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991.
J.S. Delaney J.V. Smith D.A. Carswell J.B. Dawson 《Geochimica et cosmochimica acta》1980,44(6):857-872
Micas from coarse granular Iherzolites in S. African kimberlites may be separated into two groups; those showing primary textural relationships with coexisting silicates and those with secondary, alteration relationships with other silicates. Primary-textured micas form a tight cluster with a mean composition from 10 coarse garnet lherzolites of: SiO2 41.0, TiO2 0.18, Al2O3 13.5, Cr2O3 0.82, total Fe as FeO 2.60, MnO 0.02, MgO 26.0, NiO 0.22, CaO 0.01, BaO 0.29, Na2O 0.31, K2O 10.0, Rb2O 0.028, Cl 0.08, F 0.43 wt%. Primary-textured micas in aggregates with clinopyroxene have higher TiO2 and four specimens which look similar to the primary group but have textural ambiguities have still higher TiO2Micas with secondary textures have wide ranges of composition which may be correlated with details of the textural parageneses. Micas from kelyphitic rims around garnets tend to be Cr-rich while those from veinlets are Cr-poor. Both groups tend to have higher FeO and TiO2 than the primary group. Micas produced by alteration of, or filling veinlets through, orthopyroxene have a wide compositional range which overlaps that of the primary-textured micas, especially for harzburgite specimens.The primary-textured micas show a positive correlation with coexisting pyroxenes for MgO/(MgO + FeO) and TiO2, but not for Cr2O3. Secondary-textured micas do not show correlations with coexisting pyroxenes for any elements.The ‘primary-metasomatic’ micas described by Harte and Gurney (1975) and metasomatic and other micas described by Boettcher et al. (1979) and Boettcher and O'neil (1979) are richer in FeO and TiO2 than the present primary-textured micas, and are attributed to crystallization from fractionated fluids. 相似文献
992.
Kozlov V. I. 《GeoJournal》1980,4(1):23-30
The paper deals with the processes of ethnic consolidation, ethnic and linguistic assimilation and inter-ethnic integration taking place in the USSR. The author shows the influence of consolidation and assimilation processes over the trends in the numerical strength of individual peoples and the resulting change in the country's ethnic composition as this is reflected in the Soviet population censuses of 1926, 1959, 1970, and 1979. 相似文献
993.
The isotopic composition of strontium of pore water and of authigenic minerals leached from the sediment of core 119K with hot aqua regia is similar to that of the brine in the Discovery deep and differs from that of normal seawater. The average ratio of strontium removed by acid leaching is 0.7077 ± 0.0007 (1σ) compared to a value of 0.70904 for the Red Sea. The detrital silicate fraction exhibits an approximate inverse correlation between ratios and strontium concentrations which provides tentative support for a model in which the detrital silicate fraction of deep-sea sediment is considered to be a mixture of terrigenous dust of sialic composition enriched in radiogenic 87Sr and of volcanogenic material of basaltic composition and low 87Sr abundance. The ratios of the shells of foraminifers and pteropods, expressed as δ 87Sr‰ relative to 0.70904 for seawater, decrease from at 90 cm to at 273 cm and remain constant at this value to a depth of 450 cm. The lowering of the δ 87Sr values is attributed both to the presence of aragonite overgrowths on pteropod shells and to possible isotope exchange with strontium in the connate fluid. 相似文献
994.
T.W Osborn R.G Warren R.H Smith H Wakita D.L Zellmer R.A Schmitt 《Geochimica et cosmochimica acta》1974,38(9):1359-1378
Major and trace element analyses of over 180 individual chondrules from 12 carbonaceous chondrites are reported, including individual analyses of 60 chondrules from Pueblito de Allende. Siderophile elements in most chondrules are depleted, compared to the whole chondrite. Correlations of Al-Ir and Ir-Sc among chondrules high in Ca and Al were observed. A Cu-Mn correlation was also found for chondrules from some meteorites. No correlation was observed between Au and other siderophile elements (Fe, Ni, Co and Ir). It is suggested that these elemental associations were present in the material from which the chondrules formed. Compositionally, chondrules appear to be a multicomponent mixture of remelted dust. One component displaying an Al-Ir correlation is identified as Allende-type white aggregates. The other components are a material chemically similar to the present matrix and sulfides-plus-metal material. Abundances of the REE (rare earth elements) were measured in ‘ordinary’ Allende chondrules and were 50% higher than REE abundances in Mokoia chondrules; REE abundances in Ca-Al rich chondrules were similar to REE abundances in Ca-rich white aggregates. 相似文献
995.
Four paleosols, and soil horizons within paleosols, were clearly identified in the thick calcium carbonate-free loess sections at Timaru, South Island, New Zealand, by changes in the distribution of total phosphorus and calcium phosphate in the upper 2 m to each paleosol. Extractable manganese was also sensitive in identifying paleosols, particularly the upper horizons. The distribution of bulk density values was useful in identifying paleosols; however, the maximum bulk density (>1.7 g/cc) occurred in horizons identified as B2 rather than fragipan horizons in three of four cases. The distribution of clay particles was useful in understanding the genesis of the modern soil and paleosols, but not in identifying paleosols. 相似文献
996.
