OSL quartz age underestimation due to unstable signal components

When measuring samples from southern Peru, we discovered an age offset between feldspar infrared-stimulated luminescence (IRSL) and quartz optically stimulated luminescence (OSL) ages. This age offset was not only found in these particular samples but was also observed in samples from a range of geographical localities. Extensive analysis revealed that it is actually the quartz age that underestimates the true depositional age, and this is due to a very weak fast component combined with other thermally unstable OSL signal components. We discuss properties of these poorly behaving samples and how to detect such samples prior to the OSL single-aliquot regenerative-dose (SAR) measurement. Finally, existing approaches to improve equivalent dose (D_e) determination are discussed for samples from southern Peru.     

Switching from advancing to retreating subduction in the Neoproterozoic Tarim Craton,NW China: Implications for Rodinia breakup

Geodynamic drivers for the supercontinent cycle are generally attributed to either top-down(subduction-related)or bottom-up(mantle-related)processes.Compiled geochemical data and U-Pb ages and Hf isotopic signatures for magmatic and detrital zircons from the Tarim Craton reveal a distinct change in subduction style during the Neoproterozoic.The subduction cycle is recorded in increasing and decreasing intensity of subduction-related magmatic rocks and time-equivalent sedimentary successions,and converse trends ofεHf(t)values and corresponding changes in crustal incubation time.These trends are consistent with a switch from advancing to retreating subduction.The switch likely occurred at ca.760 Ma when zirconεHf(t)values increase and crustal incubation times decrease following a transitional shift between 800 Ma and 760 Ma.A switch at this time is consistent with Rodinia breakup and may have resulted in the late Neoproterozoic Tarim rift basin.The long-lived(ca.500 Ma)subduction recorded in the Tarim Craton suggests the predominance of a top-down process for Rodinia breakup on this part of its margin.     

Unusual acid melts in the area of the unique Rosia Montana gold deposit, Apuseni Mountains, Romania: Evidence from inclusions in quartz

Crystalline and melt inclusions were studied in large (up to 2 cm across) dipyramidal quartz phenocrysts from Miocene dacites in the area of the Rosia Montana Au-Ag deposit in Romania. Data were obtained on the homogenization of fluid inclusions and the composition of crystalline inclusions and glasses in more than 40 melt inclusions, which were analyzed on a electron microprobe. The minerals identified in the crystalline inclusions are plagioclase (An 51–62), orthoclase, micas (biotite and phengite), zircon, magnetite (TiO₂ = 2.8 wt %), and Fe sulfide. Two types of the melts were distinguished when studying the glasses of the melt inclusions. Type 1 of the melts is unusual in composition. The average composition of 20 inclusions is as follows (wt %): 76.1 SiO₂, 0.39 TiO₂, 6.23 Al₂O₃, 4.61 FeO, 0.09 MnO, 1.64 MgO, 3.04 CaO, 2.79 Na₂O, 3.79 K₂O (Na₂O/K₂O = 0.74), 0.07 P₂O₅, 0.02 Cl. The composition of type 2 of the melts is typical of acid magmas. The average of 23 inclusion analyses is (wt %) 79.3 SiO₂, 0.16 TiO₂, 10.27 Al₂O₃, 0.63 FeO, 0.08 MnO, 0.29 MgO, 1.83 CaO, 3.56 Na₂O, 2.79 K₂O (Na₂O/K₂O = 1.28), 0.08 P₂O₅, 0.05 Cl. The compositions of these melts significantly differ in concentrations of Ti, Al, Fe, Mg, Ca, Na, and K. The high analytical totals of the analyses (close to 100 wt %, more specifically 98.9 and 99.0 wt %, respectively) testify that the melts were generally poor in water. Two inclusions of type 1 and two inclusions of type 2 were analyzed on an ion probe, and their analyses show remarkable differences in the concentrations of certain trace elements. These concentrations (in ppm) are for the melts of types 1 and 2, respectively, as follows: 10.0 and 0.69 for Be, 29.3 and 5.7 for B, 6.4 and 1.4 for Cr, 146 and 6.9 for V, 74 and 18 for Cu, 92 and 29 for Rb, 45 and 15 for Zr, 1.7 and 0.6 for Hf, 10.3 and 2.3 for Pb, and 52 and 1.3 for U. The Th/U ratio of these two melt types are also notably different: 0.04 and 0.19 for type 1 and 2.0 and 2.9 for type 2. These data led us to conclude that the magmatic melts were derived from two different sources. Our data on the melts of type 1 testify that the magmatic chamber was contaminated with compositionally unusual crustal rocks (perhaps, sedimentary, metamorphic, or hydrothermal rocks enriched in Si, Fe, Mg, U, and some other components). This can explain the ore-forming specifics of magmatic chambers in the area.     

