Grain boundary diffusion in enstatite

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.     

Historical Changes in the Flood Hazard at Khartoum, Sudan: Lessons and Warnings for the Future

The 1988 floods at Khartoum were frequently described as "unprecedented". However, an examination of evidence for floods caused by the Nile and rain storms during the nineteenth and twentieth centuries leads to the conclusion that neither the Nile flood nor the rain storms nor their coincidence in one season were unprecedented and that similar situations will recur.We argue that most problems were created by complacency, lack of planning and mismanagement. We conclude with some simple suggestions for flood amelioration in the future and warn that complacency is the single most important phenomenon likely to recur to the detriment of Greater Khartoum in the future.     

PHOTOGRAMMETRIC DATA CAPTURE: AN INEXPENSIVE ALTERNATIVE

A case is made for the development of an inexpensive and portable data capturing unit which could be used with existing mirror stereoscopes and which could provide an accuracy sufficient for most digital map databases. The results of simulation experiments to test the accuracy of the system are presented.     

A techno-economic comparison of power systems for autonomousunderwater vehicles

This paper compares lead-acid batteries, sodium-sulfur batteries, solid polymer fuel cells and closed-cycle diesel engines for autonomous underwater vehicle (AUV) applications. The service is described in terms of a parametric mission and life cycle. A generic AUV is used as a basis for comparison. Power systems are evaluated by two criteria: (1) submerged endurance capability and (2) life cycle cost. This study determines categories of service for which each power system is preferred. The solid polymer fuel cell can provide greater submerged endurance than other power systems examined. For extremely long duration AUV missions, the fuel cell is the required system, indicating a possible market niche for today's fuel cell technology. Considering cost projections for each power system, the results also show that the SPFC can become cost-competitive with conventional technologies, particularly for services characterized by high levels of utilization     

An Early Investigation Of The Striated Tail Of Comet Hale-Bopp (C/1995 O1)

The Sekanina-Farrell particle fragmentation model for the striated tails of dust comets is successfully applied to two images of comet Hale-Bopp to study the motions of 12 striae in a time span of March 12–15, 1997. There is evidence for recurring outbursts with a periodicity of 11^h21^m, consistent with results based on analysis of dust jets. The ejecta in all the striae appear to have been released from one source on the nucleus between the end of January and the second half of February 1997, some 60 to 40 days before perihelion. The parent particles were subjected to a radiation pressure acceleration of β_p ≃ 0.55 and their fragmentation lifetimes in 11 of the 12 striae were practically constant and equal to 13–15 days, when normalized to 1 AU from the Sun. Brief analysis of Watanabe et al.'s measurements of striae on their images from March 5–9, 1997 shows even shorter fragmentation lifetimes for the parent particles, mostly about 7–11 days at1 AU. This revised version was published online in July 2006 with corrections to the Cover Date.     

Metamorphic evolution of exhumed middle to lower crustal rocks in the Mojave Extensional Belt, southern California, USA

The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H₂O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H₂O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H₂O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.     

Multiple-source localization using GPS technology and receivedarrival time structure analysis in an air-deployed system

An efficient and robust method has been developed to locate multiple impulsive sources in an ocean environment. Global position system (GPS) receivers were installed on sonobuoys to obtain their locations within a few meters of accuracy. A sonobuoy field was deployed in a ring-type pattern. Charges were then set off at arbitrary locations within the ring, High-resolution plots were used to obtain direct path and/or first bottom bounce arrivals on each buoy. A model grid of arrival times was constructed, corresponding to the dimensions of the buoy field. A ray model previously developed here at the Applied Research Laboratories at the University of Texas at Austin (ARL:UT) was used to obtain model travel times. The minimum value of the least-square-type error between the real arrival times and the modeled travel times resulted in an unambiguous location of the source, within the limits of the grid spacing chosen. This value was calculated by picking one receiver as the reference and then summing the timing errors of the remaining receivers relative to the reference. Successive iterations with finer grid spacings result in source localization within the accuracy of the buoy locations. The localization routine was extended by allowing permutations of the pulse arrivals on each buoy to account for multiple sources closely separated in time and/or space. An automated correlation technique is presented as an alternative to the leading edge-detection method used here for obtaining relative arrival times. Two proof-of-concept experiments were performed and some results of data obtained at Lake Travis and the Gulf of Mexico are presented     

TEMPORAL TRENDS IN SOIL PRODUCTIVITY EVALUATIONS*

Studies of soil productivity must compensate for the effects of temporal trends in order to examine the pattern of crop yields along spatial gradients. An analysis of the published yield estimates for 30 soils in 233 counties, however, did not find consistent yield increases over the past three decades. On the contrary, the yield estimates for many soils were markedly uniform since 1972. The uniformity appears to have two causes: the acknowledged difficulty of making yield estimates in a time of increasing variability in soil and crop management, both within and between regions, and surveyors' awareness of data stored in a national soils data base. The effect is to cast doubt on soil productivity data reported in county soil surveys published between 1973 and 1988.