IMPROVEMENTS TO THE CLASSIFICATION PERFORMANCE OF RDA

Regularized discriminant analysis has proven to be a most effective classifier for problems wheretraditional classifiers fail because of a lack of sufficient training samples,as is often the case in high-dimensional settings.However,it has been shown that the model selection procedure of regularizeddiscriminant analysis,determining the degree of regularization,has some deficiencies associated with it.We propose a modified model selection procedure based on a new appreciation function.By means ofan extensive simulation it was shown that the new model selection procedure performs better than theoriginal one.We also propose that one of the control parameters of regularized discriminant analysis beallowed to take on negative values.This extension leads to an improved performance in certain situations.The results are confirmed using two chemical data sets.     

Direct measurements of latent heat during crystallization and melting of a ugandite and an olivine basalt

Step-scanning calorimetric measurements using a Setaram HT1500 calorimeter were performed between 800 and 1400°C on two natural samples: a ugandite from the East African rift and an olivine basalt from the western Mexican arc. Our measurements provide the first in-situ quantitative assessment of enthalpy during melting of initially crystalline natural samples. The distribution of latent heat across the liquidus-solidus intervals of the two samples is distinctly different, reflecting significant variation in the sequence and abundance of mineral phases during melting (clinopyroxene and leucite in the ugandite; olivine, clinopyroxene, and plagioclase in the basalt). Our data further indicate that the common assumption of a uniform distribution of latent heat across the liquidus-solidus interval of a magma is a reasonable approximation for the olivine basalt, but is grossly in error for the ugandite. This is due to cotectic precipitation of leucite and clinopyroxene, leading to a large, disproportionate release of latent heat early in the crystallization sequence. The implication for the thermal history of a crystallizing ugandite magma is that therate of heat loss during conductive cooling will unitially be more rapid than the average rate. The net result will be to produce lower magmatic temperatures after a given cooling interval relative to models assuming a uniform release of latent heat. An additional series of scanning calorimetric experiments were performed at variable rates (1,2 and 3°/min) to evaluate the role of kinetics on the distribution of enthalpy during both melting and crystallization of the ugandite and olivine basalt. The results indicate that clinopyroxene is the most important mineral phase in controlling the shapes of the enthalpy profiles during cooling; this is due to its large enthalpy of fusion and its tendency for sluggish nucleation, followed by rapid crystallization at temperatures that vary with cooling rate. The resolution of the calorimeter (in terms of heat detected per unit time) is also important in determining the shapes of theobserved enthalpy profiles during these rapid scans. Estimates based on the observed calorimetric signal associated with melting of olivine, and the lack of a calorimetric signal during melting of leucite, combined with known enthalpies of fusion for the two phases, indicate detection limits of approximately 0.6–1.2 kJ per 5 min increments.     

TWO STRUCTURAL MODELS FOR THE WESTERN FLANK OF THE BRABANT MASSIF*

This paper is concerned with an interpretation of the Bouguer anomaly on the Western flank of the Brabant Massif (Belgium). The position, shape, and density contrast of elementary bodies in the upper part of the earth's crust are determined in a purely numerical manner. A batholith-like body and a basin-type structure both adequately account for the observed surface field, at least from a one-sided geophysical and mathematical point of view. Since seismological control is lacking the two models are representative of the ambiguity and indeterminacy of the definitions of the geologic cause of the anomalous features, if the data are restricted to gravity information alone.     

Sedimentology of a marine intermontane Pleistocene Gilbert-type fan-delta complex in the Crati Basin, Calabria, southern Italy

The Crati Basin is a Pliocene-Holocene extensional basin filled by the progradation of different types of marine fan-delta systems. Coarse-grained Gilbert-type fan-deltas developed during the Pleistocene. They represent the sedimentary response to a strong differential uplift involving the basin margins and the basin itself. The differential uplift was responsible for the fragmentation of the basin into several sub-basins, into which these fan-deltas prograded. The protection and lateral confinement by structural highs, steep coastlines and the absence of strong tidal action in the adjacent Ionian Sea, allowed the regular progradation of these fan-deltas in the restricted gulfs and narrow embayments of the Crati Basin. For the classical Gilbert-type (fan) deltas in lacustrine settings, homopycnal inflow favours a rapid mixing of water masses and deposition of sediment close to the river mouth. In the case of the example described here, the density contrast between the sea water and the inflowing river water caused the separation of the muddy fraction from the coarse sandy and conglomeratic part of the sediment. This allowed the development of steep mud-poor coarse-grained delta foresets. Slope instability features (slump scars, conglomeratic flow slides) are fairly scarce in the proximal parts of the San Lorenzo del Vallo system. Towards the north, where protection from the Ionian Sea was less, they increase in importance.     