Structural and 40Ar/39Ar mineral age constraints for the tectonothermal evolution of the Green Head Group and Brookville Gneiss,southern New Brunswick,Canada: Implications for the configuration of the Avalon composite terrane

In the late Precambrian Avalon composite terrane of the Canadian Appalachians, the local juxtaposition of Avalonian successions against gneiss complex–platformal metasedimentary rock associations of uncertain relationship to the Avalonian overstep sequence has raised important questions about the configuration of the composite terrane. Typical of this relationship is the juxtapostion of Avalonian arc-related packages (Caledonia assemblage) with the migmatitic Brookville Gneiss and metacarbonate–quartzite Green Head Group (Brookville assemblage) along the Caledonia Fault in southern New Brunswick. Polyphase deformation of the predominantly greenschist facies Green Head Group accompanied development of a regional ductile shear zone that separates the group from the amphibolite facies Brookville Gneiss. Heterogeneous ductile flow in carbonate rocks and the development of a regional foliation was followed by NW-directed shortening and the local development of a penetrative axial planar fabric that intensifies towards the shear zone. Associated structural elements suggest regional dextral transpression, consistent with the metamorphic contrast across the shear zone. Steeply plunging east–west folds may record younger, sinistral movement on associated NE–SW faults. Deformation coincident with metamorphic culmination in the Brookville Gneiss produced a gneissic foliation that was later deformed to produce widespread minor folds of sheath-like geometry. These folds are best developed proximal to the shear zone where they locally document dextral shear, and probably include several generations that overlap early phases of deformation of the Green Head Group. Kinematic indicators within the gneiss are predominantly dextral. ³⁶Ar/⁴⁰Ar versus ³⁹Ar/⁴⁰Ar isotope-correlation ages recorded by metamorphic hornblende suggest that regional cooling of the Brookville Gneiss through ca. 500°C occurred at ca. 540 Ma, providing a minimum age for initial deformation and concomitant metamorphic culmination in the gneiss. ⁴⁰Ar/³⁹Ar plateau ages for metamorphic muscovite suggest cooling through ca. 375°C at ca. 500–520 Ma, providing a minimum age for progressive deformation in both lithotectonic sequences. Low temperature age discordance in the muscovite spectra suggest partial rejuvenation in the mid- and late Palaeozoic. Protracted Cambrian tectonothermal activity in the Brookville assemblage contrasts with the Avalonian tectonostratigraphic record of the Caledonia assemblage in which late Precambrian arc-related packages are overstepped by Cambrian–Ordovician shallow marine strata. Significant Cambrian separation between the two assemblages is therefore suggested, despite Precambrian similarities in their tectonothermal evolution. Separation as a consequence of terrane dispersal is suggested, and may imply a significant rearrangement of the Avalon composite terrane at this time. Final juxtaposition of the two assemblages pre-dates their shared late Palaeozoic rejuvenation, and may correspond to an earlier, mid-Palaeozoic thermal overprint correlated with tectonothermal activity accompanying accretion of the Avalon and outboard Meguma terranes to more inboard tectonic elements of the northern Appalachians.     

Multi-wavelength observations of the 2014 June 11 M3.9 flare: temporal and spatial characteristics

We present multi-wavelength observations of an M-class flare(M3.9) that occurred on 2014 June 11. Our observations were conducted with the Dunn Solar Telescope(DST), employing adaptive optics, the multi-camera system Rapid Oscillations in Solar Atmosphere(ROSA), the new Hydrogen-Alpha Rapid Dynamics camera(HARDcam) in various wavelengths, such as Ca II K, Mg I b_2(at 5172.7 ?A), and Hα narrow band and G-band continuum filters. Images were re-constructed using the Kiepenheuer-Institut Speckle Interferometry Package(KISIP) code, to improve our image resolution. We observed intensity increases of ≈120%–150% in the Mg, Ca K and Hα narrow band filters during the flare. Intensity increases for the flare observed in the SDO EUV channels were several times larger, and the X-rays, as recorded by GOES, increased over a factor of 30 for the harder band. Only a modest delay was found between the onset of flare ribbons of a nearby sympathetic flare and the main flare ribbons observed in these narrow band filters. The peak flare emission occurred within a few seconds for the Ca K, Mg and Hα bands. Timedistance techniques indicate propagation velocities of ≈60 km s~(-1) for the main flare ribbon and as high as300 km s~(-1) for smaller regions, which we attribute to filament eruptions. This result and delays and velocities observed with SDO(≈100 km s~(-1)) for different coronal heights agree well with the simple model of energy propagation versus height, although a more detailed model for the flaring solar atmosphere is needed. Finally, we detected marginal quasi-periodic pulsations(QPPs) in the 40–60 s range for the Ca K,Mg and Hα bands, and such measurements are important for disentangling the detailed flare-physics.     

