南半球对流层气候年代际变化及其与太阳活动的联系

通过南半球对流层温度场谱分析和逐次滤波分析发现，南半球对流层大气温度场半个多世纪以来呈现明显的持续升温趋势，升温幅度由低层到高层逐步增加，其中地面层1 000 hPa年升温率为0.013℃/a，对流层中部500 hPa年升温率为0.019℃/ a，对流层上部300 hPa年升温率为0.036℃/ a；滤除南半球大气温度场的趋势变化，发现南半球大气温度场从地面层直至对流层顶广泛盛行着十分显著的与太阳磁场磁性22年周期变化相一致的变化周期。太阳磁场磁性周期变化趋势略有超前，分析认为，这是南半球对流层大气气候系统对太阳磁场周期性变化的响应。进一步分析还发现，南半球从地面层1 000 hPa到对流层顶，再到平流层中部10 hPa各层次大气温度变化22年周期分量振荡位相基本一致，周期振幅由低层到高层迅速增大，说明太阳磁场变化对对流层高层比低层影响大，对平流层影响更大。其中地面层1 000 hPa温度场的22年变化周期是在滤除趋势变化和11年周期之后才显现出来的，所以太阳磁场磁性周期变化对地面层气候的影响较小并且经常处于被掩盖状态；南半球地面层1 000 hPa温度场滤除趋势变化之后显示出十分显著的与太阳活动11年周期相一致的变化周期，分析认为，这是南半球对流层大气气候系统对太阳活动11周期性变化的响应。对流层上层300 hPa温度场滤除趋势变化和22年周期之后也显示出11年变化周期，而对流层中部500 hPa则无此周期反应，说明太阳活动11年周期对地面层1 000 hPa大气气候影响最明显，对流层中上层影响较弱。     

在卸荷产生拉剪情况下裂隙岩体的力学行为

据岩体在卸荷情况下的拉剪应力状态,确定了节理岩体的线弹性断裂力学模型。依照此模型,可以得到相对远离裂隙(该位置的点到裂隙中心的距离比裂缝长度大)且受裂隙影响区域内应力、应变和变形方程。这些对评估裂隙岩石变形有重要的参考意义。通过用理论方程的计算结果和卸荷情况下试验观测所得的数据对比,证明该模型应用于实际工程中具有可行性。     

库水位变化对库岸边坡稳定性的影响

在假定坡体孔隙水水位为水平线且不考虑渗透作用影响的基础上,基于极限平衡法考察了水位上升及下降的快慢对边坡安全系数的影响。对比计算表明:在水位缓慢变化即坡体内外水位线等高的条件下,边坡的安全系数随着水位坡高比的增大先略减小后急剧增大,且在水位坡高比为0.3处取得最小值,在边坡完全淹没于水中时取得最大值。当边坡完全淹没于水中后,水位高于坡顶的多少对边坡安全系数没有影响;在水位骤降或陡升条件下,相同库水位对应的边坡安全系数基本上均小于水位缓慢变化情况下的安全系数,故工程实际中无论是排水还是蓄水,都应尽量保持水位缓慢变化,这样才能使边坡处于较安全的状态。     

基于Markov chain理论的科技成果转化的市场预测

科技成果成功转化的主要标志是其产品的市场畅销度。产品的畅销度由于受各种内外部不确定因素影响，具有随机不确定性。基于这种随机不确定性，运用Markov chain对其产品进行市场预测，并通过实证分析说明其有效性，为科技成果的转化提供具体可行的定量依据。     

浓硫酸钠水溶液中的离子对

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。     

The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.     

