Comportement géochimique des éléments métalliques en milieu réducteur et diagrammes (log S,pH)

Résumé L'existence de relations entre les teneurs en carbonates et en sulfures dans les eaux des bassins réducteurs, ainsi que l'irreversibilité de la réaction sulfate-sulfure, conduisent à proposer le remplacement des diagrammes Eh. pH, par les diagrammes log S, pH (S désignant la concentration totale de S (-II)). Nous donnons ici le principe de construction, des exemples de diagrammes et quelques applications.

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The existence of relations between the amounts of carbonates and the sulfides in the water of anoxic basins and the irreversibility of the reaction sulphate-sulfide lead us to propose the substitution of diagrams Eh, pH by diagrams log S, pH (S being the total concentration of S (-II)). The principle of how diagrams should be drawn is outlined and some examples and applications are given.

     

Les caractères magmatiques du volcanisme plio-quaternaire des Andes dans le Sud du Pérou

Chemical data on late cenozoic lavas (83 new analyses) from southern of Peru indicate a zonal arrangement of lavas types according to their distance from the trench. The nearest belong to a calc-alkaline suite and the farthest are shoshonites rocks. The calc-alkaline rocks show progressive increase in K₂O content and in K₂O/Na₂O ratio in northeastern direction. The shoshonitic rocks are more potassic and titaniferous, and the K₂O/Na₂O ratio is approximatively constant. The potash content of the two series correlate with the depth of the inclined seismic zone beneath the volcanoes, but this correlation is less well established than in island arcs.     

生物质燃烧颗粒物有机示踪化合物的测定和应用

使用气相色谱-质谱法对2002年7月-2003年7月的北京市大气粗、细颗粒物样品中的左旋葡聚糖等糖类化合物进行了测定。结果表明，左旋葡聚糖主要存在于细颗粒中，可以作为示踪化合物来研究生物质燃烧现象。生物质燃烧对北京市大气颗粒物有较重要的贡献。对应于12％-40％的PM2.5有机碳和10％-33％的PM10有机碳。北京市在2002年10月和11月受到明显的生物质燃烧的影响，可能由于农田秸杆焚烧和秋季落叶焚烧。2003年5月7日颗粒物样品受到直线距离约为1000km以外的内蒙古自治区呼伦贝尔市大兴安岭林区森林大火烟雾的影响。生物质燃烧事件具有突发性，可以长距离传输；生物质作为农村生物燃料的使用其燃烧排放具有经常性和持久性的特征。     

Pits,rifts and slumps: the summit structure of Piton de la Fournaise

A clear model of structures and associated stress fields of a volcano can provide a framework in which to study and monitor activity. We propose a volcano-tectonic model for the dynamics of the summit of Piton de la Fournaise (La Reunion Island, Indian Ocean). The summit contains two main pit crater structures (Dolomieu and Bory), two active rift zones, and a slumping eastern sector, all of which contribute to the actual fracture system. Dolomieu has developed over 100 years by sudden large collapse events and subsequent smaller drops that include terrace formation. Small intra-pit collapse scars and eruptive fissures are located along the southern floor of Dolomieu. The western pit wall of Dolomieu has a superficial inward dipping normal fault boundary connected to a deeper ring fault system. Outside Dolomieu, an oval extension zone containing sub-parallel pit-related fractures extends to a maximum distance of 225 m from the pit. At the summit the main trend for eruptive fissures is N80°, normal to the north–south rift zone. The terraced structure of Dolomieu has been reproduced by analogue models with a roof to width ratio of approximately 1, suggesting an original magma chamber depth of about 1 km. Such a chamber may continue to act as a storage location today. The east flank has a convex–concave profile and is bounded by strike-slip fractures that define a gravity slump. This zone is bound to the north by strike-slip fractures that may delineate a shear zone. The southern reciprocal shear zone is probably marked by an alignment of large scoria cones and is hidden by recent aa lavas. The slump head intersects Dolomieu pit and may slide on a hydrothermally altered layer known to be located at a depth of around 300 m. Our model has the summit activity controlled by the pit crater collapse structure, not the rifts. The rifts become important on the mid-flanks of the cone, away from pit-related fractures. On the east flank the superficial structures are controlled by the slump. We suggest that during pit subsidence intra-pit eruptions may occur. During tumescence, however, the pit system may become blocked and a flank eruption is more likely. Intrusions along the rift may cause deformation that subsequently increases the slump’s potential to deform. Conversely, slumping may influence the east flank stress distribution and locally control intrusion direction. These predictions can be tested with monitoring data to validate the model and, eventually, improve monitoring.     

