Machine learning reveals the influences of grain morphology on grain crushing strength

Acta Geotechnica - Grain morphology has significant impacts on the mechanical behaviors of granular materials. However, its influences on grain breakage are still poorly understood due to the...     

黄骅坳陷地热资源研究

黄骅坳陷在勘探石油过程中发现了丰富的地下热水。根据实际资料对黄烨坳陷大港探区的地热资源进行了初步评价,提出了黄骅场陷储热系统和热异常区的分布规律,通过水化学分析,指出坳陷补给条件差,可实行人工回灌,增加地下热水资源。     

四川盆地ZQ8井五峰组-龙一段有机质富集机制研究

四川盆地五峰组-龙一段黑色页岩为一套厚度稳定、有机质丰度高的优质海相烃源岩,是页岩气勘探开采的重要层系。为了解五峰组-龙一段有机质富集机制,对四川盆地川南低陡褶带南缘的ZQ8井进行了岩心、岩石薄片、X-衍射、扫描电镜、有机碳、有机碳同位素及微量元素分析。氧化还原指标（Ni/Co、V/Cr、U/Th）表明五峰组海水氧化还原条件由早期富氧氧化条件过渡到缺氧还原条件,龙一₁¹-龙一₁³小层为缺氧-贫氧还原环境,龙一₁⁴-龙一₂⁴小层为富氧氧化环境。氧化还原指标、生产力、笔石、矿物组分和TOC含量的相关性,证明缺氧或贫氧的还原性水体环境是有机质富集的主控因素,笔石、生物成因石英和黄铁矿促进有机质的富集,黏土矿物抑制有机质的富集。综合分析表明：五峰组富有机质页岩主要由火山作用带来大量的营养物质及温暖湿润气候条件下,笔石及浮游动植物繁殖,生产力高,在强滞留缺氧环境下形成;五峰组后期富有机质页岩主要由于冰川作用造成的大量生物灭绝,提供大量有机物质,在缺氧硫化环境下保存形成;龙马溪组富有机质页岩主要受极地冰川溶解,带来丰富的营养物质,生产力水平升高,在高水位海域形成的底部静海相缺氧环境下形成。     

Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.     

柿庄南区块煤层气井早期生产特征及开采建议

从水文地质的角度揭示了不同情况下单井的排水采气机理。在此基础上结合柿庄南区块59口井的实际排采数据,综合分析了气水产量,井底流压,套压及动液面随时间的变化曲线;并将早期生产特征归纳为3种类型：①低产水-高产气型,见气早,产气量高（>1000 m3/d）、产量递减缓慢、峰值产量高,日产水量小（<2m3/d）,套压高;②低产水-中低产气型,日产气小于1000 m3,产量衰减明显且波动大,排水期较长;③高产水型,产气极少或无,日产水量大（>10m3/d）,动液面下降缓慢,套压很低或为零。最后针对不同类型的低产井,提出相应的开采建议：低产水-低产气型井可采用二次压裂措施,改善煤层渗透率;高产水井可通过无机堵水或加大排采强度等方式排采;煤层气井排采要勇于实践,探索适合该区不同煤层的成功排采方法。     

层序地层学在区域地质调查中的应用

在四川北部广元地区1：5万区域地质调查填图工作中，应用层序地层理论和方法，对测区古生代一中生代海相沉积地层进行了详细划分，利用层序地层对岩石地层单位界线进行了优化，从而提高了测区地层划分对比的精度和预测地质体的能力，使岩石地层单位的划分更为合理。建立了测区岩石地层单位，并论述了层序地层与岩石地层的相关性，提出了层序地层在沉积岩区1：5万区调地质图面的表达方式。     

Microelectrode Study of Oxygen Uptake and Organic Matter Decomposition in The Sediments of Xiamen Western Bay

Sediment cores were sampled from Xiamen Western Bay at five sites during the summer and winter of 2006 and Hg–Au microelectrodes were used to make on board measurements of the concentration gradients of dissolved oxygen, Mn²⁺, and Fe²⁺ within the sediments. The O₂ concentrations decreased sharply from about 200 μmol L⁻¹ in the bottom seawater to zero within a depth of a few millimeters into the sediment. Dissolved Mn²⁺ was detected below the oxic zones with peak concentrations up to 600 μmol L⁻¹, whereas dissolved Fe²⁺ had peak concentrations up to 1,000 μmol L⁻¹ in deeper layers. The elemental contents of organic carbon and nitrogen within the sediments were analyzed and their C/N ratios were in the range of 9.0 to 10.1, indicative of heavy terrestrial origin. Sediments from two sites near municipal wastewater discharge outlets had higher organic contents than those from the other sites. These high organic contents corresponded to shallow O₂ penetration depths, high dissolved Mn²⁺ and Fe²⁺ concentrations, and negative redox potentials within the sediments. This indicated that the high organic matter content had promoted microbial respiration within the sediments. Overall, the organic content did not show any appreciable decrease with increasing sediment depths, so a quadratic polynomial function was used to fit the curve of O₂ profiles within the sediments. Based on the O₂ profiles, O₂ fluxes across the seawater and sediment interface were estimated to be in the range 6.07 to 14.9 mmol m⁻² day⁻¹, and organic carbon consumption rates within the surface sediments were estimated to be in the range 3.3 to 20.8 mgC cm⁻³ a⁻¹. The case demonstrated that biogeochemistry within the sediments of the bay was very sensitive to human activities such as sewage discharge.     

一种新的流动注射在线共沉淀技术的研究及应用

建立了应用流动注射在线共沉淀分离富集火焰原子吸收法测定天然水样中痕量铬的价态分析方法。利用铬（Ⅲ）在碱性条件下与氢氧化镧形成共沉淀而与共存离子分离并得到富集，沉淀不需过滤，直接用稀盐酸从编织反应器（ＫＲ）中溶解并洗脱下来，用原子吸收测定。本体系的浓集倍率２２，检出限（３σ）０．８μｇ／Ｌ，相对标准偏差（ｎ＝１１）２．７２％，用水标样考察，分析结果与推荐值相符。该方法成功地用于天然水中铬的快速测定。     

地质样品中微量金银的在线分离富集方法

提出用ＶＳ－Ⅱ型强碱性阴离子交换纤维定量富集、硫脲解脱，流动注射在线分离富集—火焰原子吸收光谱法测定地质样品中痕量金银的分析方法。该方法检出限低，金为１．４μｇ／ｍＬ，银为０．３５μｇ／ｍＬ，相对标准偏差均小于２％，采样频率为１２０次／ｈ，用于地质样品中痕量金银的直接测定，结果令人满意。