Deformation structures and an alteration zone linked to deposition of volcanogenic sulphate in an ancient playa (Oligocene of Nebraska, USA)

Historic, sulphur-rich volcanic eruptions have altered global climate for as much as five years, and much larger events are known from the geologic record. At Scotts Bluff, Nebraska, Early Oligocene strata of the lower Arikaree Group contain a tephra bed with abundant calcite pseudomorphs after gypsum. Previous work has shown sulphate from the pseudomorphs in this tephra bears a high ¹⁷O anomaly indicative of oxidation of sulphur gases by ozone or hydrogen peroxide in the atmosphere. Possible sources of the tephra were caldera eruptions at about 28 Ma in the San Juan volcanic field of south-western Colorado (∼500 km SW of the study site) and the eastern Great Basin (∼1000 km WSW). The present sedimentological study shows that tephra and volcanogenic sulphate were deposited and preserved within a small, surface-discharging playa that developed on the irregular upper surface of aeolian siltstones of the subjacent White River Group. Sulphate solutions (including perhaps sulphuric acid) percolated downward within the vadose zone, dissolving early formed smectite cement within underlying volcaniclastic sandstones, reddening these rocks along an irregular alteration front. Preserved fine-scale stratification within the sandstones precludes the possibility that reddening took place during pedogenesis. Displacive growth of gypsum at the playa centre folded tephra beds and forced tephra into underlying sandstones, forming elongate cones. The large mass fraction of gypsum (now replaced by calcite) in the playa sediments suggests a huge, long-distance delivery of sulphate aerosols. Some of the sulphate and tephra may have come from the same eruption, or the fine-grained tephra may simply have aided preservation of dry-fog sulphate derived from an unrelated, effusive eruption of lava.     

Precipitation of dolomite using sulphate-reducing bacteria from the Coorong Region, South Australia: significance and implications

Dolomite was successfully precipitated in culture experiments that simulated microbiogeochemical conditions prevailing during late stages of evaporation in ephemeral, hypersaline dolomitic lakes of the Coorong region, South Australia. Analyses of lake- and pore-water samples document rapid geochemical changes with time and depth in both dolomitic and non-dolomitic lakes. Extremely high sulphate and magnesium ion concentrations in lake waters decline rapidly with depth in pore waters throughout the sulphate-reduction zone, whereas carbonate concentrations in pore waters reach levels up to 100 times those of normal sea water. Ultimately, sulphate is totally consumed and no solid sulphate is recorded in the dolomitic lake sediments. ‘Most probable number’ calculations of lake sediment samples record the presence of large populations of sulphate-reducing bacteria, whereas sulphur-isotope analyses of lake-water samples indicate microbial fractionation in all the lakes studied. Viable populations of microbes from the lake sediments were cultured in anoxic conditions in the laboratory. Samples were then injected into vials containing sterilized clastic or carbonate grains, or glass beads, immersed in a solution that simulated the lake water. Falls in the levels of sulphate and rising pH in positive vials were interpreted as indicating active bacterial sulphate reduction accompanied by increased concentrations of carbonate. Within 2 months, sub-spherical, sub-micron-size crystals of dolomite identical to those of lake sediments were precipitated. It is concluded that bacterial sulphate reduction overcomes kinetic constraints on dolomite formation by removing sulphate and releasing magnesium and calcium ions from neutral ion pairs, and by generating elevated carbonate concentrations, in a hypersaline, strongly electrolytic solution. The results demonstrate that bacterial sulphate reduction controls dolomite precipitation in both the laboratory experiments and lake sediments. It is proposed that dolomite formation, through bacterial sulphate reduction, provides a process analogue applicable to thick platformal dolostones of the past, where benthic microbial communities were the sole or dominant colonizers of shallow marine environments.     

Regulation of sand transport in the Colorado River by changes in the surface grain size of eddy sandbars over multi-year timescales

In settings where the transport of sand is partially or fully supply limited, changes in the upstream supply of sand are coupled to changes in the grain size of sand on the bed. In this manner, the transport of sand under the supply-limited case is ‘grain-size regulated’. Since the closure of Glen Canyon Dam in 1963, the downstream reach of the Colorado River in Marble and Grand Canyons has exhibited evidence of sand-supply limitation. Sand transport in the river is now approximately equally regulated by changes in the discharge of water and changes in the grain sizes of sand on the channel bed and eddy sandbars. Previous work has shown that changes in the grain size of sand on the bed of the channel (driven by changes in the upstream supply of sand owing to both tributary floods and high dam releases) are important in regulating sand transport over timescales of days to months. In this study, suspended-sand data are analysed in conjunction with bed grain-size data to determine whether changes in the grain size of sand on the bed of the channel or changes in the grain size of sand on the surface of eddy sandbars have been more important in regulating sand transport in the post-dam Colorado River over longer, multi-year timescales. The results of this study show that this combined theory- and field-based approach can be used to deduce which environments in a complicated setting are the most important environments for regulating sediment transport. In the case of the regulated Colorado River in Marble and Upper Grand Canyons, suspended-sand transport has been regulated mostly by changes in the surface grain size of eddy sandbars.     

