Noble metals in the insoluble carbonaceous substance of black shales and ores: Direct atomic emission data

The way of extraction of insoluble carbonaceous substance (ICS) from black shales and technique of determination of noble metals (NM) in it by direct arc atomic emission analysis (AEA) were developed. The first results are reported on the determination of mineral-bound noble metals in ICS concentrates, which were extracted from the rocks and ores of the Sukhoi Log, Vernyi, Vasil’evskoe, Kuranakh, Daugyztau, Bakyrchik, Kamennoe, El’dorado, and other deposits.     

Ore belts of the Greater Altai and their ore resource potential

The results of comprehensive geological and metallogenic studies of the Greater Altai are presented. This project has been carried out since 1997 under the guidance of Academician G.N. Shcherba. The importance of these investigations is determined by the need to enhance and further develop mineral resources of nonferrous, noble, rare, and other metals for operating mining and metallurgical enterprises of Kazakhstan. The great body of information on the geology, geophysics, and metallogeny of the region obtained over many years has been integrated on the basis of new global tectonics. The Greater Altai embraces the Hercynides of the Rudny Altai, Qalba-Narym, West Qalba, Zharma-Saur, and the adjacent territories of Russia and China. The present-day tectonic units are considered to be detached blocks of ancient continental massifs that drifted in the Paleoasian ocean and then amalgamated into the structure of the Greater Altai during the Hercynian collision. The tectonic and metallogenic demarcation of the studied territory made possible the recognition of the Rudny Altai, Qalba-Narym, West Qalba, and Zharma-Saur ore belts, different in geology, geodynamic evolution, and metallogeny. The formation conditions and localization of volcanic-hosted massive sulfide, gold, and rare-metal deposits pertaining to certain ore-bearing geochronological levels were specified, and the potential of the region for various mineral resources was estimated.     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.     

Effects of sludge pretreatment on sludge reduction in a lab-scale anaerobic/anoxic/oxic system treating domestic wastewater

Excess sludge disposal is one of the serious challenges in biological wastewater treatment. Reduction of sludge production would be an ideal way to solve sludge-associated problems rather than the post-treatment of the sludge produced. In this study, a new wastewater treatment process combining anaerobic/anoxic/oxic system with thermochemical sludge pretreatment was tested in a laboratory scale experiment. In this study, the effects of the sludge pretreatment on the excess sludge production in anaerobic/anoxic/oxic were investigated. The system was operated in two Runs (1 and 2). In Run 1, the system was operated as a reference and in Run 2, a part of the mixed liquid was pretreated thermochemically and was returned to the bioreactor. The average solubilization efficiency of pretreated sludge was found to be about 35 % during the study period of 220 days. Sludge production rate in Run 2 was less than that in Run 1 by about 52 %. Total phosphorous was removed by enhanced biological phosphorous removal with the removal efficiency of 83–87 % and 81–83 % for Run 1 and Run 2, respectively. Total nitrogen removal in Run 2 (79–82 %) was slightly higher than that in Run 1 (68–75 %). The mixed liquor suspended solids/mixed liquor volatile suspended solids ratio was identical after both runs in the range 78–83 %. The effluent water qualities were not significantly affected when operated with thermochemical pretreatment at pH 11 and 60 °C for 3 h during 7 months. From the present study it is concluded that thermochemical sludge pretreatment of anaerobic/anoxic/oxic process plays an important role in reduction of sludge production.     

Chemical evolution and petrogenetic implications of loparite in the layered,agpaitic Lovozero complex,Kola Peninsula,Russia

Summary Lovozero, the largest of the world’s layered peralkaline intrusions, includes gigantic deposits of Nb + REE-loparite ore. Loparite, (Na,Ce,Ca)₂(Ti,Nb)₂O₆, became a cumulus phase after crystallisation of about 35% of the ‘Differentiated Complex’, and its compositional evolution has been investigated through a 2.35 km section of the intrusion. The composition of the cumulus loparite changes systematically upwards through the intrusion with an increase in Na, Sr, Nb and Th and decrease in REE and Ti. This main trend of loparite evolution records differentiation of the peralkaline magma through crystallisation of 1600 m of the intrusion. The formation of the loparite ores was the result of several factors including the chemical evolution of the highly alkaline magma and mechanical accumulation of loparite at the base of a convecting unit. At later stages of evolution, when concentrations of alkalis and volatiles reached very high levels, loparite reacted with the residual melt to form a variety of minerals including barytolamprophyllite, lomonosovite, steenstrupine-(Ce), vuonnemite, nordite, nenadkevichite, REE, Sr-rich apatite, vitusite-(Ce), mosandrite, monazite-(Ce), cerite and Ba, Si-rich belovite. The absence of loparite ore in the “Eudialyte complex” is likely to be a result of the wide crystallisation field of lamprophyllite, which here became a cumulus phase. Received November 6, 2000; revised version accepted January 18, 2001     