Non‐Destructive or Noninvasive? The Potential Effect of X‐Ray Fluorescence Spectrometers on Luminescence Age Estimates of Archaeological Samples

The non‐destructive nature of X‐ray fluorescence (XRF) spectrometers is a principal reason for an increase in their use in archaeological science over the last 15 years, especially for analyzing museum‐curated artifacts and in situ site fabrics. Here, we show that low‐power XRF spectrometry can be detrimental for luminescence dating (surface applications such as mud‐wasp nest dating in particular). We investigated the effects of irradiation by X‐rays emitted from handheld and benchtop spectrometers on optically stimulated luminescence (OSL) signals. Measurements were taken using a portable OSL (pOSL) unit on the following unprepared archaeological materials: sedimentary quartz grains, pottery, a mud‐wasp nest, stone tools, and a rock flake with anthropogenically applied pigment and natural pigmentation (iron oxides). We observed an increase in luminescence compared to initial background counts for all materials tested, which could lead to overestimation of age determinations in some situations. Our experiment provides a reminder of the potential effects of X‐ray radiation, and the need for thorough documentation of all recording and analytical techniques applied to archaeological materials.     

http://www.sciencedirect.com/science/article/pii/S167498711200103X

The supercontinent cycle has had a profound effect on the Earth's evolution since the Late Archean but our understanding of the forces responsible for its operation remains elusive. Supercontinents appear to form by two end-member processes: extroversion, in which the oceanic lithosphere surrounding the supercontinent (exterior ocean) is preferentially subducted (e.g. Pannotia), and introversion in which the oceanic lithosphere formed between dispersing fragments of the previous supercontinent (interior ocean) is preferentially subducted (e.g. Pangea). Extroversion can be explained by “top–down” geodynamics, in which a supercontinent breaks up over a geoid high and amalgamates above a geoid low. Introversion, on the other hand, requires that the combined forces of slab-pull and ridge push (which operate in concert after supercontinent break-up) must be overcome in order to enable the previously dispersing continents to turn inward. Introversion may begin when subduction zones are initiated along boundaries between the interior and exterior oceans and become trapped within the interior ocean. We speculate that the reversal in continental motion required for introversion may be induced by slab avalanche events that trigger the rise of superplumes from the core-mantle boundary.     

Changes in water quality and runoff in the Upper Oder River Basin

The aim of the study is the analysis of runoff and water quality changes in the Upper Oder River Basin above the Krapkowice gauging station (catchment area A = 10 720.6  km²).The issue of water quality is of particular importance to Poland, which has comparatively poor water resources compared with many countries of the European Union (EU). What is more, large pollutant loads in the upper course of the Oder pose huge problems for water consumers and users in its middle and lower course (including Germany) and pollute the Baltic Sea.Changes in 7 indices of water pollution, including BOD₅ and COD (synthetic indices), sulphates, chlorides and suspended matter (mineral substances) and nitrates and phosphates (biogenic substances), were investigated for 8 monitoring sites. The study spans the period before and after political transformation in Poland and the Czech Republic, which significantly altered the economies of these countries. In addition, the patterns of runoff changes were analysed at 3 gauging stations: Chałupki, Krzyżanowice and Miedonia, which were also water quality monitoring points. The analysis encompassed 2 periods: 1970–2000 and 1991–2000.The results demonstrated that poor water quality in the Oder improved significantly during the 1990s, as the result of closure of many industries and plants, improvement of sewage treatment and noticeable increases in runoff causing greater dilution of pollutants.As the EU Water Framework Directive is implemented, better water and sewage management can be expected that will contribute to further improvement of water quality in the Oder. However, problems that remain to be solved are the issues of saline mine waters and surface washings and the long-term accumulation of many hazardous substances in bottom sediments in rivers and reservoirs.     

The walking school bus: extending children's geographies?

In many Western cities, the journey between home and school has become problematic, due to intensifying traffic and growing fears for children's safety. Accordingly, many parents now chauffeur their children to and from school. This situation has compounded congestion, prompting efforts to identify safe alternatives. One recent innovation is the walking school bus (WSB). In this paper we report on the development of this initiative, and its adoption at a primary school in Auckland, New Zealand. We conclude that although WSBs extend children's geographies they are, at best, an ambivalent response to the hegemony of motorized transport.     

Nick Rast and the recognition of the Avalonian Arc

Recognition of the eastern (Avalonian) margin of the northern Appalachian orogen as a Late Precambrian microcontinental arc terrane, rather than the opposing passive margin of the Proto-Atlantic (Iapetus) Ocean to that of eastern Laurentia, constituted a fundamental advance in Appalachian geology that profoundly influenced subsequent models for the orogen's plate tectonic evolution. This advance was first clearly articulated by Nick Rast and his students in 1976, who, by correlating rocks of the Avalon Platform with those of the British Midlands, established the Avalonian volcanic belt as a Japan-like microcontinent. Contrary to contemporary views of the Avalon Platform, which favored an extensional, Basin and Range-like setting for its volcanism, Rast argued on the basis of this correlation that the association of Avalonian volcanism with compressional orogeny, widespread calc-alkaline plutonism and, in Angelsey, with blueschists and ophiolitic rocks, indicated a convergent plate margin setting. Rast further proposed that the Avalonian volcanic belt was ensialic, and was bordered to the northwest and southeast by Precambrian oceanic domains. Contemporary reconstructions of the Avalonian and Cadomian belts as fragments of a Cordilleran-like accretionary orogen that developed along an active margin of Neoproterozoic Gondwana owe their origin to these early ideas and, while far removed from the tectonic model that Rast envisaged, are a direct heritage of his recognition of the Avalonian volcanic belt as a microcontinental arc terrane.