in optimization, model’s ability to track instrumental drifts in the spectrum and the double fibres performance were discussed. It is observed that the optimized model is able to predict to a high accuracy the drifts in the spectrum from environmental fluctuations. It is also observed that the pattern in the spectral drifts across the 2D spectrum which vary from image to image is predictable with the optimized model. We will also discuss the possible science cases where the model can contribute.     

Methods to determine the angular resolution of the HEGRA extended air shower scintillator array

A precise knowledge of the angular resolution of scintillator arrays used to observe extended air showers (EAS) is of key importance in the search for VHE/UHE γ point sources. Four independent methods have been used to determine the mean resolution for which a value of ΔΘ₆₃ of 0.8°(1.0°) at a proton threshold of 50 (40) TeV has been found for the HEGRA EAS-array.