Kinetics of the Coesite-Quartz Transition: Application to the Exhumation of Ultrahigh-Pressure Rocks

The kinetics of the quartz–coesite phase transition hasbeen studied in situ by X-ray diffraction in the 2·1–3·2GPa, 500–1010°C pressure–temperature range.Analysis of the data within Cahn's model of nucleation and growthat grain boundaries reveals that the prograde and retrogradereactions have different kinetics. The quartz     

The lithostratigraphy of the Les Echets basin, France: tentative correlation between cores

Two new long sediment cores (EC1 and EC3), recovered from different locations within the infilled basin at Les Echets, France, provide a new high-resolution record of terrestrial and lacustrine responses to climatic changes during Marine Isotope Stages (MIS) 3 and 2. The lithologies of the cores are described in detail and correlated with each other by stratigraphic marker horizons, fluctuations in organic matter and AMS radiocarbon ages. The tentative correlation of the new cores to those described and analysed by de Beaulieu et al. (1980) and de Beaulieu & Reille (1984a) provides a preliminary chronostratigraphic framework. Sedimentation during MIS3 started with accumulation of sands and silts and was followed by alternating gyttja and clayey gyttja silts. Exceptionally high sedimentation rates during MIS2 led to the infilling of the basin. Alternating organic-rich and minerogenic-rich sediments appear to coincide with changes in pollen assemblages (de Beaulieu & Reille 1984a) and suggest that millennial-scale climatic changes controlled lake productivity and catchment stability during most of MIS3.     

Sensitivity analysis of the climate of a chaotic system

This paper addresses some fundamental methodological issues concerning the sensitivity analysis of chaotic geophysical systems. We show, using the Lorenz system as an example, that a naïve approach to variational ("adjoint") sensitivity analysis is of limited utility. Applied to trajectories which are long relative to the predictability time scales of the system, cumulative error growth means that adjoint results diverge exponentially from the "macroscopic climate sensitivity"(that is, the sensitivity of time‐averaged properties of the system to finite‐amplitude perturbations). This problem occurs even for time‐averaged quantities and given infinite computing resources. Alternatively, applied to very short trajectories, the adjoint provides an incorrect estimate of the sensitivity, even if averaged over large numbers of initial conditions, because a finite time scale is required for the model climate to respond fully to certain perturbations. In the Lorenz (1963) system, an intermediate time scale is found on which an ensemble of adjoint gradients can give a reasonably accurate (O(10%)) estimate of the macroscopic climate sensitivity. While this ensemble‐adjoint approach is unlikely to be reliable for more complex systems, it may provide useful guidance in identifying important parameter‐combinations to be explored further through direct finite‐amplitude perturbations.     

NORTH ATLANTIC OSCILLATION SIGNATURES IN WESTERN IBERIAN TREE-RINGS

Exactly dated ring-width chronologies derived from Pyrenean oak and sweet chestnut trees growing in northern Extremadura, Spain, were evaluated for their potential as proxies for regional precipitation and North Atlantic Oscillation variability. The relationships among tree-rings, instrumental climatic records, and three versions of the NAO index were computed for different time subperiods over the last century. The results indicate that tree-ring records reflect, with variable intensity, both short-term and long-term variations in climate. Multiple correlation and regression analysis revealed that summer precipitation appeared to be the major factor affecting tree growth at inter-annual timescales. Moreover, since fluctuations in accumulated variability in annual rainfall over southwest Iberia are controlled by winter precipitation, the accumulated rainfall (August of the year n -1 to July of year n ) and winter NAO indices are also strongly correlated with tree-ring records at interdecadal timescales. This relationship appears to be especially strong during the second half of the 20th century, which is consistent with an increase of the NAO signal in the annual precipitation during the later part of the century. These results indicate that tree-rings from western Iberia are potential proxies of the NAO variability, useful to be included in palaeoclimatic model studies.     

