T.C. Hoering 《Organic Geochemistry》1984,5(4):267-278

Finely divided samples of the Messel shale that had first been extracted with organic solvents were subjected to pyrolysis at 330°C for 3 days in the presence of excess water or heavy water and also with added pure organic substances. About 8% of the organic carbon was converted into an assemblage of saturated hydrocarbons that closely resembled petroleum hydrocarbons. No olefins were observed in the products. When the reaction was performed in heavy water, extensive deuteration occurred. The extent of substitution and the position of heavy hydrogen in a variety of hydrocarbon structural types were measured by mass spectrometry. A control experiment in which a saturated hydrocarbon was added showed that this deuterium substitution was not due to simple homogeneous exchange.A mechanism for the production of polydeuterated hydrocarbons is advanced, based on a model wherein the molecular fossils that are chemically bonded into kerogen matrix are released as free radicals. During the subsequent chain reactions, migration of olefinic bonds in intermediates and attack by deuterium free radicals result in multiple deuteration with retention of the carbon skeleton of the molecular fossil.  相似文献   

    

Y. Kudoh  T. Inoue  H. Arashi 《Physics and Chemistry of Minerals》1996,23(7):461-469

The crystal structure of hydrous wadsleyite, Mg_1.75SiH_0.5O₄ synthesized in an MA 8-type apparatus at conditions of 1300°C and 15.5 GPa, has been analyzed and refined in space group Imma, using the X-ray intensities measured on a 60X60X10 μm single crystal. The composition (Z=8) and unit cell are Mg_1.74Si_0.97H_0.65O₄ by E.P.M.A. analysis and a=5.663(1) Å, b= 11.546(2) Å, c=8.247(4) Å, V=539.2(5) ų. The partial M-site occupancies were determined; vacancies associated with the incorporation of water are strongly concentrated on the Mg 3 site. The OH in the structure was confirmed by Raman and FTIR spectroscopies. The result of valence sum calculation based on the refined bond lengths indicates that O1 is a hydroxyl. The formula of hydrous wadsleyite can be expressed as Mg_2-xSiH_2xO₄, where 0≤x≤0.25. When x=0.25, all of the O1 site is hydroxyl and the maximum solubility of 3.3 wt% H₂O is realized. Structural relations to other dense hydrous phases are discussed.  相似文献   

    

T.H. Torsvik  M.A. Smethurst  J.G. Meert  R. Van der Voo  W.S. McKerrow  M.D. Brasier  B.A. Sturt  H.J. Walderhaug 《Earth》1996,40(3-4):229-258

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  总被引：4，自引：0，他引：4  

D. W. T. JACKSON 《Sedimentology》1996,43(5):791-796

A new aeolian sediment trap is described which can give up to 1 Hz measurement frequency in field conditions. The trap adopts a circular, horizontal trap design with a load cell connection to give continuous, unobtrusive trap measurement of sediment flux. Simultaneous velocity recording is carried out using an anemometer. Trap construction costs are approximately £200. Initial results in field conditions using a direct comparison of wind velocity data, sampled at an equivalent frequency, have given a first-order relationship between sediment flux and velocity. The trap enables simultaneous sampling of wind velocity and sediment flux at a sufficiently short interval to enable investigation of sediment transport dynamics under a variety of field conditions.  相似文献   

    

Stephen B. Weisberg  Peter Himchak  Tom Baum  Harold T. Wilson  Russell Allen 《Estuaries and Coasts》1996,19(3):723-729

Water quality in the tidal Delaware River has improved dramatically over the last several decades. Areas near Philadelphia that were once anoxic and formed a pollution block to migratory fish passage now rarely experience dissolved oxygen concentrations less than 3 ppm. To assess whether these improvements in water quality led to increased abundance of juvenile fishes, data from a beach seine survey conducted annually since 1980 were examined. The number of species captured increased throughout the tidal river, but the increase was greatest in the areas downstream of Philadelphia, wheare water quality has improved the most. Abundance of juvenile striped bass and American shad, two important game species in the river whose migratory patterns make them susceptible to water quality problems, both increased more than, 1,000-fold during the last decade. Correlatations between the temporal abundance patterns of these species in the tidal Delaware River and in other East Coast systems were poor, suggesting that increases in their numbers were related more closely to improving conditions within the Delaware than to factors affecting coastal stocks.  相似文献   

