Quantification of electron microprobe compositional maps of rock thin sections: an optimized method and examples

Quantification of discrete pressure–temperature domains in deformed chlorite + white mica‐bearing metapelites was undertaken on mineral compositions derived by two‐dimensional microprobe compositional mapping of selected areas of rock thin sections. In order to achieve compositional information at sufficient analytical precision, spatial resolution and sample coverage within a typical analysis time of 1 day, an optimization of measurement methods was necessary. The method presented here allows collection of raw counts for eight different element concentrations at an analytical precision of ～1–2 wt%. X‐ray intensity multiplane maps (one map per measured chemical element) are translated into concentration multiplane maps, utilizing selected conventionally measured spot analyses combined with the Castaing approximation for each mineral. As this step requires identification of the different minerals present in the mapped area, a statistical clustering technique to identify different groups of composition was developed, guided by simple petrographic inspection of the thin section, to delineate the important minerals in the mapped area. Finally, the compositions of each pixel are translated into a mineral structural formula thus yielding a new kind of image with a high content of petrological information. The reliability of the mineral composition images was emphasized by carrying out precision tests on the analytical data. The possible use of chemical maps to infer the P–T–deformation history of metamorphic rocks is illustrated with two samples from the Spitzbergen and the Sambagawa blueschist facies belts. In both samples, a strong correlation between structures and chemistry is observed. Qualitative estimates of P–T conditions from the Si‐content of mica and chlorite are in good agreement with their location in microstructures that formed at different times. Therefore, the combination of chemical maps with microstructural observations is a very powerful approach to understand both the evolution of complex metamorphic rocks and the control by deformation of mineral reactivity.     

INVESTIGATION OF INFILTRATION CHARACTERISTICS AND DEBRIS FLOW INITIATION CONDITIONS IN DEBRIS FLOW SOURCE AREAS USING A RAINFALL SIMULATOR

Rainfall was simulated on unconfined plots on regolith in debris flow source areas using a portable simulator. In total, 351 simulations were carried out on steep slopes (27–54°) with rainfall intensities of 28–291 mm/h. From these rainfall simulations the infiltration parameters sorptivity (S) and steady-state infiltration capacity (K) of the regolith, and a threshold for the occurrence of micro-scale mass movements, were obtained. Two evaluation methods were used to obtain the infiltration parameters K and S. The ‘infiltration envelope’ method uses rainfall intensity and time to ponding from multiple tests and fits an infiltration envelope through the data from which K and S can be obtained. The ‘constant runoff’ method uses rainfall intensity and overland flow intensity to calculate K, after which S can be calculated in several ways by using time to ponding. The constant runoff method produced K values of 16.6–128 mm/h, which usually show a log-normal distribution. K values depend on the regolith parent material and rainfall intensity. Using this method, S values are 0.088–0.381 cm/min^1/2. The infiltration envelope method produced K values of 9.8–131 mm/h and S values of 0.14–0.32 cm/min^1/2. It can be argued that both methods overestimate K as well as S, but quantitative relations between measured/calculated and actual values of K and S have not yet been obtained. At high rainfall intensities, typically 100 mm/h or more, micro-scale mass movements sometimes occur. A lower threshold curve for the occurrence of these micro-scale mass movements has been constructed. It is a function of both slope angle and rainfall intensity. The micro-scale mass movements could play an important part in the initiation of debris flows in the study area, possibly by delivering sediment to overland flow. On the very steep slopes, the sediment-rich overland flow can easily mobilize coarse material.     

Understanding how environmental heterogeneity and elevation drives the distribution of woody communities across vegetation types within the campo rupestre in South America

The campo rupestre sensu lato is a vegetation type that occurs in South American mountains, supports a distinctive flora characterized by high rates of endemism, high herbaceous species richness and often-neglected but also species-rich of the arboreal stratum. We aimed to investigate how environmental factors and elevation are associated with the distribution and diversity of woody species in different rupestrian vegetation types across South America. Using a database of 2,049 woody species from 185 sites across four vegetation types within the campo rupestre, we assessed how the vegetation types were grouped according to their floristic composition and number of shared indicator species, as well as by using different beta diversity indices. The most important variables from a set of 27 variables(e.g. altitude, geo-edaphic and climatic) explaining species distribution were identified using redundancy analysis(RDA) and variation partitioning methods. The distribution of vegetation types was related to both environmental and spatial fractions, with a set of 17 variables retained(e.g. rockiness, grass cover and temperature seasonality as the most important variables). There was an association between the floristic composition of each vegetation type and the elevation range. Although the identified vegetation types are floristically related, they are distinguished by exclusive and habitat-specialist woody species. This uniqueness of vegetation types should be considered in terms of complementarity for the conservation of campos rupestres.     

