A Classification of Hypersaline Waters, Based on Trophic Criteria

Abstract. A classification of hypersaline waters is proposed on the basis of the food chain structure of their biota. Four steps of increasing salinity and respective shortening of the food-chains are recognized, respectively named: alpha-, beta-, gamma- and delta-hypersaline waters.
Some general aspects, dealing with cosmopolitism of the biota, production, competition and benthic ecology in hypersaline waters are discussed.
The relevance of ecological studies in hypersaline waters to theoretical ecology and to the new technological uses of saline waters is briefly mentioned.     

Phosphate adsorption and desorption in a tropical estuary (Maracaibo system)

The Maracaibo Estuary is of particular interest because of its location in the tropics, its large size (over 12,000 km²), the economic importance of its underlying hydrocarbon deposits and its increasing rate of pollution. Sediments from this estuary were studied in order to characterise their capacity to adsorb and desorb phosphorus. Considerable variability in capacity for phosphate sorption was found among the seventeen samples studied. This variability can be attributed first to the differences among the samples in total P content and, secondly, to their differences in free iron content. Also, it appears that P retention contributes to the control of P concentration in the water and therefore the sediments serve as a buffer in controlling P eutrophication in the estuary.     

Generation of small-scale turbulence in the Antarctic circumpolar current

A functional connection between probability of turbulence generation by shear instability in current velocity and Väisälä-Brunt frequency is obtained. Examples are cited of sections with isoclines of probable turbulence generation in the 30–500-m layer in the Antarctic circumpolar current north of Kergelen island.UDK [551.465.15+551.46.08] (269)     

Hurricane effects on surface gulf stream currents

A 3-dimensional model methodology for predicting the upper ocean currents under the combined influence of Gulf Stream and hurricane is described. Predicted currents are highly dependent on the turbulence closure scheme and nonlinear interactions. New field data will be required to determine the appropriate formulation for turbulent momentum transfer. However, the model points out the importance of nonlinear terms in the equations of motions for preserving the jet-like structure of the Gulf Stream and for properly accounting for interaction between the Gulf Stream and a hurricane. A potentially worst case condition is obtained for the so-called resonant hurricane.     

Phytoplankton productivity in relation to light intensity: A simple equation

A simple exponential equation is used to describe photosynthetic rate as a function of light intensity for a variety of unicellular algae and higher plants where photosynthesis is proportional to (1-e^−β1). The parameter β ( ) is derived by a simultaneous curve-fitting method, where I is incident quantum-flux density. The exponential equation is tested against a wide range of data and is found to adequately describe P vs. I curves. The errors associated with photosynthetic parameters are calculated. A simplified statistical model (Poisson) of photon capture provides a biophysical basis for the equation and for its ability to fit a range of light intensities. The exponential equation provides a non-subjective simultaneous curve fitting estimate for photosynthetic efficiency (a) which is less ambiguous than subjective methods: subjective methods assume that a linear region of the P vs. I curve is readily identifiable. Photosynthetic parameters β and a are used widely in aquatic studies to define photosynthesis at low quantum flux. These parameters are particularly important in estuarine environments where high suspended-material concentrations and high diffuse-light extinction coefficients are commonly encountered.     

The reliability of analytical data for tributyltin (TBT) in sea water and its implications on water quality criteria

To investigate the reliability of analytical data for tributyltin (TBT) in sea water, split water samples were distributed to ten laboratories in six countries. The sub-surface samples comprised: (i) an offshore (0·5 km) water sample, (ii) the same sample but spiked with an undisclosed quantity of TBT standard compound (175 ng TBT⁺ liter⁻¹), and (iii) a sample taken from a yacht marina. The seven acceptable data sets were in good agreement for the spiked sample (178 ± 26 ng TBT⁺ liter⁻¹) but showed a greater variation in concentrations reported for the yacht marina sample (366 ± 93 ng TBT⁺ liter⁻¹). Atomic absorption and gas chromatographic-flame photometric detection techniques produced results of similar accuracy and precision. Samples acidified with 1 ml of 10% (v/v) acetic acid appeared stable for more than 2 weeks when stored refrigerated and in darkness. Analyses of the offshore seawater sample revealed TBT contamination (9 ± 7 ng TBT⁺ liter⁻¹) indicating dispersion of the compound to the shelf waters off Monaco. The spread in values reported by the laboratories demonstrates inherent difficulties in obtaining good precision below approximately 20 ng TBT⁺ liter⁻¹. This observation is discussed with respect to the setting and enforcing of water quality standards.