  总被引：1，自引：0，他引：1  

A. N. Thorpe  F. E. Senftle  R. B. Finkelman  F. T. Dulong  N. H. Bostick 《International Journal of Coal Geology》1998,36(3-4)

Magnetization measurements have been made on natural coke–coal samples collected at various distances from a felsic porphyry dike in a coal seam in Dutch Creek Mine, Colorado to help characterize the nature and distribution of the iron-bearing phases. The magnetization passes through a maximum at the coke-to-coal transition about 31 cm from the dike contact. The magnetic measurements support the geochemical data indicating that magmatic fluids along with a high-temperature gas pulse moved into the coal bed. Interaction of the magmatic fluids with the coal diminished the reducing power of the thermal gas pulse from the dike to a point about 24 cm into the coal. The hot reducing gas penetrated further and produced a high temperature (400–525°C) zone (at about 31 cm) just ahead of the magmatic fluids. Metallic iron found in this zone is the principal cause of the observed high magnetization. Beyond this zone, the temperature was too low to alter the coal significantly.  相似文献   

    

John T. Andrews 《第四纪科学杂志》1998,13(1):3-16

In the last several years evidence has mounted that a series of abrupt changes in sediment delivery and palaeoceanography effected the North Atlantic; they are recorded in a variety of proxy records but most dramatically in changes of grain-size and mineralogy associated with postulated iceberg rafting events, specifically Heinrich (H) events. This review paper examines the evidence for such evidence prior to the development of the ‘Heinrich event’ concept (1988–1992), and then examines the explosion of data and correlations that stemmed from the acceptance and use of this paradigm. Specific attention is focused on ideas pertaining to the cause(s) of glaciological mechanisms, sediment delivery, and sediment source, and major gaps in our understanding of the underlying glaciological, glacial geological, and glacial marine processes are stressed. Abrupt changes across boundaries associated with H-2 in the Labrador Sea are illustrated from core HU87033-009LCF. The case is made that correlations between records need to be more rigorous, especially within the range of radiocarbon dating, but it appears that abrupt changes in the delivery of iceberg rafted debris, which characterize these intervals, are multisourced. It is unclear how global ‘climate’ can simultaneously influence the abrupt behaviour of ice margins in different parts of the world—for marine-based margins, changes in relative sea-level are one possibility. A qualitative model is presented for triggering H events, which includes global changes in mass balance, changes in relative sea-level at ice margins due to glacial isostasy, and changes in the basal thermal regime of tidewater ice-streams. © 1998 John Wiley & Sons, Ltd.  相似文献   

    

D. T. Rudnick  Z. Chen  D. L. Childers  T. D. Fontaine 《Estuaries and Coasts》1999,22(2):398-416

A large environmental restoration project designed to improve the hydrological conditions of the Florida Everglades and increase freshwater flow to Florida Bay is underway. Here we explore how changing freshwater inflow to the southern Everglades is likely to change the input of nutrients to Florida Bay. We calculated annual inputs of water, total phosphorus (TP), total nitrogen (TN), and dissolved inorganic nitrogen (DIN) to Everglades National Park (ENP) since the early 1980s. We also examined changes in these nutrient concentrations along transects through the wetland to Florida Bay and the Gulf of Mexico. We found that the interannual variability of the water discharge into ENP greatly exceeded the interannual variability of flow-weighted mean nutrient concentrations in this water. Nutrient inputs to ENP were largely determined by discharge volume. These inputs were high in TN and low in TP; for two ENP watersheds TN averaged 1.5 mg l^?1 (0.11 mM) and 0.9 mg l^?1 (0.06 mM) and TP averaged 15 μg l^?1 (0.47 μM) and 9 μg l^?1 (0.28 μM). Both TP and DIN that flowed into ENP wetlands were rapidly removed from the water. Over a 3-km section of Taylor Slough, TP decreased from a flow-weighted mean of 11.6 μg l^?1 (0.37 μM) (0.20 μM) and DIN decreased from 240 μg l^?1 (17μM) to 36 μ l^?1 (2.6 μM). In contrast, TN, which was generally 95% organic N, changed little as it passed through the wetland. This resulted in molar TN:TP ratios exceeding 400 in the wetland. Decreases in TN concentrations only occurred in areas with relatively high P availability, such as the wetlands to the north of ENP and in the mangrove streams of western ENP. Increasing freshwater flow to Florida Bay in an effort to restore the Everglades and Florida Bay ecosystems is thus not likely to increase P inputs from the freshwater Everglades but is likely to increase TN inputs. Based on a nutrient budget of Florida Bay, both N and P inputs from the Gulf of Mexico greatly exceed inputs from the Everglades, as well as inputs from the atmosphere and the Florida Keys. We estimate that the freshwater Everglades contribute <3% of all P inputs and <12% of all N inputs to the bay. Evaluating the effect of ecosystem restoration efforts on Florida Bay requires greater understanding of the interactions of the bay with the Gulf of Mexico and adjacent mangrove ecosystems.  相似文献   