The genesis of lateral accretion deposits in recent intertidal mudflat channels, Solway Firth, Scotland

ABSTRACT The pattern of lateral accretion on an intertidal point bar is a response to the suspended sediment concentrations to which it is exposed. In summer, high sediment concentrations occur only during shallow (ebb) channel flows; deposition therefore takes place mainly on the point bar toe. In winter, high concentrations obtain at all depths and deposition therefore occurs on the upper point bar slopes. Accretion of the point bar toe is limited by scouring resulting from the high rainfall runoff of winter. High suspended sediment concentrations have little effect, however, if flow velocities are too high to allow deposition. Deposition is dependent on the non-uniformity of curved channel flow and is often confined to the downstream (ebb-sense) portion of the point bar. The lateral accretion deposits form a series of wedge-shaped units. Each unit represents one year's deposition, bounded by erosion scarps produced during successive winters. The base of the point bar deposit shows a gradual aggradation, keeping pace with the build-up of the adjacent interchannel flats.     

EFFECTS OF RIVER NETWORK WORKS AND SOIL CONSERVATION MEASURES ON RESERVOIR SILTATION

Knowledge of the morphological dynamics of a water course is essential for management of reservoir siltation. With an example of sedimentation in a reservoir in Basilicata, Italy, this paper demonstrates the effect on reservoir siltation of the hydraulic works, which are aimed to reduce sediment transport along the fluvial network and to prevent part of the sediment discharge from reaching the lake. The effect depends on the river type and on the the geological features of river basin slopes. The paper also shows how mass erosion can significantly contribute to development of reservoir siltation. Finally, preliminary results are provided about the time needed for river training works to be effective.     

Magmatic Evolution of the La Pacana Caldera System, Central Andes, Chile: Compositional Variation of Two Cogenetic, Large-Volume Felsic Ignimbrites

La Pacana is one of the largest known calderas on Earth, andis the source of at least two major ignimbrite eruptions witha combined volume of some 2700 km³. These ignimbrites have stronglycontrasting compositions, raising the question of whether theyare genetically related. The Toconao ignimbrite is crystal poor,and contains rhyolitic (76–77 wt % SiO₂) tube pumices.The overlying Atana ignimbrite is a homogeneous tuff whose pumiceis dacitic (66–70 wt % SiO₂), dense (40–60% vesicularity)and crystal rich (30–40 % crystals). Phase equilibriaindicate that the Atana magma equilibrated at temperatures of770–790°C with melt water contents of 3·1–4·4wt %. The pre-eruptive Toconao magma was cooler (730–750°C)and its melt more water rich (6·3–6·8 wt% H₂O). A pressure of 200 MPa is inferred from mineral barometryfor the Atana magma chamber. Isotope compositions are variablebut overlapping for both units (⁸⁷Sr/⁸⁶Sr_i 0·7094–0·7131;¹⁴³Nd/¹⁴⁴Nd 0·51222–0·51230) and are consistentwith a dominantly crustal origin. Glass analyses from Atanapumices are similar in composition to those in Toconao tubepumices, demonstrating that the Toconao magma could representa differentiated melt of the Atana magma. Fractional crystallizationmodelling suggests that the Toconao magma can be produced by30% crystallization of the observed Atana mineral phases. Toconaomelt characteristics and intensive parameters are consistentwith a volatile oversaturation-driven eruption. However, thelow H₂O content, high viscosity and high crystal content ofthe Atana magma imply an external eruption trigger. KEY WORDS: Central Andes; crystal-rich dacite; eruption trigger; high-silica rhyolite; zoned magma chamber     

Basin dimensions and morphology as controls on amplification of tidal motions (the Early Miocene North Hungarian Bay)

Following the Late Aquitanian sea-level fall, tide-influenced deposition started in the North Hungarian Bay, an embayment in the Paratethys open to the north-east. The relatively narrow, funnel shape of the bay supported amplification of tidal movements, resulting in the generation of strong tidal currents. The length and the depth of the North Hungarian Bay and the connecting seaway through East Slovakia fell into the ‘Tidal Amplification Window’and thus fulfilled the conditions needed for resonant amplification of semidiurnal (M2) tides. Tide-influenced deposits were formed at both sides of the North Hungarian Bay. They reflect dominant currents in opposite directions and of different strengths at either side of the basin. This difference was the result of bottom-tide interactions. Cyclonic (anticlockwise) residual currents were induced above the asymmetrical central depression in the bay and were superimposed upon the tidal currents, producing an anticlockwise, time-and-velocity asymmetrical current system. The North Hungarian Bay and other examples show that amplification of tidal motions and formation of tide-influenced deposits may occur if basin dimensions pass through the ‘Tidal Amplification Window’. This window represents ideal conditions for resonant or amphidromic amplification of tidal currents. It determines an ideal length/depth or width/depth ratio relative to the wavelength of the astronomical tides. Thus signs of strong tidal influence in fossil basin fills can be used to reconstruct the dimensions (length, depth and width) of such basins.     

Anmerkungen zu „Geochemische Untersuchungen an Sedimenten des Persischen Golfs“

Ohne Zusammenfassung     

THE WILLOWBAR METEORITE*

The Willowbar, Oklahoma meteorite was found by Kendall Rhoton in December, 1971, lat 36° 44′ N.; long 102° 12′ W. It is a shocked brecciated L6 chondrite (Fa-24.3) with large black veins cutting areas of normal chondritic texture. It weighed 2.07 kg.