Metamorphic evolution of lawsonite eclogites from the southern Motagua fault zone,Guatemala: insights from phase equilibria and Raman spectroscopy

Lawsonite eclogite (metabasalt and metadolerite) and associated metasedimentary rocks in a serpentinite mélange from an area just south of the Motagua fault zone (SMFZ), Guatemala, represent excellent natural records of the forearc slab–mantle interface. Pseudosection modelling of pristine lawsonite eclogite reproduces the observed predominant mineral assemblages, and garnet compositional isopleths intersect within the phase fields, yielding a prograde P–T path that evolves from 20 kbar, 470 °C (M1) to 25 kbar, 520 °C (M2). The dominant penetrative foliation within the eclogite blocks is defined by minerals developed during the prograde evolution, and the associated deformation, therefore, took place during subduction. Thermometry using Raman spectra of carbonaceous material in metasedimentary rocks associated with the SMFZ eclogites gives estimates of peak‐T of ～520 °C. Barometry using Raman spectroscopy shows unfractured quartz inclusions in garnet rims retain overpressures of up to ～10 kbar, implying these inclusions were trapped at conditions just below the quartz/coesite transition, in agreement with the results of phase equilibrium analysis. Additional growth of Ca‐rich garnet indicates initial isothermal decompression to 20 kbar (M3) followed by hydration and substantial cooling to the lawsonite–blueschist facies (M4). Further decompression of the hydrated eclogite blocks to the pumpellyite–actinolite facies (3–5 kbar, 230–250 °C) is associated with dehydration and veining (M5). The presence of eclogite as m‐ to 10 m‐sized blocks in a serpentinite matrix, lack of widespread deformation developed during exhumation and derived prograde P–T path associated with substantial dehydration of metabasites within the antigorite stability field suggest that the SMFZ eclogites represent the uppermost part of the forearc slab crust sampled by an ascending serpentinite diapir in an active, moderate‐T subduction zone.     

2012-2018西藏“雨窝”降水特征及其成因分析

本文采用2012-2018年西藏74个气象站的降水资料,以及墨脱站小时、日、月、季、年的降水资料,对西藏的降水日数、累计降水量、强降水的空间分布进行了分析,结果表明:①墨脱是西藏降水日数最多、累计降水量最大的中心,也是出现极端强降水概率最高的区域.②墨脱的降水主要集中在3-10月,降水呈现双峰型,峰值分别出现在6月和9...     

Vegetation patterns, recent pollen deposition and distribution of non-pollen palynomorphs in a polygon mire near Chokurdakh (NE Yakutia, NE Siberia)

Fine-scaled distribution patterns of vegetation and palynomorphs in a polygon mire in NE Siberia were studied in 31 × 31 plots of 1 m² (vegetation) and along a transect at intervals of 1 m (palynomorphs). Pollen and non-pollen-palynomorph contents clearly reflect differences between polygon ridges and centres. For most single pollen types, however, no unambiguous relation with actual plant abundances and distribution exists. High pollen values are restricted to the immediate vicinity of the pollen sources, which is attributed to the low height of the vegetation. For several plant taxa, high pollen values were found to be restricted to particular plant specimens in the population. High values of pollen ascribed to taxa currently absent at the relevant plot show that the sampled mosses contain a pollen signal of several years. Betula exilis produces two morphologically clearly distinct pollen types. The distribution of selected non-pollen palynomorphs correlates to microrelief, moisture regime and/or trophic conditions. The study shows that single palaeo-sections from arctic peatlands should not be over-interpreted with respect to their palaeoecological value. Local vegetation types and site conditions, however, can be accurately reconstructed from the total assemblages and from combined occurrences of specific palynomorph types.     