  总被引：2，自引：1，他引：1  

T. K. Kyser  C. E. Lesher  D. Walker 《Contributions to Mineralogy and Petrology》1998,133(4):373-381

Differences between the δ¹⁸O values of Si- and Fe-rich immiscible liquids in the system Fe₂SiO₄-KAlSi₂O₆-SiO₂ (Fa-Lc-Q) in isothermal experiments at 0.1 MPa have been determined experimentally to be 0.6 permil. The observed partition of ¹⁸O into the Si-rich liquid is consistent with previous experience with the preferential partition of ¹⁸O into Si-rich minerals in isothermal equilibrium with minerals of less polymerized structure. Crystallochemical principles affect the distribution of oxygen isotopes in coexisting isothermal liquids in the same way as they apply to isothermally coexisting crystals. The effects of Soret (thermal) diffusion on the distribution of oxygen isotopes in silicate liquids above the solvus in the system Fa-Lc-Q under conditions of an imposed temperature gradient of ca. 250 °C over 4 mm and at 2 GPa have also been investigated experimentally. Both the magnitude and the direction of separation of oxygen isotopes as a result of Soret diffusion are unexpected. For each of the silicate liquids, the cold end of the charge is enriched in ¹⁸O by up to 4.7 permil, and the highest δ¹⁸O values are associated with the most silica-poor compositions. The distribution of oxygen isotopes appears to be similar in each liquid, regardless of their chemical compositions, which is in contrast to the behaviour of cations whose distributions are compositionally dependent and characterized by strong crystallochemical effects wherein network-forming species such as Si and Al separate to the hot end and Mg, Fe and Ca are segregated preferentially to the cold end. Structural units in the melts are evidently less selective between oxygen isotopes than between cations, because oxygen redistribution over all possible sites in these units proceeds according to mass. Self-diffusion coefficients of oxygen in basaltic liquids estimated from the Soret experiments are in accord with those from other isotope tracer experiments, and comparable to those of Si. The possible effects of Soret diffusion on the oxygen isotopic composition of metasomatic veins in the mantle are examined in light of these data, and indicate that decay of the thermal gradients in the veins exceeds that of the diffusion of oxygen needed to produce variations in the δ¹⁸O values of mantle minerals. Variations in oxygen isotope ratios in most natural systems as a result of Soret effects are unlikely. Received: 6 January 1997 /  Accepted: 28 June 1998  相似文献   

    

Ufimtsev  G. F.  Skovitina  T. M.  Kulchitsky  A. A. 《Natural Hazards》1998,18(2):167-183

The mountain province of East Siberia, which includes the Baikal Rift system, is a zone of high tectonic and seismic hazard. Earthquakes and coseismic faulting are dangerous not only by themselves but also as far as they initiate rock collapse and downslope movement of unconsolidated deposits, which may block river valleys and produce rockfall-dammed lakes. Within some rifts of the rift system, evidence of past dammed lakes was discovered that arose instantly, in a geological sense, and flooded large areas of forest. In mountains around some rift basins, small living dammed lakes were encountered, as well as traces of catastrophic debris flows that may have accompanied breaching of earlier collapse-produced dams. Analysis of geomorphological setting in the region, especially in the Muya Rift Basin, revealed conditions favourable to hazardous origination of rockfall-dammed lakes. A large dammed lake may come into existence due to the collapse of bedrock over the narrow antecedent valley of Vitim in the Muya Rift. Preliminary estimates based upon data on the Vitim River discharge showed that the lake might form in as short as 27 days, though the rapidity of its formation, and hence the degree of the risk, can vary as a function of the highly variable amount of summer discharge of the river. Rockfall-dammed lakes may also originate in the floors of Chara and Tunka Rift Basins. Due to their rapid formation, lakes will bring about extensive flooding and cause danger to the taiga, railways and constructions in this populated developing area, and will cause degradation of the permafrost.  相似文献