Origin of stratified basal ice in outlet glaciers of Vatnajökull and Öræfajökull,Iceland

Larson, G.J., Lawson, D.E., Evenson, E.B., Knudsen, Ó., Alley, R.B. & Phanikumar, M.S. 2010: Origin of stratified basal ice in outlet glaciers of Vatnajökull and Öræfajökull, Iceland. Boreas, Vol. 39, pp. 457–470. 10.1111/j.1502‐3885.2009.00134.x. ISSN 0300‐9483. During the period 2000–2005, we collected samples of englacial ice, vent water, frazil/anchor ice and stratified basal ice from warm‐based outlet glaciers of Vatnajökull and Öræfajökull, Iceland, and analysed them for ³H, ¹⁸O and D. Results of ³H analyses show that the stratified basal ice contains ³H from atmospheric thermonuclear testing and is younger than the englacial ice. Results of the ¹⁸O and D analyses show that frazil/anchor and stratified basal ice are both enriched by an average of 2.4‰ in ¹⁸O and 11‰ in D relative to vent water. These values are consistent with fractionation during partial freezing of supercooled subglacial water in an open system, one in which the remaining water is continuously removed and replenished by water of similar composition. The isotopic data and field observations do not support either a regelation or a thermal ad‐freeze‐on origin for the stratified basal ice.     

Monazite-Xenotime Thermochronometry and Al2SiO5 Reaction Textures in the Picuris Range, Northern New Mexico, USA: New Evidence for a 1450-1400 Ma Orogenic Event

Al₂SiO₅ reaction textures in aluminous schist and quartziteof the northern Picuris range, north-central New Mexico, recorda paragenetic sequence of kyanite to sillimanite to andalusite,consistent with a clockwise P–T loop, with minor decompressionnear the Al₂SiO₅ triple-point. Peak metamorphic temperaturesare estimated at 510–525°C, at 4·0–4·2kbar. Kyanite and fibrolite are strongly deformed; some prismaticsillimanite, and all andalusite are relatively undeformed. Monaziteoccurs as inclusions within kyanite, mats of sillimanite andcentimetre-scale porphyroblasts of andalusite, and is typicallyaligned subparallel to the dominant regional foliation (S₀/S₁or S₂) and extension lineation (L₁). Back-scatter electron imagesand X-ray maps of monazite reveal distinct core, intermediateand rim compositional domains. Monazite–xenotime thermometryfrom the intermediate and rim domains yields temperatures of405–470°C (±50°C) and 500–520°C(±50°C), respectively, consistent with the progradeto peak metamorphic growth of monazite. In situ, ion microprobeanalyses from five monazites yield an upper intercept age of1417 ± 9 Ma. Near-concordant to concordant analyses yield²⁰⁷Pb–²⁰⁶Pb ages from 1434 ± 12 Ma (core) to 1390± 20 Ma (rim). We find no evidence of older regionalmetamorphism related to the 1650 Ma Mazatzal Orogeny. KEY WORDS: Al₂SiO₅; metamorphism; monazite; thermochronometry; triple-point     

Grain-size information from the statistical properties of digital images of sediment

The autocorrelation technique for estimating grain-size from digital images of sand beds has been extended and validated for use on coarse sand (0·7 mm) and gravel (up to ∼20 mm). A number of aspects of the technique have been explored and some potential improvements suggested. Autocorrelation is just one suitable statistical method sensitive to the grain-size of sediment in digital images; four additional techniques are presented and their relative merits discussed. A collective suite of techniques applicable to the general problem of grain-size estimation from digital images of sediment might broaden the applicability to more sedimentary environments, as well as improve its accuracy. These techniques are compared using a large data set from a gravel barrier beach in southern England. Based on over 180 samples, mean grain-size of sieved and imaged sediments correspond to within between 8% and 16%. Some theoretical aspects of the spatial arrangement of image intensity in digital images of natural sediments are addressed, including the fractal nature of sediments in images, which has potential implications for derivation of grain-size distributions from images of sand-sized material through segmentation and thresholding. The methods outlined in this contribution may also find application in further uncovering the geometric structure of sediment beds, as well as in the simulation of sedimentation processes.