Mineralogy of nitrogenous guano on the Bounty Islands, SW Pacific Ocean

By far the commonest consituents of insular phosphate deposits are calcium phosphates of the apatite series of minerals, especially varieties that contain structural carbonate in their crystal lattices, e.g. francolite and dahllite. This reflects the fact that the vast majority of described insular phosphate deposits occur in low latitudes, where they have formed, in a tropical environment, by metasomatic replacement of carbonate in coral substrates by phosphate derived either from avian excrement or from phosphorus-enriched lagoonal/lacustrine waters. Thin, recently-formed guano accumulations on islands of the subantarctic Bounty group differ radically in that they consist principally of struvite, a hydrated ammonium magnesium phosphate that is better known as a component of human/mammalian urinary stones and enteroliths, and of bat guano in sheltered speleothems. Apatite occurs only in an accessory role in the Bounty Islands guano. This contrast in mineralogy, and the somewhat anomalous survival of soft, unstable struvite in a totally exposed environment on the Bounty Islands, are attributed to climatic factors and to the nature of the granodioritic rock substrate.     

Melanite garnet-bearing nepheline syenite minor intrusion in Mawpyut ultramafic–mafic complex,Jaintia Hills,Meghalaya

Mawpyut igneous suite in Jaintia Hills of Meghalaya plateau comprises differentiated suite of ultramafic–mafic rocks. The complex differs from other ultramafic–alkaline–carbonatite igneous emplacements of Shillong plateau and Mikir Hills like Jesra, Sung, Samchampi complexes, by the absence of alkaline–carbonatite rocks as major litho-units. Melanite garnet-bearing nepheline syenite, occurs as late phase minor intrusion in Mawpyut igneous complex, posseses alkaline character and shows inubiquitous relation with the host ultramafic–mafic rocks. On the other hand, this alkaline intrusive bodies of the Mawpyut igneous complex shows chemico-mineralogical resemblance with garnet-bearing nepheline syenite, ijolite litho-members of Jesra, Sung, Samchampi complexes of the region. It is interpreted that melanite garnet-bearing nepheline syenite intrusion in Mawpyut is contemporaneous with Jesra, Sung, Samchampi ultramafic–alkaline–carbonatite complexes and the host rocks of Mawpyut complex is an earlier magmatic activity possibly from a comparatively least enriched source.     

A COMPARATIVE STUDY OF GLAUCONITE AND THE ASSOCIATED CLAY FRACTION IN MODERN MARINE SEDIMENTS

The crystallinity and mineralogy of both the glauconite and the clay fraction of samples from six contemporary marine environments were investigated by X-ray diffraction. In those areas where glauconite is now forming, the mineralogy and the degree of crystallinity of both the glauconite pellets and the associated clay fraction are similar. In contrast, detrital and relic glauconites are observed to have mineralogies that are different from their clay fractions. No consistent relationship was observed between degree of crystallinity and color of the pellets. Further, only two classes of glauconite as defined by BURST (1958) were common: expandable, interlayered clays and two or more clay minerals in a mixed assemblage. Based on the clay fraction-glauconite similarities and other supporting evidence, glauconite on the Scotia Ridge is concluded to be authigenic. Glauconite from Santa Monica Bay, California and from the continental shelf off Morocco appear to be detrital. Glauconite pellets in the shelf sediments off Guinea and the southeastern Atlantic Shelf of the United States are both detrital and authigenic. The poor crystallinity exhibited by the Chatham Rise glauconite is in contrast to the well-crystallized associated clay fraction and indicates that they are not genetically related. However, the origin of this glauconite remains in doubt.