Chemical aspects of iron oxide coagulation in water: Laboratory studies and implications for natural systems

Initial coagulation rates of colloidal hematite (-Fe₂O₃) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 10⁴ in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G _ads ⁰ >G _coul ⁰ ) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10^–7 to 10^–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10^–3 to 10^–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems.     

荒漠植被红砂（Reaumurta soongorica）水热响应的年轮学研究

 红砂是黄土高原荒漠植被带主要建群植物种之一，在植被恢复重建和生态建设中具有重要意义。本文以皋兰县40 a天然植被封育区为例，运用树木年轮学方法，对不同坡向红砂与当地水热条件变化的时空响应及分布格局进行了研究。研究结果表明，红砂具有明显的年轮特征，可以进行树木年轮方面的研究。虽然不同坡向水分条件和植被状况有很大差异，但红砂径向生长对区域水热变化具有非常一致的响应模式：同生长季降水呈正相关关系，尤以7月降水量最为显著；同生长季气温呈负相关关系，以6月最为显著。根据不同坡向红砂年龄分布格局分析结果，并考虑到水土流失的防治效果，黄土高原西部荒漠植被带的封育期限不宜少于10 a。     

An experimental study of anorthosite dissolution in lunar picritic magmas: Implications for crustal assimilation processes

Experiments characterizing the kinetics of anorthosite dissolution in lunar picritic magmas (very low-Ti, low-Ti, and high-Ti picritic glasses) were conducted at 0.6 GPa and 1250-1400 °C using the dissolution couple method. Reaction between the anorthosite and lunar picritic magmas at 1250-1300 °C produced a spinel + melt layer. Reaction between the anorthosite and an olivine-saturated low-Ti magma at 1250-1300 °C produced a crystal-free region between the spinel + melt layer and the olivine-saturated magma. The anorthosite dissolution experiments conducted at 1400 °C simply dissolved anorthosite and did not result in a crystal-bearing region. The rate of anorthosite dissolution strongly depends on temperature and composition of the reacting melt. Concentration profiles that develop during anorthosite dissolution are nonlinear and extend from the picritic glass compositions to anorthite. These profiles feature a large and continuous variation in melt density and viscosity from the anorthosite-melt interface to the initial picritic magmas. In both the low-Ti and high-Ti magmas the diffusive fluxes of TiO₂, Al₂O₃, and SiO₂ are strongly coupled to the concentration gradients of CaO and FeO. Anorthosite dissolution may play an important role in producing the chemical variability of the lunar picritic magmas, the origin of spinel in the lunar basalts and picritic glasses, and the petrogenesis of the high-Al basalts.     

下庄铀矿田337矿床成矿流体稀土元素示踪

337铀矿床位于下庄矿田东缘,区内发育近EW向、NNE向构造裂隙群及NW向辉绿岩和正长岩脉体,发育以碱性为主的多种围岩蚀变。区内矿床主要赋矿围岩的稀土元素特征属壳源型。矿石内金属矿物以沥青铀矿为主,矿石的LREE/HREE比值为3.25,Sm/Nd比值平均为0.307,Ce/Yb比值为7.127,这些数据都显示出成矿流体具有较深来源。矿石较围岩亏损稀土元素尤其是轻稀土元素,稀土元素分布模式平缓,与幔源辉绿岩特别是与正长岩的稀土元素分布模式相近,负铕异常比围岩更为强烈,反映成矿流体的来源具有幔源性。结合区域地质特征,可以认为337矿床成矿流体来源具有幔源性质。     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

用BP神经网络预测土抗剪强度指标c、ψ

提出了应用BP神经网络来预测土抗剪强度指标c、ψ.结合工程实例,详细介绍了该方法的建模过程,结果表明预测结果和实测结果很接近,神经网络在土性参数方面应用前景很广阔.     

电子地图中多尺度地图数据显示的研究

将计算机三维模型简化中的LOD思想引入到电子地图的组织和显示中,提出了同一比例尺数字地图不同详细程度的分层显示方法和不同比例尺数字地图嵌套显示方法,实现了电子地图的多级缩放。     

柴达木盆地西部尕斯库勒油田E31油藏成藏条件与机制

柴达木盆地西部原油为盐湖相未成熟-低成熟原油,属于典型的原油成因类型。尕斯库勒油田是柴达木盆地西部最大的油田。从油气生成运移、聚集成藏诸方面,较为系统地研究了该油田中E1₃ 油藏的形成条件,动态地探讨了油藏的形成机制,为该油藏的成因认识和进一步勘探开发提供了科学依据。     

翁牛特旗--库伦旗一带严重缺水区的地质环境及找水途径

翁牛特旗--库伦旗一带为西辽河平原周边的严重缺水区.通过分析研究区地下水形成的地质环境,认为降水量、地形地貌、岩性构造和地下水循环是造成研究区严重缺水的主要因素,地层岩性和新构造运动是影响地下水富集的决定性因素.指出要加强含水层的岩性和构造、基岩区的断裂性质和产状的研究,并提出在基岩区、低山丘陵区寻找构造裂隙水和断裂带脉状水是解决研究区严重缺水的较好途径.     

基于MAPGIS明码文件的绘图转换系统开发及应用

介绍了基于MAPGIS明码文件开发出的MAPGIS明码格式转换系统软件的结构及功能,并说明该软件在地球物理、地球化学领域中的应用。