From global politics to local land users: applying the United Nations Convention to combat desertification in Swaziland

This paper explores the relevance of the United Nations Convention to Combat Desertification (UNCCD) and its related National Action Programmes (NAPs) to people affected by land degradation and change in Swaziland. Household data collected from three chiefdoms are examined, together with policy analyses and information from interviews with policymakers and NGO representatives, as the barriers that inhibit successful implementation of the UNCCD at the national level are explored. We demonstrate how the issues addressed by Swaziland's NAP do not always match the environmental challenges that most threaten the sustainability of rural livelihoods, despite the 'participatory' and 'consultative' approach taken in developing the policy. This is because the more powerful members of society restricted the public's access to policy space. We argue that local involvement in environmental policy and decision-making as prescribed from the international political arena is insufficient to ensure empowerment and democracy in dealing with land degradation in national and local contexts, particularly within highly centralized political systems. Although the UNCCD represents a useful global framework in which to situate local anti-degradation initiatives, in centralized political systems, its success depends upon changes being made to the ethos of national facilitating organizations. Only when the power balance is challenged and greater moves are made towards decentralization will local land users be able to assume a meaningful role in combating desertification.     

The role and impact of freshwater–seawater mixing zones in the maturation of regional dolomite bodies within the proto Floridan Aquifer, USA

Palaeogene dolostones from the sub‐surface of Florida are ideal for the study of dolomite maturation because they record the early stages of a secondary dolomite overprint without destruction by later diagenetic overprints. Two distinct dolomite textures occur in the dolostones of the Upper Eocene Ocala and Lower Oligocene Suwannee limestones in west‐central Florida: a porous and permeable sucrosic dolomite and a less porous and relatively impermeable indurated non‐sucrosic dolomite. In both textures, the initial matrix dolomite is dully luminescent, whereas the secondary overprint is dominantly luminescent cement in the Suwannee and only neomorphic luminescent dolomite in the Ocala. The abundance of luminescent dolomite ranges from 2% to 38%, which translates to 1·6 km³ of material in the Suwannee and 13·5 km³ in the Ocala. Extrapolated trace‐element contents (Sr and Na) and δ¹⁸O values for the matrix and luminescent end‐members indicate a marine origin for the matrix dolomite in both units, and a freshwater–seawater mixing‐zone origin for the secondary luminescent dolomites. The δ¹⁸O values indicate that a saline, middle mixing‐zone environment overprinted the Suwannee but a more dilute mixing zone affected the Ocala. Fluid–fluid mixing models constrained by modern Floridan aquifer hydrochemistry and extrapolated ⁸⁷Sr/⁸⁶Sr values of the luminescent phases indicate that the mixing zones operated during the Late Miocene to Pliocene in the Ocala and affected the Suwannee in the Pliocene. The luminescent Suwannee mixing‐zone cement reduced porosity up to threefold and permeability up to 100‐fold, which converted many sucrosic dolomites to indurated dolomites. By contrast, the neomorphic luminescent Ocala dolomite did not have an appreciable impact on the maturations. Although freshwater–seawater mixing zones were not the sites of the initial dolomitization, the mixing‐zone environment did dramatically overprint and mature the regionally widespread dolomites of the Ocala and Suwannee limestones. This maturation occurred shortly after formation of the proto‐Floridan aquifer; the timing suggests the matrix dolomites were ‘ripe’ for alteration and that the only prerequisite for mixing‐zone dolomite is pre‐existing dolomite substrates to reduce kinetic barriers. In contrast to recent claims, the results of this study demonstrate that mixing zones can be effective in forming regionally significant amounts of secondary dolomite and influencing the petrophysical maturation of dolomite bodies.     

CHRISTALLER CENTRAL PLACE STRUCTURES: AN INTRODUCTORY STATEMENT. By Nurudeen Alao, Michael F. Dacey, Omar Davies, Kenneth G. Denike, James Huff, John B. Barr, M. J. Webber.

Book reviewed in this article:
THE SOCIAL AND ECONOMIC IMPACT OF TOURISM ON PACIFIC COMMUNITIES. Edited by Bryan H. Far-rell.
A NEW KIND OF SUGAR: TOURISM IN THE PACIFIC. Edited by Ben R. Finney and Karen Ann Watson.