Origin and composition of fluid responsible for metasomatic processes in shear zones of the Bolshie Keivy tectonic nappe,baltic shield: Carbon isotope composition of graphite

Doklady Earth Sciences -     

Biogeochemical Modelling of a Seasonally Anoxic Lake: Calibration of Successive and Competitive Pathways and Processes in Lake Aydat,France

A reactive transport model was developed to describe seasonal variations of biogeochemical and physical processes in Lake Aydat. The model includes physical processes such as vertical mixing, sedimentation and advection related to inflows into the lake and biogeochemical conversion processes in the water column and in the sediment surface layer. The reactions described in the model include primary redox reactions such as primary production, aerobic and anaerobic respiration, methanogenesis and secondary reactions established between oxidants and reducers produced by the primary reactions. After adjusting various kinetic constants, the model reasonably reproduced the main features of seasonal variations of dissolved oxygen and nitrate depth profiles and pH. The reactive transport model was also used to quantify the relative importance of different biogeochemical pathways. For instance, ferrous denitrification seems to play an important role when stratification is increasing.     

Sediment movement under unidirectional flows: an assessment of empirical threshold curves

A selection of threshold data sets from previous investigations is used to re-examine, selectively, some of the empirical curves that are most commonly used for the prediction of sediment threshold. Simple analytical formulae are derived describing single line curves for mean threshold values and envelopes for the initial movement of discrete particles and the commencement of mass sediment transport phases of the critical condition.The complexity of factors governing the prevailing conditions at threshold, together with the randomness of events, limits deterministic solutions; however, the curves provide an approach that can be used readily in practical applications. In contrast, the envelope presentation is more of a stochastic approach to the definition of threshold. It recognises that there is no definitive threshold condition under which a particular particle size can be displaced, but rather that a range of threshold values exist.The empirical threshold relationships were derived on the basis of a relatively large amount of data. However, the sources utilised have interpreted the ‘critical condition’ in various ways, implying that the formulae must be treated with caution in applications.     

A wave model for the Great Barrier Reef

A new wind wave generation model, WAMGBR, is presented that has been adapted from WAM especially for use in the complex geometry of the Great Barrier Reef. A technique (reef parameterization) has been presented that incorporates sub-grid scale dissipation caused by coral reefs. Three other improvements to WAM have been proposed. An explicit/implicit finite difference scheme has been implemented that allows for more efficient modelling (longer time steps) while maintaining diffusive characteristics that are at least as good as those of WAM. An offset in discrete angles creates more uniform diffusive characteristics. And, a transformed spherical coordinate system allows for more efficient grid sizes and smaller grid dependent refraction. Comparisons between modelling techniques and between model and measured data show that WAMGBR produces very good results in the difficult challenge of modelling both non-cyclonic and tropical cyclone waves in the geographically complex environment of the Great Barrier Reef.     

Upstream dams and downstream clams: growth rates of bivalve mollusks unveil impact of river management on estuarine ecosystems (Colorado River Delta, Mexico)

We studied how the extensive diversion of Colorado River water, induced by dams and agricultural activities of the last 70 years, affected the growth rates of two abundant bivalve mollusk species (Chione cortezi and Chione fluctifraga) in the northern Gulf of California. Shells alive on the delta today (‘Post-dam’ shells) grow 5.8–27.9% faster than shells alive prior to the construction of dams (‘Pre-dam’ shells). This increase in annual shell production is linked to the currently sharply reduced freshwater influx to the Colorado River estuary. Before the upstream river management, lower salinity retarded growth rates in these bivalves. Intra-annual growth rates were 50% lower during spring and early summer, when river flow was at its maximum. Growth rates in Chione today are largely controlled by temperature and nutrients; prior to the construction of dams and the diversion of the Colorado River flow, seasonal changes in salinity played an important role in regulating calcification rates.Our study employs sclerochronological (growth increment analysis) and geochemical techniques to assess the impact of reduced freshwater influx on bivalve growth rates in the Colorado River estuary. A combination of both techniques provides an excellent tool to evaluate the impact of river management in areas where no pre-impact studies were made.     

