Stability and phase relations of nonstoichiometric clinopyroxenes in the join diopside-Ca-Eskola component at high pressures

The stability of nonstoichiometric clinopyroxenes in the Di-CaEsk join was experimentally studied, and phase diagrams were constructed for this join at pressures of 2.0 and 3.0 GPa. It was found that melting in the diopside part of the join occurs at anomalously low temperatures, and nonstoichiometric clinopyroxene coexists with a phase approaching diopside in composition. Phase relations along the Di-CaEsk join can be described and consistently interpreted only assuming that the diopside phase (α-diopside) is thermodynamically stable. The following phase volumes were observed along the solidus of the join at a pressure of 3.0 GPa: Cpx, αDi+Cpx, αDi+Cpx+Qtz, αDi+Cpx+Grt+Qtz, Cpx+Grt+Qtz, Cpx+Grt+Ky+Qtz, Grt+Ky+Qtz. Melting occurs via the eutectic reaction αDi+Cpx+Grt+Qtz=L at a temperature of about 1200°C in the diopside part of the system and via the eutectic reaction Cpx+Grt+Ky+Qtz=L at a temperature of 1400°C in the calcium-rich part of the system. At a pressure of 2.0 GPa, melting occurs at temperatures of 1200–1300°C via the eutectic reaction αDi+Cpx+ An + Qtz=L. The invariant equilibrium (L, An, Cpx, Grt, αDi, Qtz) lies within the pressure range 2.0–3.0 GPa. Nonstoichiometric clinopyroxenes form complex solid solutions, the compositions of which are not strictly confined to the Di-CaEsk join and depend on temperature, pressure, and phase association. Grossular garnets coexist with nonstoichiometric clinopyroxenes and α-diopside.     

Quantification of the environmental structural risk with spoiling ties: is randomization worthwhile?

Many recent works show that copulas turn out to be useful in a variety of different applications, especially in environmental sciences. Here the variables of interest are usually continuous, being times, lengths, weights, and so on. Unfortunately, the corresponding observations may suffer from (instrumental) adjustments and truncations, and eventually may show several repeated values (i.e., ties). In turn, on the one hand, a tricky issue of identifiability of the model arises, and, on the other hand, the assessment of the risk may be adversely affected. A possible remedy is to adopt suitable randomization procedures: here three different strategies are outlined. The goal of the work is to carry out a simulation study in order to evaluate the effects of the randomization of multivariate observations when ties are present. In particular, it is investigated whether, how, and to what extent, the randomization may change the estimation of the structural risk: for this purpose, a coastal engineering example will be used, as archetypical of a broad class of models and problems in engineering applications. Practical advices and warnings about the use of randomization techniques are hence given.     

Modeling of deep-seated high-alumina parageneses on the basis of the stability fields of corundum- and spinel-normative assemblages of the system CaO–MgO–Al2O3–SiO2

To elaborate physicochemical models for the origin of crystalline rocks, experimental studies of the field of high-alumina assemblages of the system CaO–MgO–Al₂O₃–SiO₂ were carried out at 10–30 kbar and 1250–1535 °C. We have determined the phase relations between the melt (L) and An, Sp, Cpx, Cor, and Ga, the slope of the rays of the monovariant reactions An + Sp = Cpx + Cor + (Ga) and L = Cpx +Ga + Cor + Sp, the position of the nonvariant point (An, Sp, Cpx, Cor, Ga, L), and the compositions of phases participating in these reactions. Based on a topological analysis of the studied segment of the system CaO–MgO–Al₂O₃–SiO₂, we have substantiated that “eclogitization” must follow the reaction Opx + An + Sp = Cpx + Ga. A fundamental continuous series of eutectic monovariant equilibria was observed: L = Cpx + Opx + Fo + An, L = Cpx + Opx + An + Sp, L = Cpx (+ Ga) + An + Sp, and L = Cpx + Cor (+ Ga) + An. A change in the melt composition in this series of eutectic reactions depending on pressure must reflect the most likely magma genesis trend in nature. Comparision of the composition fields in which the above series of reactions is observed with the composition fields of the rocks of magmatic formations showed that this series is most similar to the alkali-earth series of rocks. The mineralogical compositions of cumulates and phenocrysts found in the effusive and dike varieties of these rocks correspond to unique sets of subsolidus phase associations and individual subsolidus phases crystallizing in this fundamental eutectic series.     