Quantifying the impact of landscape changes on hydrological variables in the alpine and cold region using hydrological model and remote sensing data

Quantifying the impact of landscape on hydrological variables is essential for the sustainable development of water resources. Understanding how landscape changes influence hydrological variables will greatly enhance the understanding of hydrological processes. Important vegetation parameters are considered in this study by using remote sensing data and VIC-CAS model to analyse the impact of landscape changes on hydrology in upper reaches of the Shule River Basin (URSLB). The results show there are differences in the runoff generation of landscape both in space and time. With increasing altitude, the runoff yields increased, with approximately 79.9% of the total runoff generated in the high mountains (4200–5900 m), and mainly consumed in the mid-low mountain region. Glacier landscape produced the largest runoff yields (24.9% of the total runoff), followed by low-coverage grassland (LG; 22.5%), alpine cold desert (AL; 19.6%), mid-coverage grassland (MG; 15.6%), bare land (12.5%), high-coverage grassland (HG; 4.5%) and shrubbery (0.4%). The relative capacity of runoff generation by landscapes, from high to low, was the glaciers, AL, LG, HG, MG, shrubbery and bare land. Furthermore, changes in landscapes cause hydrological variables changes, including evapotranspiration, runoff and baseflow. The study revealed that HG, MG, and bare land have a positive impact on evapotranspiration and a negative impact on runoff and baseflow, whereas AL and LG have a positive impact on runoff and baseflow and a negative impact on evapotranspiration. In contrast, glaciers have a positive impact on runoff. After the simulation in four vegetation scenarios, we concluded that the runoff regulation ability of grassland is greater than that of bare land. The grassland landscape is essential since it reduced the flood peak and conserved the soil and water.     

Diatom‐based reconstruction of summer sea‐surface salinity in the South China Sea over the last 15 000 years

We present a new reconstruction of summer sea‐surface salinity (SSS) over the past 15 000 years based on a diatom record from piston core 17940, located on the northern slope of the South China Sea (SCS). The reconstructed diatom‐based summer SSS values for the modern period are in accord with instrumental observations of summer SSS in the area. Here, the modern summer SSS is primarily controlled by river runoff, in particular from the Pearl River. The reconstruction presented in this study shows that the summer SSS varied between 33.3 and 34.2 psu over the past 15 000 years. The long‐term summer SSS trend closely followed the trend of the orbitally controlled solar insolation at 20°N, suggesting that orbital forcing was the dominant driver of changes in summer SSS in this area. Comparisons to speleothem δ¹⁸O data and studies of surface hydrography in the region suggest that changes in solar insolation affected the summer SSS through changes in the East Asian Monsoon and sea‐level changes associated with the last deglaciation. Univariate spectral analyses indicate that centennial‐scale oscillatory variations in summer SSS were superimposed on the long‐term trend. During the deglacial period (c. 12 000–9000 cal. a BP), the dominant periodicity was centred around 230–250 years, whereas a ～350‐year oscillation dominated in the period 2200–4500 cal. a BP. The balance of evidence suggests that these centennial‐scale changes in summer SSS may have been driven by solar‐induced changes in the East Asian Monsoon, but further evidence is needed to firmly establish this relationship.     

A two‐dimensional coupled hydromechanical discontinuum model for simulating rock hydraulic fracturing

Within the framework of our discontinuous deformation analysis for rock failure algorithm, this paper presents a two‐dimensional coupled hydromechanical discontinuum model for simulating the rock hydraulic fracturing process. In the proposed approach, based on the generated joint network, the calculation of fluid mechanics is performed first to obtain the seepage pressure near the tips of existing cracks, and then the fluid pressure is treated as linearly distributed loads on corresponding block boundaries. The contribution of the hydraulic pressure to the initiation/propagation of the cracks is considered by adding the components of these blocks into the force matrix of the global equilibrium equation. Finally, failure criteria are applied at the crack tips to determine the occurrence of cracking events. Several verification examples are simulated, and the results show that this newly proposed numerical model can simulate the hydraulic fracturing process correctly and effectively. Although the numerical and experimental verifications focus on one unique preexisting crack, because of the capability of discontinuous deformation analysis in simulating block‐like structures, the proposed approach is capable of modeling rock hydraulic fracturing processes. Copyright © 2014 John Wiley & Sons, Ltd.