Polarization of individual pulses of radio pulsars at the low frequencies 40, 60, and 103 MHz

Measurements of the linear polarization of individual pulses at 40, 60, and 103 MHz are presented for ten pulsars. The degree and position angle of a linear polarization were measured with a temporal resolution of 1–7 ms, and the longitudinal distributions of these parameters were constructed for each pulsar at one or more of these frequencies. These are the first such measurements for pulsars B0031-07, B0320 + 39, B0628-28, and B2217 + 47. Apart from B0628-28, all the pulsars are characterized by the simultaneous presence of orthogonal polarization modes in at least one component of the integral profile. The secondary polarization mode increases at frequencies ≤100 MHz for pulsars whose integrated pulses contain pairs of conal components (B0031-07, B0329 + 54, B0834 + 06, B1133 + 16, B2020 + 28). This is manifested both as an expansion of the longitudinal range where the secondary polarization mode is observed and an increase in its contribution to the emission at a given longitude. New data confirming the dependence of the linear polarization of individual pulses on the intensity and mode of the pulsar emission have been obtained.     

Constraints on the thermal evolution of continental lithosphere from U-Pb accessory mineral thermochronometry of lower crustal xenoliths,southern Africa

U-Pb isotopic thermochronometry of rutile, apatite and titanite from kimberlite-borne lower crustal granulite xenoliths has been used to constrain the thermal evolution of Archean cratonic and Proterozoic off-craton continental lithosphere beneath southern Africa. The relatively low closure temperature of the U-Pb rutile thermochronometer (~400-450 °C) allows its use as a particularly sensitive recorder of the establishment of "cratonic" lithospheric geotherms, as well as subsequent thermal perturbations to the lithosphere. Contrasting lower crustal thermal histories are revealed between intracratonic and craton margin regions. Discordant Proterozoic (1.8 to 1.0 Ga) rutile ages in Archean (2.9 to 2.7 Ga) granulites from within the craton are indicative of isotopic resetting by marginal orogenic thermal perturbations influencing the deep crust of the cratonic nucleus. In Proterozoic (1.1 to 1.0 Ga) granulite xenoliths from the craton-bounding orogenic belts, rutiles define discordia arrays with Neoproterozoic (0.8 to 0.6 Ga) upper intercepts and lower intercepts equivalent to Mesozoic exhumation upon kimberlite entrainment. In combination with coexisting titanite and apatite dates, these results are interpreted as a record of postorogenic cooling at an integrated rate of approximately 1 °C/Ma, and subsequent variable Pb loss in the apatite and rutile systems during a Mesozoic thermal perturbation to the deep lithosphere. Closure of the rutile thermochronometer signals temperatures of 𙠂 °C in the lower crust during attainment of cratonic lithospheric conductive geotherms, and such closure in the examined portions of the "off-craton" Proterozoic domains of southern Africa indicates that their lithospheric thermal profiles were essentially cratonic from the Neoproterozoic through to the Late Jurassic. These results suggest similar lithospheric thickness and potential for diamond stability beneath both Proterozoic and Archean domains of southern Africa. Subsequent partial resetting of U-Pb rutile and apatite systematics in the cratonic margin lower crust records a transient Mesozoic thermal modification of the lithosphere, and modeling of the diffusive Pb loss from lower crustal rutile constrains the temperature and duration of Mesozoic heating to 𙡦 °C for ₞ ka. This result indicates that the thermal perturbation is not simply a kimberlite-related magmatic phenomenon, but is rather a more protracted manifestation of lithospheric heating, likely related to mantle upwelling and rifting of Gondwana during the Late Jurassic to Cretaceous. The manifestation of this thermal pulse in the lower crust is spatially and temporally correlated with anomalously elevated and/or kinked Cretaceous mantle paleogeotherms, and evidence for metasomatic modification in cratonic mantle peridotite suites. It is argued that most of the geographic differences in lithospheric thermal structure inferred from mantle xenolith thermobarometry are likewise due to the heterogeneous propagation of this broad upper mantle thermal anomaly. The differential manifestation of heating between cratonic margin and cratonic interior indicates the importance of advective heat transport along pre-existing lithosphere-scale discontinuities. Within this model, kimberlite magmatism was a similarly complex, space- and time-dependent response to Late Mesozoic lithospheric thermal perturbation.