Influence of the saffman force,lift force,and electric force on sand grain transport in a wind–sand flow

Quasi-horizontal trajectories of salting sand grains were found using high-speed video-recording in the desertified territory of the Astrakhan region. The sizes and displacement velocities of the saltating sand grains were determined. A piecewise logarithmic approximation of the wind profile in a quasi-stationary wind–sand flow is suggested, which is consistent with the data of observations and modeling. It was established that, in the regime of stationary saltation, the wind profile in the lower saltation layer of the wind–sand flow depends only slightly on the wind profile variations in the upper saltation layer. The vertical profiles of the horizontal wind component gradient in a quasi-stationary wind–sand flow were calculated and plotted. It was shown using high-speed video recording of the trajectory of a sand grain with an approximate diameter of 95 μm that the weightlessness condition in the desertified territory of the Astrakhan region in a stationary wind–sand flow is satisfied at a height of approximately 0.15 mm. The electric parameters of a wind–sand flow, which can provide for compensation of the force of gravity by the electric force, were estimated. In particular, if the specific charge of a sand grain is 100 μC/kg, the force of gravity applied to the sand grain can be compensated by the electric force if the vertical component of the electric field in a wind–sand flow reaches approximately 100 kV/m. It was shown that the quasi-horizontal transport of sand grains in the lower millimeter saltation layer observed in the desertified territory can be explained by the joint action of the aerodynamic drag, the force of gravity, the Saffman force, the lift force, and the electric force.     

Mesoscale and macroscale aspects of the morning Urban Heat Island around Athens,Greece

Summary This paper examines the characteristics of the morning Urban Heat Island (UHI) in Athens basin, Greece. The study is performed by using and analyzing mesoscale and synoptic data covering the period 1990–2001. The UHI was estimated using the 0600 Local Time (LT) minimum temperature differences between rural and urban areas of the city. The analysis results in 7 UHI classes. A strong UHI was found for the 1/3 of days. The specific meteorological characteristics (surface and upper air, cooling rate) of each UHI class were revealed and examined. The spatial and temporal characteristics of the UHI were also identified. The UHI is largest on nights with clear skies and low relative humidity. In all seasons the UHI switches on rapidly in afternoon. During spring and summer, sea breeze commonly reduces and delays the UHI. Cases documenting the sensitivity and rapidity of changes of the UHI to changes in classes (cloud cover, wind) are also presented. The cooling rate is higher in the urban area under negative and lower under positive UHI conditions. Mesoscale and macroscale phenomena were examined during the different UHI classes through a weather type scheme. It was emerged that high UHI classes are associated with anticyclonic conditions or advection in the lower troposphere, while low UHI classes are associated with strong northeasterly winds. Anticyclonic conditions which frequently occur in spring and early summer, reduce or reverse the UHI to Urban Cooling Island.     

Post-breakup basaltic magmatism along the East Greenland Tertiary rifted margin

Mafic and ultramafic intrusions in East Greenland adjacent to the offshore Greenland–Iceland ridge were emplaced 5–9 My after continental breakup at 55 Ma [1]. Rare earth element (REE) concentrations determined by secondary ion mass spectrometry are reported for cumulus clinopyroxene from these intrusions, and the data are used to estimate REE abundance in equilibrium melts using available partitioning data. Estimated equilibrium melts from intrusions have strongly fractionated REE patterns with Nd/Dy(N) in the range 2 to 5.6 and Yb/Dy(N) 0.55 to 0.92, similar to values for coeval basalts. These melts have markedly higher Nd/Dy(N) than earlier breakup related flood basalts. The moderately low Yb/Dy(N) for the post-breakup volcanism is indicative of residual garnet in the source, while their high Nd/Dy(N) ratios can best be explained by aggregating low degree melts from a light-REE-enriched garnet- and spinel-bearing mantle source. We also report He, Sr, and Nd isotopic data for the intrusions. The highest ³He/⁴He ratios (>10 R/R_a) are found in the samples whose REE data reflect the largest proportion of melts from a garnet-bearing source, and having Sr and Nd isotopic compositions identical with the radiogenic Sr and unradiogenic Nd isotope end of the Iceland compositional field. There is no indication of a MORB-type mantle in the source of the intrusions. We postulate that post-breakup volcanism along the East Greenland coastline reflects the increasing proximity of the mantle plume to the East Greenland continental margin. The low degree of melting at high mean pressure inferred for the parental melts for the intrusions may reflect re-thickening of the lithosphere, which in turn was caused by the vigorous volcanism during breakup, with accompanying depletion of upper mantle and underplating of the crust at the continental margin.     

SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namibia

The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to peraluminous, calc-alkaline granitoids, predominantly with volcanic arc geochemical signatures. The zircon protolith ages for the orthogneisses range from 1861 ± 3 to 1758 ± 3 Ma. Anatexis in the migmatitic Epupa gneisses was dated from a melt patch at 1762 ± 4 Ma, and the anatectic Otjitanda Granite has a zircon age of 1757 ± 4 Ma. Migmatization and anatexis therefore occurred almost immediately after granitoid emplacement and date a widespread high-temperature Palaeoproterozoic event at ∼1760 Ma which has not been recorded elswhere in northern Namibia. The Nd isotopic systematics of all dated samples are surprisingly similar and suggest formation of the protolith from a source region that probably separated from the depleted mantle about 2.4–2.0 Ga ago. A major Archaean component in the source area is unlikely.     

Stable carbon isotope variations in northwest Europe during the last glacial–interglacial transition

Stable carbon isotope data that span part of the last glacial–interglacial transition (ca. 14-9 ka ¹⁴C BP; ca. 15–11 ka cal. BP), and which derive from organ-specific plant macrofossils recovered from two lake sediment profiles in the UK and one in Norway, are compared. The recorded temporal variations show similar trends, which, over a millennial time-scale appear to parallel the main drift in δ¹⁸O as determined for the GRIP ice-core. It is postulated that some smaller scale variations in the δ¹³C profiles may reflect the shorter term oscillations in δ¹⁸O values evident in the GRIP record, although this is less certain. Overall, however, the results suggest that stable carbon isotope measurements based on organ-specific terrestrial plant macrofossils may provide (i) a means for establishing correlations between terrestrial successions and (ii) additional paleoenvironmental information, as the apparent ‘shadowing’ of the GRIP record indicates a common forcing mechanism for both Greenland δ¹⁸O and northwest European δ¹³C variations. From the evidence available we suggest that the recorded δ¹³C variations reflect fluctuations in air temperature and/or changes in water vapour pressure in the atmosphere. © 1997 John Wiley & Sons, Ltd.     

An Investigation of the Influence of Cyclonic Airstreams on Midwestern Snowfall

Although previous climatological studies have investigated the relationship between cyclone frequency and trajectory and regional weather, analyses of structural airflow features and precipitation have been confined to meteorological case studies. In the following paper, the influence of Colorado cyclone airstreams on Midwestern snowfall is investigated using isentropic streamline maps for five cold season months. Results indicate that Colorado cyclones account for a minor percentage of Midwestern snowfall events and amounts. When snowfall is induced by Colorado cyclogenesis, diffluence and instability in the cold sector portions of the cyclone are the dominant lifting mechanisms.     

Import of coastally-derived chlorophylla to South Slough, Oregon

Material transfer between estuaries and the nearshore zone has long been of interest, but information on the processes affecting Pacific Northwest estuaries has lagged behind other areas. The west coast of the U.S. is a region of seasonally variable upwelling that results in enhanced phytoplankton production in the nearshore zone. We examined estuarine-nearshore links over time by measuring physical oceanographic variables and chlorophylla concentration from an anchor station in South Slough, Oregon. Data was collected during 24-h cruises conducted at approximately weekly intervals during summer 1996 and spring 1997. The results demonstrate that the physical oceanography of this estuarine site was strongly influenced by the coastal ocean. Marine water reached the estuarine site on every sampled tide, and chlorophylla was clearly advected into the estuary with this ocean water. In contrast, phytoplankton concentrations were comparatively reduced in the estuarine water. There were, however, large fluctuations in the import of chlorophyll over the course of the summer. These variations likely reflect upwelling-generated phytoplankton production in the coastal ocean and subsequent cross-shelf transport to the estuary. Suspension feeding organisms in South Slough likely depend on the advection of this coastally-derived phytoplankton. The large allochthonous chlorophyll input measured for this system appears dissimilar from most estuaries studied to date. Previous investigations have focused on the outwelling and inwelling of materials in estuaries. We must now consider the influence of coastal upwelling and downwelling processes on estuarine material exchange.