柴达木盆地北缘果可山石英闪长岩LA-ICP-MS锆石U-Pb定年及其成因

柴达木盆地北缘果可山地区石英闪长岩LA-ICP-MS锆石U-Pb定年获得的206 Pb/238 U加权平均年龄为247±3 Ma。石英闪长岩由斜长石(55%~60%)、石英(15%~20%)、角闪石(10%~15%)和黑云母(5%~10%)组成,属准铝质-弱过铝质系列(A/CNK=0.95~1.02),具有I型花岗岩特征。样品富集轻稀土元素和大离子亲石元素(K、Rb、Cs、Ba、Th等),相对亏损重稀土元素和高场强元素(Nb、Ta、P、Ti等),类似弧岩浆岩。样品中MgO含量(2.04%~2.44%)和Mg#值(48.9~51.9)均高于变玄武岩/变泥岩在1~4GPa压力下部分熔融形成的熔体,且包含大量暗色包体,这暗示它们可能是由角闪岩相下地壳部分熔融产生的岩浆和富集地幔来源的岩浆发生混合而成。低的锆石Ti温度和高Ce~(4+)/Ce~(3+)比值,表明其结晶自低温、高氧逸度岩浆,岩浆形成过程中可能有富水熔体/流体的加入。在花岗岩构造环境判别图解上,样品均落在火山弧环境;同时,样品La/Nb比值(2.27~2.64)与活动大陆边缘区高La/Nb比值(2.0)特征相吻合。结合区域地质背景分析,我们认为果可山石英闪长岩形成于古特提斯洋向北俯冲的活动大陆边缘弧环境。     

Relative sea-level history from the Lambert Glacier region, East Antarctica, and its relation to deglaciation and Holocene glacier readvance

We present a relative sea-level (RSL) history, constrained by AMS radiocarbon-dated marine-freshwater transitions in isolation basins from a site adjacent to the Lambert Glacier, East Antarctica. The RSL data suggest an initial ice retreat between c. 15,370 and 12,660 cal yr B.P.. Within this period, meltwater pulse IA (mwp IA, between c. 14,600-14,200 and 14,100-13,700 cal yr B.P.) occurred; an exceptionally large ice melting event, inferred from far-field sea-level records. The RSL curve shows a pronounced highstand of approximately 8 m between c. 7570-7270 and 7250-6950 cal yr B.P. that is consistent with the timing of the RSL highstand in the nearby Vestfold Hills. This is followed by a fall in RSL to the present. In contrast to previous findings, the isolation of the lakes in the Larsemann Hills postdates the isolation of lakes with similar sill heights in the Vestfold Hills. An increase in RSL fall during the late Holocene may record a decline in the rate of isostatic uplift in the Larsemann Hills between c. 7250-6950 and 2847-2509 cal yr B.P., that occurred in response to a documented mid-Holocene glacier readvance followed by a late-Holocene retreat.     

Generation of homologous porphyrins under simulated geochemical conditions

Crude oils generally contain at least one symmetrical homologous series of porphyrins, which is usually centered at m/e 476 (DPEP) or m/e 478 (etioporphyrin). Simulated geochemical conditions in the present study resulted in decarboxylations and alkylations which ultimately led to the synthesis of homologous porphyrins from a single porphyrin. In several series of closed tube experiments, mesoporphyrin IX dimethylester (MPDME) was mixed with a variety of constituents including benzene, acetic acid, propionic acid, water and clay; the experiments were performed at temperatures between 135°C and 400°C at time intervals up to 80 days. Dealkylation, alkylation, hydrolysis, decarboxylation and metallation products were observed. An unsymmetrical homologous series of porphyrins was produced from MPDME. The dominant mass was m/e 478 (corresponding to a double deoarboxylation). Dealkylation products in multiples of 14 amu below the m/e 478 peak comprised the other members of the series. Cu-MPDME also produced homologous porphyrins. These, however, exhibited symmetry about the dominant members, similar to the symmetry found for the porphyrins of most petroleums and oil shales.     

滇东南地区中三叠统沉积型锰矿的热释光特征

矿物和岩石的热释光是矿物晶体特征中研究程度较低的领域。将采自滇东南地区中三叠统的锰矿样品分类后进行热释光实验研究。实验发现:上矿段褐红色锰碳酸盐集合体的热释光谱线多两峰型,前特征峰位于250～350℃之间,后特征峰位于350～430℃之间,且前峰的峰值明显低于后峰,热释光强度最大值均出现在最高温度——450℃处,前峰均存在,后峰偶有缺失;下矿段黑色锰氧化物集合体的热释光特征是在280～340℃处为第一峰,而在390±10℃范围内为一拐点,420±10℃处为另一拐点,使热释光谱线呈现阶梯状,但部分样品第一峰缺失。将上、下矿段同类矿样的热释光谱线对比发现:上、下矿段内部的同类型矿石的热释光特征具相似性,上、下矿段之间的同类型矿石的热释光特征几乎无可比性,说明矿石形成时所处环境对热释光谱线的影响大于矿物成分对矿石热释光谱线的影响。     

Early Cretaceous Climate Changes Recorded in Magnetic Susceptibility and Color Index Variations of the Lower Liupanshan Group, Central China

This study carried out comprehensive analysis on sedimentology, magnetic susceptibility(χlf) and color data of the continental sediments of the Liupanshan Group in Central China so as to obtain climatic change information during the 129.14–122.98 Ma interval. Based on the results of the ?lf and of the redness(a*), the section can be divided into two segments:(1) 129.14–126.3 Ma, with the lowest ?lf values and strongly variable relatively high values of redness and(2) 126.3–122.98 Ma, with high ?lf values and relatively low redness. Analysis of the lithology and facies as well as the magnetic minerals and their contents points to a detrital origin of the magnetic minerals and this allow us to interpret the relationship between magnetic susceptibility variations and climate changes. Our study shows that the climate was significantly dry and hot during the whole studied interval although the interval between 126.3 Ma and 122.98 was a little bit cooler with increased humidity.     

华山云海的变化特征以及与气象要素的关系

用华山气象站1985—2014年气象要素资料,分析近30 a华山云海的变化及云海与降水、相对湿度、风速的关系。结果表明,华山年平均云海日为26.27 d,最多年份72 d,最少年份仅3 d;面积200 km~2云海年平均日数24.23 d;面积≥200 km~2云海平均日数2.87 d,最多有20 d (1985、1994年),最少有2 d(1997年),1997年后再没有面积≥200 km~2的云海出现。云海的出现呈逐年下降的趋势,年际差异明显。秋季云海出现日数最多(平均云海日数8.13 d),冬季最少(平均4.60 d);各月的云海日数8月最多,5月最少。面积≥200 km~2云海冬季出现日数最多,夏季最少;11月出现最多,3、12月次之,5月最少。面积≥200 km~2云海出现的前一天或当天一般都有降水,两天中至少有一天出现降水的几率是84.30%;平均相对湿度≥70%时,较易形成云海;云海日出现时常伴有风,但总体风速不大,通常≤10.0 m·s~(-1),利于云海的形成保持。     

上海淀山湖水生高等植物现状及其近30年变化

于2009年8月至2010年5月调查淀山湖水生高等植物现状.并结合历史资料分析其近30年变化,探讨水生植被的发展趋势及退化原因.淀山湖现有水生高等植物29种,隶属18科,25属,栽培种、外来种比例较过去升高.30年来水生植被(尤其是沉水植被)面积严重萎缩,主要植被类型从沉水植物占优势转变为漂浮植物占优势,沉水植被主要优...