Diagenetic processes in carbonate mound sediments at the south‐west Rockall Trough margin

Cold water coral covered carbonate mounds at the south‐west margin of the Rockall Trough form ridges several kilometres long and up to 380 m high. Piston cores obtained at three mound crests reveal the complex internal structure of the mound build up, with alternating unlithified coral‐dominated intervals and lithified intervals. The most recent lithified interval is covered by corals embedded in a fine‐grained matrix, comprising ca 11 000 years of continuous mound evolution. Before this time ²³⁰Th/U dating shows the presence of several hiatuses in mound build‐up. Aragonitic coral material is absent or only present as mouldic porosity in the lithified intervals and coccoliths display widespread overgrowth. Downcore X‐ray fluorescence scanning, computer tomography scan images and petrographic observations indicate different degrees of diagenetic alteration. The upper boundary of the most recent lithified interval shows some erosional features, but petrographic observations indicate that initial lithification of the sediments is not related to this erosive event or to long‐term non‐sedimentation, but to earlier sub‐surface diagenesis. Organic matter oxidation and the subsequent lowering of the saturation state of the carbonate system drives dissolution of the unstable aragonitic coral skeletons. Depending on the openness of the system, this can lead to precipitation of a more stable low‐magnesium carbonate. A model is presented describing the sedimentary and diagenetic processes leading to the formation of lithified intervals.     

西藏高原汛期水汽输送特征与降水异常

利用1979—2006年NCEP/NCAR再分析资料计算垂直积分的整层水汽输送通量及水汽通量散度,分析西藏高原汛期5—9月水汽输送特征。结果表明：两藏高原汛期主要有两条水汽输送带,印度季风输送带和中纬度西风输送带;印度季风对汛期水汽输送起着决定性的作用,决定高原汛期开始时间和雨带的推进,水汽通量向北输送达到30 kg·m~（-1）·s~（-1）时,该经度上的测站将从南到北逐渐进入汛期;在水汽的空间分布上,高原南部边缘的3个水汽输送散度场中心恰好对应着高原的水汽输送通道,其形成与西藏高原的地形直接相关;西藏高原汛期降水主要可以分为3种雨型：全区型、东西型和南北型,并分别对应着不同的水汽输送异常：全区型时索马里越赤道急流水汽输送异常较强,高原区为水汽辐合区;东西型时西藏东南部为东北向输送异常,东南部水汽供应较常年偏弱;南北型时东南部水汽输送充足而错那以西地区水汽输送不足。     

全新世东地中海的陆源碎屑输入及其水文气候变化:海盆尺度地球化学分析

地中海位于非洲季风气候和欧洲温带气候的交界处,同时接受周边地区岩石性质和风化状况差异极大的碎屑物质,所以是研究地球表层水文循环的理想区域。前人的认识集中于撒哈拉风尘和尼罗河输入,往往忽视了其他的陆源碎屑沉积,尤其对不同水文气候条件下的潜在变化缺乏考虑。针对形成于全新世非洲湿润期的腐泥层S1页岩沉积,并结合采自岩心顶部的晚全新世/现代沉积物,文章从18个站位选取了30个样品开展碎屑组分的地球化学分析,通过在具有不同干湿环境背景的时间片段上开展盆地尺度的对比(约9.5~8.9 ka vs. 约1.7~0 ka),探讨全新世东地中海的陆源碎屑输入模式。Ti/Al、Zr/Al、Ca/Al、Y/Al都清晰显示了经向和纬向上的梯度变化,可用作撒哈拉风尘的可靠指标;这些碎屑元素之间的差异反映了北非风尘来源和传送路径的变化。这些风尘指标在南-北向上的一致变化指示了副热带高压与西风带的交互界限为36°N,该界限在全新世应稳定存在。与风尘相反,河流输入的指标值在早全新世时显著高于现代,并呈现不同的地理分布。K/Al具有西高东低、北高南低的分布特征,指示了地中海北部沿岸地区的河流输入。根据与Ti/Al、K/Al的差异,利用(Cr+Ni)/Al可较好地识别被增强的季风降雨所激活的北非古河流沉积。河流输入在早全新世时显著上升,但不同河流系统的影响范围差异很大,受制于源区水文气候、表层洋流搬运等因素。