EJECTION–COLLISION ORBITS AND INVARIANT PUNCTURED TORI IN A RESTRICTED FOUR‐BODY PROBLEM

We study the motion of an infinitesimal mass point under the gravitational action of three mass points of masses μ, 1–2μ and μ moving under Newton's gravitational law in circular periodic orbits around their center of masses. The three point masses form at any time a collinear central configuration. The body of mass 1–2μ is located at the center of mass. The paper has two main goals. First, to prove the existence of four transversal ejection–collision orbits, and second to show the existence of an uncountable number of invariant punctured tori. Both results are for a given large value of the Jacobi constant and for an arbitrary value of the mass parameter 0<μ≤1/2. This revised version was published online in July 2006 with corrections to the Cover Date.     

Hubble Space Telescope-WFPC2/Hα Observations of the Ejected Nebula M1-67

We present HST-WFPC2/Hα deep images of the ejected nebula M1-67. Our data suggest that M1-67 is the imprint of a previous, slow LBV wind ejected from the central star WR124, now a WN8 star. We find evidence that the LBV wind is highly variableand anisotropic. Some dense, persisting clumps have possibly been ejected directly from the stellar surface. This revised version was published online in July 2006 with corrections to the Cover Date.     

Spinel-olivine geothermometry in peridotites from ultramafic complexes

An empirical calibration of the spinel-olivine geothermometer (Evans and Frost, 1975) is attempted and applied to parageneses of lherzolitic rocks. In ultramafic complexes, most of the derived temperature estimates range between 700 ° and 850 °C, and appear generally lower than those given by other geothermometers, based upon Ca or Al contents of coexisting pyroxenes. A comparison of the different thermometric data in two well studied occurrences, the Ronda ultramafic complex and the San Carlos xenolith field, suggests that differential rates of diffusion and recrystalization may account for the large range of temperatures (between 700 ° and 1200 °C) determined by various mineral geothermometers in peridotites. The equilibrium exchange of Mg and Fe between spinel and olivine would be the fastest one and would continue effectively during the cooling down to relatively low temperatures, while other exchange reactions used as geothermometers in peridotites, like partitioning of Ca and Al in coexisting pyroxenes, are blocked at higher temperatures.     

Determination of crystallization temperatures in fractional crystallization series by nickel partitioning equations

Four high-quality seismic refraction profiles were recorded parallel to the structural grain in the Cuvier Basin and adjacent Wharton Basin to study the nature of the earth's crust in this area. The principal result of this experiment is that this area is generally floored with oceanic crust. No transitional velocity structure exists at the base of the continental slope. Departures from a standard oceanic crustal section are observed on an intermediate profile that are attributed to structural complications on the flank of an abandoned spreading ridge. Additional magnetic anomaly profiles in the eastern Cuvier Basin are used to correlate the lineations in that area with Early Cretaceous reversals M-5 to M-10. This correlation dates the onset of plate separation at 120–125 m.y., essentially contemporaneous with the opening of the Perth Basin to the south. However, it leaves a 220-km gap between M-4 and M-5 in the Cuvier Basin that suggests a ridge jump of that magnitude occurred nominally at 118 m.y. Early Cretaceous magnetic lineations northwest of the Exmouth Plateau suggest that spreading at the seaward edge of the Exmouth Plateau began 120 m.y. ago, while Late Jurassic marine sediments and fault structures landward of the Exmouth Plateau suggest rifting in that area at 155 m.y.     

Biotites and associated minerals as markers of magmatic fractionation and deuteric equilibration in granites

Analyses of 80 biotite, alkali feldspar, oligoclase, hornblende, Fe-Ti oxide separates from the coarse-grained granites of a late-hercynian epizonal diapir, the Ploumanac'h complex, Brittany, show that these minerals display a regular concentric cryptic layering related to fractional crystallization. The Ca, Mg, Ba, Sr, Cr, V content of minerals decreases as the Na, Fe, and Rb content increases. Biotites become more dioctahedral towards the outer residual syenogranite, with a correlative K deficiency. Trioctahedral biotites from the inner accumulative monzogranite are secondarily oxidized with a gain of Fe³⁺ and a loss of OH. This alteration id due to the percolation of exsolved fluids rich in H₂O and containing a small amount of CO₂, F, S, Cl. During this autometamorphic stage, trace elements like Rb, Sr are completely redistributed on the scale of hand specimens, with a restricted range of partition coefficients between biotite, perthite and oligoclase. This equilibration occurred at a temperature about 550 ° C and a fluid pressure about 1,000 bars, with f _H2_O probably less than 500 bars. A later stage of fluid circulation along fractures brings up a slight Li metasomatism. Biotites are a sensitive marker of both magmatic and postmagmatic stages of subsolvus or ‘wet’ plutonites.