PCDD/Fs in sediments of Central Vietnam coastal lagoons: in search of TCDD

Samples from nine Central Vietnam coastal lagoons, together with three soils and sediments collected in two freshwater reservoirs of the Thua Thien-Hué province, were analysed for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Total concentrations are low, from 192 to 2912 pg g⁻¹ and depth profiles in Tam Giang-Cau Hai (TG-CH) sediment cores show only minor changes over time in PCDD/F input and composition. Octachloro dibenzo-p-dioxin (OCDD) is the prevailing congener (approximately 90%), indicating combustion as the main PCDD/F source to these coastal systems, whereas natural formation might be partly responsible for the presence at depth. 2,3,7,8-Tetrachloro dibenzo-p-dioxin (TCDD), largely sprayed together with Agent Orange over the study areas during the war (1961–1971), is absent or very low. This result supports the hypothesis of strong degradation soon after spraying. Multivariate statistical analyses account for the presence of local, short-range sources as observed in the northern part of the TG-CH lagoon.     

南非Prieska铜矿区与碰撞有关的P—T—t轨迹

本文通过对南非Namaqua省格林维尔年龄界线以东Prieska铜矿的岩相学及地质年代学的研究,建立了本区保存完好的PTt轨迹。本区的围岩为Areachap群的一部分,属于英安岩-玄武质火山岩及其不成熟沉积物的高级变质产物,地球化学研究表明它形成于1300Ma以前的弧后构造环境之中。其矿体含有5000万吨块状黄铁矿,并含有闪锌矿、黄铜矿。Middleton(1975)和Wagener(1980)曾首先将其解释为一个几乎未遭变质的Noranda型火山沉积矿床,是蒸发性盆地的沉积产物。而我们的工作表明它经历过高级变质作用,是一个形成于弧后盆地与玄武质岩浆作用有关的Besshi型火山沉积矿床。     

Localized thermal anomalies in haloclines of coastal Yucatan sinkholes

A temperature spike is reported in the haloclines of three Yucatan sinkholes along a 1 km NW-SE transect from 5 to 4 km inland from the Caribbean coast. The temperature spike decreases in magnitude from 3.5 degrees C to 0.2 degrees C, approaching the coast. The anomaly does not vary diurnally and does not extend down into the underlying sea water. These conditions are inconsistent with explanations such as radiation absorption within the halocline, in situ microbially mediated sulfate reduction within the halocline and the underlying sea water, and sulfide oxidation by photosynthetic purple and green bacteria within the halocline. One explanation consistent with the shape and halocline location of the temperature spike involves a localized sea water convection cell operating near the coast. Cold sea water from the Caribbean Sea enters the coastal limestone at depths of a few hundred meters and heats up because of the geothermal gradient, buoyantly rising in vertical fractures within the unconfined aquifer. Blocked by the less dense fresh water, the movement stops in the halocline where the warm sea water mixes with brackish water. The convection cycle would be completed by the coastward movement of cooling brackish water. The observed temperature anomalies could possibly be snapshots of this warm layer moving coastward.     

Geographical distribution and accumulation features of organochlorine residues in bivalves from coastal areas of South Korea

As a part of Mussel Watch Program in Korea, the contamination levels and accumulation features of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) were assessed for 82 bivalve samples collected from 66 sites along the entire coast of Korea. The dry weight based ∑PCBs and ∑OCPs ranged from 4.4 ng g⁻¹ to 422.0 ng g⁻¹ (geometric MEAN=36.9 ng g⁻¹) and from 9.95 ng g⁻¹ to 131.37 (34.88) ng g⁻¹, respectively. PCB was predominant in Korean coast, followed by DDTs, HCHs, and Chlordanes. From the observed log normal distribution of PCB and each OCP, low- and high-levels were defined as geometric mean ±1 S.D., respectively. The levels at the sites near urban and/or industrial areas often exceeded the high-levels and the spatial distributions of ∑DDTs and ∑CHLs were correlated with that of ∑PCBs, indicating terrestrial input pathways. Even distribution of ∑HCHs suggested a possibility of atmospheric input pathway of HCHs. The observed isomer ratios of DDTs, HCHs, and CHLs indicated that aging has occurred.     

Evidence for a Black Hole and Accretion Disk in the LINER NGC 4203

We examine the supernova remnant SNR 0540-697 in the Large Magellanic Cloud (LMC) using data from the Chandra Advanced CCD Imaging Spectrometer. The X-ray emission from this supernova remnant (SNR) had previously been hidden in the bright emission of the nearby X-ray binary LMC X-1; however, new observations with Chandra can finally reveal the SNR's structure and spectrum. We find the SNR to be a thick-shelled structure about 19 pc in diameter, with a brightened northeast region. Spectral results suggest a temperature of 0.31 keV and an X-ray luminosity (0.3-3.0 keV) of 8.4x1033 ergs s(-1). We estimate an age of 12,000-20,000 yr for this SNR, but note that this estimate does not take into account the possibility of cavity expansion or other environmental effects.     

Distribution of trace elements in subcellular fractions of three aquatic birds

This study investigated the subcellular distribution of Cu, Zn, Cd and Ag in liver of mallard (Anas platyrhynchos), spot-billed duck (A. poecilorhyncha) and great cormorant (Phalacrocorax carbo) to better understand metal fractionation and dynamics in avian liver. Most of the total Cu, Zn, Cd and Ag were present in hepatocytosol, and their concentrations increased with total hepatic levels in all the three avian species. Copper, Zn and Cd in hepatocytosol were present mostly in metallothionein fractions (MTs), and Cu and Cd contents in this fraction were positively correlated with hepatocytosol levels in all the species. Silver was observed mostly in both high-molecular weight and MT fractions in hepatocytosol in mallard and great cormorant, whereas it was present in both low-molecular weight and MT fractions in spot-billed duck, suggesting that distribution of Ag in the hepatocytosol was species-specific. The elution profile of metals in MT fractions revealed six metallic peaks in mallard and spot-billed duck, and three peaks in great cormorant, implying the presence of multiple MT isoforms in the liver of these avian species. The present study demonstrated that MTs are closely associated with metal regulation, especially Cu and Cd, in these three aquatic birds.