The vertical hydraulic conductivity of an aquitard at two spatial scales

Aquitards protect underlying aquifers from contaminants and limit recharge to those aquifers. Understanding the mechanisms and quantity of ground water flow across aquitards to underlying aquifers is essential for ground water planning and assessment. We present results of laboratory testing for shale hydraulic conductivities, a methodology for determining the vertical hydraulic conductivity (K(v)) of aquitards at regional scales and demonstrate the importance of discrete flow pathways across aquitards. A regional shale aquitard in southeastern Wisconsin, the Maquoketa Formation, was studied to define the role that an aquitard plays in a regional ground water flow system. Calibration of a regional ground water flow model for southeastern Wisconsin using both predevelopment steady-state and transient targets suggested that the regional K(v) of the Maquoketa Formation is 1.8 x 10(-11) m/s. The core-scale measurements of the K(v) of the Maquoketa Formation range from 1.8 x 10(-14) to 4.1 x 10(-12) m/s. Flow through some additional pathways in the shale, potential fractures or open boreholes, can explain the apparent increase of the regional-scale K(v). Based on well logs, erosional windows or high-conductivity zones seem unlikely pathways. Fractures cutting through the entire thickness of the shale spaced 5 km apart with an aperture of 50 microns could provide enough flow across the aquitard to match that provided by an equivalent bulk K(v) of 1.8 x 10(-11) m/s. In a similar fashion, only 50 wells of 0.1 m radius open to aquifers above and below the shale and evenly spaced 10 km apart across southeastern Wisconsin can match the model K(v).     

Reliably estimating the effect of toxicants on fertilization success in marine broadcast spawners

Recently, there has been a dramatic increase in the number of ecotoxicological studies examining the effects of toxicants on fertilization success in marine broadcast spawners and it appears that this life-history stage is one of the most vulnerable to toxicants. Most of the studies examining this issue use single sperm concentrations in their assays. Here, I discuss recent advances in fertilization ecology that suggest this technique has some severe limitations resulting in unreliable estimations of the size and direction of toxicant effects. I present an alternative assay technique and two metrics (F(max) and [Sperm](max)) that will reliably estimate the size of a toxicant's effect on fertilization success. This technique has the added advantage of making comparisons among species and studies easier without an impractical increase in effort.     

Eigenvector Sky Subtraction

We develop a new method for estimating and removing the spectrum of the sky from deep spectroscopic observations. Our method does not rely on simultaneous measurement of the sky spectrum with the object spectrum. The technique is based on the iterative subtraction of continuum estimates and eigenvector sky models derived from singular value decompositions of sky spectra and sky spectra residuals. Using simulated data derived from small-telescope observations, we demonstrate that the method is effective for faint objects on large telescopes. We discuss simple methods to combine our new technique with the simultaneous measurement of sky to obtain sky subtraction very near the Poisson limit.     

VLA Imaging of the Disk Surrounding the Nearby Young Star TW Hydrae

The TW Hydrae system is perhaps the closest analog to the early solar nebula. We have used the Very Large Array to image TW Hya at wavelengths of 7 mm and 3.6 cm with resolutions of 0&farcs;1 ( approximately 5 AU) and 1&farcs;0 ( approximately 50 AU), respectively. The 7 mm emission is extended and appears dominated by a dusty disk of radius greater than 50 AU surrounding the star. The 3.6 cm emission is unresolved and likely arises from an ionized wind or gyrosynchrotron activity. The dust spectrum and spatially resolved 7 mm images of the TW Hya disk are fitted by a simple model with temperature and surface density described by radial power laws, T&parl0;r&parr0;~r-0.5 and Sigma&parl0;r&parr0;~r-1. These properties are consistent with an irradiated gaseous accretion disk of mass approximately 0.03 M middle dot in circle with an accretion rate approximately 10-8 M middle dot in circle yr-1 and viscosity parameter alpha=0.01. The estimates of mass and mass accretion rates are uncertain since the gas-to-dust ratio in the TW Hya disk may have evolved from the standard interstellar value.     

Degradates provide insight to spatial and temporal trends of herbicides in ground water

Since 1995, a network of municipal wells in Iowa, representing all major aquifer types (alluvial, bedrock/karst region, glacial drift, bedrock/nonkarst region), has been repeatedly sampled for a broad suite of herbicide compounds yielding one of the most comprehensive statewide databases of such compounds currently available in the United States. This dataset is ideal for documenting the insight that herbicide degradates provide to the spatial and temporal distribution of herbicides in ground water. During 2001, 86 municipal wells in Iowa were sampled and analyzed for 21 herbicide parent compounds and 24 herbicide degradates. The frequency of detection increased from 17% when only herbicide parent compounds were considered to 53% when both herbicide parents and degradates were considered. Thus, the transport of herbicide compounds to ground water is substantially underestimated when herbicide degradates are not considered. A significant difference in the results among the major aquifer types was apparent only when both herbicide parent compounds and their degradates were considered. In addition, including herbicide degradates greatly improved the statistical relation to the age of the water being sampled. When herbicide parent compounds are considered, only 40% of the wells lacking a herbicide detection could be explained by the age of the water predating herbicide use. However, when herbicide degradates were also considered, 80% of the ground water samples lacking a detection could be explained by the age of the water predating herbicide use. Finally, a temporal pattern in alachlor concentrations in ground water could only be identified when alachlor degradates were considered.