Images of the seabed in the Faroe-Shetland Channel from commercial 3D seismic data

A large number of 3D deep seismic surveys in the Faroe-Shetland Channel gives continuous coverage over most of the region. These surveys were designed primarily to image depths in excess of 4 km, use low frequency sources and are recorded at low temporal sample rates. However, commercial 3D data can generate highly detailed images of the seabed due to the high spatial sample rate, typically 12.5 m. This is particularly true in waters below 200 m. Despite geophysical artefacts, the images reveal that there are a number of sedimentary processes at work adjacent to and within this channel. On the West Shetland Shelf, iceberg scouring and moraines reflect the impact of glaciation. On the West Shetland slope there is clear evidence for down-slope processes, such as debris flows, linear erosion channels, basal fans and (one case) slope failure. Along-slope processes are also active as indicated by the presence of sediment waves and contourite mounds. On the floor of the basin, polygonal cracking can be observed. The most spectacular feature appears to be the Judd Deeps, a system of cliffs approximately 200 m high and 40 km across. Traditionally, seabed investigation has been performed using high-resolution surveys. This study shows that deep exploration data can also provide useful images of the seafloor.     

Species, tissue and gender-related organochlorine bioaccumulation in white-sided dolphins, pilot whales and their common prey in the northwest Atlantic

Organochlorine concentrations were measured in white-sided dolphins, pilot whales, and their prey from the Gulf of Maine and used to identify species, tissue, and gender differences, and trophic transfer trends, in bioaccumulation. Polychlorinated biphenyl concentrations ([PCB]) in dolphin blubber (13 +/- 7.1 micrograms/g fresh wt.) were twice those in pilot whales, but pesticide concentrations (20 +/- 13 micrograms/g fresh) were similar between species. 4,4'-DDE, trans-non-achlor, Cl6(153) and Cl6(138) concentrations were highest. Skin tissues had more recalcitrant organochlorines than the internal organs. Male dolphins bioaccumulated higher concentrations of nonmetabolizable PCBs and hexachlorocyclohexane (HCH) isomers, whereas pilot whales had no gender-related differences in bioaccumulation. Pilot whales, mackerel, and herring had proportionately higher concentrations of DDTs, whereas [PCB] were higher in dolphins and squid. Although these odontocetes feed at the same trophic level and store a similar suite of contaminants, dolphins bioaccumulated higher and potentially hazardous 4,4'-DDE and PCB concentrations from food in their more geographically restricted range.     

Using Hydrogeochemical Methods To Evaluate Complex Quaternary Subsurface Stratigraphy Block Island,Rhode Island,USA