Gypsum crystals of authigenic origin have been found in manganese nodules of the deep-sea sediment surface (4500-5500 m water depth) from the Central Pacific Ocean. 相似文献
997.
57Fe Mössbauer spectra have been obtained from samples of humic acid, fulvic acid and kerogen and from the organic material extracted from bituminous chalk with benzene-methanol. The spectra indicate that iron occurs in a trivalent form in the silicate residue of the humic acid fraction, as hydrated ferrous ions associated with the fulvic acid fraction, as pyrite in kerogen and in a form not detectable by Mössbauer spectroscopy in the benzene-methanol extract. 相似文献
998.
R.M. Moore J.D. Burton P.J.LeB. Williams M.L. Young 《Geochimica et cosmochimica acta》1979,43(6):919-926
Fractionation by ultra-filtration of the dissolved organic material (DOM) in the River Beaulieu, with typical concentrations of dissolved organic carbon (DOC) of 7–8 mg C/l, showed it to be mainly in the nominal molecular weight range of 103–105, with 16–23% of the total DOC in the fraction > 105. The molecular weight distribution of DOM in the more alkaline River Test (average DOC, 2 mg C/l) was similar. In the River Beaulieu water, containing 136–314 βg Fe/l in ‘dissolved’ forms, 90% or more of this Fe was in the nominal molecular weight fraction > 105. Experiments showed that DOM of nominal molecular weight <105 could stabilize Fe(III) in ‘dissolved’ forms. The concentrations of ‘dissolved’ Fe in the river water probably reflect the presence of colloidal Fe stabilized by organic material and this process may influence the apparent molecular weight of the DOM. Dissolved. Mn (100–136 βg/l) in the River Beaulieu was mainly in true solution, probably as Mn(II), with some 30% in forms of molecular weight greater than ca 104.During mi xing in the Beaulieu Estuary, DOC and dissolved Mn behave essentially conservatively. This contrasts with the removal of a large fraction of the dissolved Fe (Holliday and LISS, 1976, Est. Coastal Mar. Sci. 4, 349–353). Concentrations of lattice-held Fe and Mn in suspended particulate material were essentially uniform in the estuary, at 3.2 and 0.012%, respectively, whereas the non-lattice held fractions decreased markedly with increase in salinity. For Mn the decrease was linear and could be most simply accounted for by the physical mixing of riverborne and marine participates, although the possibility that some desorption occurs is not excluded. The non-linear decrease in the concentration of non-lattice held Fe in particulates reflected the more complex situation in which physical mixing is accompanied by removal of material from the ‘dissolved’ fraction. 相似文献
999.
Portions of the Gunflint Iron Formation, originally a ferruginoussediment, were metamorphosed by the intrusion of the DuluthComplex to assemblages containing: pigeonite (Wo10En24Fs66)+olivine(Fo13Fa37)+Fe-Ti oxide (Mt62Usp34Hc4)+plagioclase (An94Ab6)+vapor+augite (Wo40En20Fs40) or cummingtonite Fe/(Fe+Mg) {smalltilde} 0.69; quartz was present but probably was not in equilibriumwith olivine. Comparison with synthetic phase-equilibrium studiesindicate conditions of initial recrystallization of T 800 °C,Ptotal 2kb, fo2 slightly below that of the pure fayalite-magnetite-quartzassemblage, and PH2O < Ptotal. During the slow cooling process following initial recrystallization,the phases present underwent a complex series of exsolution,inversion, oxidation, and hydration reactions. Pigeonite initiallyexsolved augite along (001), then inverted to orthopyroxene,which then exsolved augite along (100). The augite exsolvedonly pigeonite on (001) during its cooling history. The Fe-Tioxide for the most part oxidized to an intergrowth of magnetiteand ilmenite, although unoxidized portions later exsolved ulvöspinel.Cummingtonite exsolved actinolite, forming irregular patchesof the latter. Olivine, orthopyroxene, and augite reacted withplagioclase to form retrograde amphiboles. Orthopyroxene had difficulty nucleating during this slow coolingprocess, forming only at widely spaced points in mosaics ofprimary pigeonite grains, and never nucleating within primaryaugite grains. The resulting orthopyroxene grains are much largerthan the original pigeonite grains. 相似文献
1000.
Oxygen isotope fractionation between rutile and water 总被引:1,自引:0,他引:1
Synthetic rutile-water fractionations (1000 ln α) at 775, 675, and 575° C were found to be ?2.8, ?3.5, and ?4.8, respectively. Partial exchange experiments with natural rutile at 575° C and with synthetic rutile at 475° C failed to yield reliable fractionations. Isotopic fractionation within the range 575–775° C may be expressed as follows: 1 $$1000\ln \alpha ({\rm T}i{\rm O}_{2 } - H_2 O) = - 4.1 \frac{{10^6 }}{{T_{k^2 } }} + 0.96$$ . Combined with previously determined quartz-water fractionations, the above data permit calibration of the quartz-rutile geothermometer: 1 $$1000\ln \alpha ({\text{S}}i{\rm O}_{2 } - Ti{\rm O}_{2 } ) = 6.6 \frac{{10^6 }}{{T_{k^2 } }} - 2.9$$ . When applied to B-type eclogites from Europe, as an example, the latter equation yields a mean equilibration temperature of 565° C. 相似文献