Ab initio molecular orbital studies of low-energy, metastable isomers of the ubiquitous cyclopropenylidene

The discovery of cyclopropenylidene in space suggests that other C3H2 isomers may be present and a tentative detection of one such isomer, propargylene (HCCCH), has been reported. Ab initio molecular orbital theory has been used to characterize five low-lying, metastable isomers of cyclopropenylidene. Four are found to be stable minima and their vibrational frequencies are reported, although the stable form of triplet propargylene is not firmly established. Extended calculations including the electron correlation energy, show that the lowest in energy is singlet propadienylidene, followed by propargylene; the singlet and triplet of the latter are too close in energy to allow an assignment of the ground state; triplet propadienylidene is at a significantly higher energy. Rotational frequencies computed to an expected accuracy of +/- 1%-2% do not confirm the tentative detection of propargylene in space, although the discrepancy between theory and the observation is not so great as to unequivocally rule out this possibility.     

尼罗河三角洲平原沉积物来源和沿岸土壤流失的特例

尼罗河三角洲平原沉积物来源和沿岸土壤流失的特例Ｄ．Ｊ．Ｓｔａｎｌｅｙ尼罗河三角洲曾经是地中海最大的沉积中心，如今它已基本上成为一个人工改造的沿岸平原，不再向地中海延伸，局部开始后退。尼罗河三角洲不再是一个活动的三角洲（Ｓｔａｎｌｅｙ和Ｗａｒｎｅ，１９...     

新石器人类活动反映了中国长江三角洲海平面控制地形的变化

新石器人类活动反映了中国长江三角洲海平面控制地形的变化Ｄ．Ｊ．Ｓｔａｎｌｅｙ等该地质一考古学综合调查主要研究早、中全新世时期长江三角洲平原上影响新石器人类迁徒的环境限定因素。最近的资料表明：（１）该三角洲最早的新石器文化虽然比中国内陆早期的新石器文化...     

Microscale characterization of dissolved organic matter production and uptake in marine microbial mat communities

Intertidal marine microbial mats exhibited biologically mediated uptake of low molecular weight dissolved organic matter (DOM), including D-glucose, acetate, and an L-amino acid mixture at trace concentrations. Uptake of all compounds occurred in darkness, but was frequently enhanced under natural illumination. The photosystem 2 inhibitor, 3-(3,4-dichlorophenyl)-1,1-dimethyl urea (DCMU) generally failed to inhibit light-stimulated DOM uptake. Occasionally, light plus DCMU-amended treatments led to uptake rates higher than light-incubated samples, possibly due to phototrophic bacteria present in subsurface anoxic layers. Uptake was similar with either 3H- or 14C-labeled substrates, indicating that recycling of labeled CO2 via photosynthetic fixation was not interfering with measurements of light-stimulated DOM uptake. Microautoradiographs showed a variety of pigmented and nonpigmented bacteria and, to a lesser extent, cyanobacteria and eucaryotic microalgae involved in light-mediated DOM uptake. Light-stimulated DOM uptake was often observed in bacteria associated with sheaths and mucilage surrounding filamentous cyanobacteria, revealing a close association of organisms taking up DOM with photoautotrophic members of the mat community. The capacity for dark- and light-mediated heterotrophy, coupled to efficient retention of fixed carbon in the mat community, may help optimize net production and accretion of mats, even in oligotrophic waters.     

黔南大贵州滩早三叠世高频旋回堆积型式及其与地球轨道参数变化周期的 …

大贵州滩是右江盆地内的一个三叠纪弧立碳酸盐岩台地。其早三叠世滨潮坪５级小旋回由是潮下泥粒灰岩和潮间条纹岩及蓝藻细菌吉岩等组成。小旋回组合规律为：小旋回按４：的比例组成小旋回束,后者又按３：１的比例组成小旋回组。     

超折射与未来降水

我们在雷达观测工作中发现,当出现“强超折射”时,常在其后1—2天内出现降水天气过程。超折射的强度,我们是以江西玉山县境内的大茅山王京峰的回波为参考的。该山海拔1500m,处在本站的265度方位、155—160km距离上。在无超折射的情况下,天线仰角为零度时,只能观测到该山的顶部。而当出现超折射时,王京峰周围的地物回波增加;回波外观高度增高,一般达到3.5—4km,最强时达6.1km,比无超折射时增高4km多。当本站观测到这样强度的超折射时,当天下午至第3天内将可能出现一次降水天气过程。 于是我们根据超折射与天气过程有一定联系这一现象,寻找相应的指示关系,以延长雷达天气预报时效。1977年9月—1978年10月的超折射回波记录共     

6月17日风暴的雷达资料分析

1974年6月17日,我省全境自北向南经历一次飑线灾害天气,这次过程的特点是风大雨急。地面风力之大、持续时间之长,在历史上是罕见的。我们用小天气图和雷达观测资料对这次飑线过程进行了初步分析。 一、飑线的初生阶段 17日上午山东半岛的一些地方出现雷雨、大风。13时雷达观测到山东曲阜,临沐和江苏连云港附近有略成带状的对流回波区,此现象表明了飑线在13时以前已形成。14时的地面图上,在豫苏皖交界处有一热低压,在热低压中有一条西北风与西南风的切变线。15时在热低压中可分析出由西北风与西南风     

二维地震波折射层析成象

给出了一种用地震折射波初至走时确定二维速度的迭代层析成象反演法。该反演法适用于源－接收器间距比常规剖面法密的折射剖面，它是以线性化问题的迭代解为依据，不仅能用于近水平界面的几何形态，而且也能用于连续速度变化的情况。每次迭代中用射击法进行两点间的射线追踪，来建立线性系统。速度场用速度梯度为常数的三角形单元定义，这样射线路径可解析计算。根据正问题的不同线性化公式对两种不同的反演方法作了研究。用线性化走时－速度雅可比行列式反演得出的结果比用更近似于一般级数展开法的慢度公式的结果好。分辨率的例子不仅揭示了源－接收器组合方式及速度结构对分辨率的影响，而且也揭示了射线的几何形态造成的水平向模糊不清和分辨率随深度降低。反演例子表明，使用较好的初始模型时，整体范数产生的解比用最小扰动法计算的解更接近真实模型。对不均匀射线覆盖产生的条纹作用及其排除作了实例说明。