One of the major problems in hydrogeologic investigations of glaciated regions is the determination of complex stratigraphic relationships in the subsurface where insufficient information is available from drilling and geophysical records. In this paper, chemical characteristics of groundwater were used to identify stratigraphic changes in glacial deposits that were previously inferred on Block Island, Rhode Island, USA, an emergent remnant of the late Wisconsinan terminal moraine, located approximately 16 km south of the Rhode Island mainland. Two chemically distinct water types are recognized on the island: 1) high-iron, characterized by dissolved silica levels in excess of 20 mg/L, bicarbonate greater than 30 mg/L and dissolved iron ranging from 1-20 mg/L; and 2) low-iron, characterized by dissolved silica levels below 16 mg/L, bicarbonate less than 30 mg/L, and less than 0.3 mg/L dissolved iron. The spatial distribution of iron-bearing minerals and organic matter and the resulting redox conditions are believed to control the occurrence of high-iron groundwater. The high-iron waters occur almost exclusively in the eastern half of the island and appear to coincidence with the presence of allochthonous blocks of Cretaceous-age coastal-plain sediments that were incorporated into Pleistocene-age deposits derived from the Narragansett Bay-Buzzard's Bay lobe of the Late Wisconsinan Laurentide ice sheet. The low-iron waters occur in the western half of the island, where the occurrence of these Cretaceous-age blocks is rare and the sediments are attributed to a sublobe of the Hudson-Champlain lobe of the Late Wisconsinan ice-sheet. RÉSUMÉ: L'un des principaux problèmes dans les études hydrogeologiques des régions qui ont été englacées est la définition des relations stratigraphiques complexes sous la surface, lá où les informations fournies par les forages et par la géophysique sont insuffisantes. Dans l'exemple traité, les caractéristiques chimiques de l'eau souterraine sont utilisées pour identifier les variations stratigraphiques dans les dépôts glaciaires qui avaient auparavant été supposées, sur l'île de Block (Rhode Island), restes émergeant d'une moraine terminale du Wisconsinien récent, situé à environ 16 km au sud de Rhode Island. Deux types d'eau chimiquement distincts ont été reconnus dans l'île: 1) à fortes teneurs en fer, caractérisées par des concentrations en silice supérieures à 20 mg/L, en bicarbonates supérieures à 30 mg/L et en fer comprises entre 1 et 20 mg/L; et 2) à faibles teneurs en fer, marquées par des concentrations en silice inférieures à 16 mg/L, en bicarbonate inférieures à 30 mg/L et en fer dissous inférieures à 0.3 mg/L. La distribution spatiale des minéraux riches en fer et de la matière organique et les conditions redox résultantes contrôlent probablement la présence de fer dans les eaux souterraines à fortes concentrations. Les eaux à fortes teneurs en fer sont connues presque exclusivement dans la moitié orientale de l'île et semblent coïncider avec la présence de blocs allochtones provenant des sédiments côtiers crétacés, introduits dans les formations pléistocènes liées au lobe glaciaire des baies de Narragansett et du Busard de la calotte glaciaire laurentide du Wisconsinien récent. Les eaux à faibles teneurs en fer apparaissent dans la moitié occidentale de l'île, là où ces blocs de Crétacé sont rares et où les sédiments sont attrbués à une digitation du lobe de l'Hudson-Champlain de la calotte glaciaire du Wisconsinien récent. RESUMEN: Uno de los mayores problemas en la investigación hidrogeológica en regiones glaciares es la determinación de las complejas relaciones estratigráficas en el subsuelo, donde la información procedente de registros de perforaciones y de geofísica no es suficiente. En este artículo, se han usado las características químicas del agua subterránea para identificar unos cambios estratigráficos que se habían predicho previamente en unos depósitos glaciares en Block Island, Rhode Island (Estados Unidos), un remanente emergente de la morrena terminal del Winsconsiniense tardío, situada unos 16 km al sur de la Rhode Island continental. En la isla se encuentran dos tipos de agua distintos: 1) de alto contenido en hierro, caracterizada por niveles de sílice disuelto superando los 20 mg/L, bicarbonatos por encima de 30 mg/L y hierro disuelto oscilando entre 1-20 mg/L; y 2) de bajo contenido en hierro, caracterizada por niveles de sílice disuelto inferiores a 16 mg/L, bicarbonatos por debajo de 30 mg/L y menos de 0.3 mg/L de hierro disuelto. La distribución espacial de los minerales ricos en hierro y de la materia orgánica, así como las condiciones redox resultantes se supone que condicionan la presencia de aguas de alto contenido en hierro. Estas aguas aparecen casi exclusivamente en la mitad oriental de la isla y parecen coincidir con la presencia de bloques alóctonos de sedimentos costeros, de edad cretácica, que se incorporaron a los depósitos de edad pleistocena procedentes del lóbulo de la Bahía de Narragansett-Bahía de Buzzard, correspondiente a la capa glaciar del Winsconsiniense-Lauréntido tardío. Las aguas de bajo contenido en hierro aparecen en la mitad occidental de la isla, donde la presencia de estos sedimentos de edad cretácica es rara y los sedimentos se suponen procedentes de un sublóbulo del lóbulo de Hudson-Camplain, correspondiente a la capa glaciar del Winsconsiniense tardío.