Laboratory simulation of volatilisation from melts induced by micrometeoroid impacts

The laboratory simulation experiments on volatilization from the melts formed due to micrometeoroid impacts on the lunar surface were carried out. The simulation was performed using modulated laser pulses incident on rocks and minerals in vacuum; in so doing microcraters on the targets, glass particles, condensates were formed and gases solved in the bulk of the rock and mineral grains were released. It is shown that volatilization from only the crater glass layers is negligible, which fully confirms the theoretical predictions of Nussinov and Chernyak.The volatilizations from the drops formed by the micrometeoric impacts can be noticeable. For micron-sized drops, predominant among the others after the impact, the volatilization of Na, K and other volatiles can be up to 10 to 20%. For larger-sized (d10² m) drops the volatilization should lead to the appearance of the significant gradients of the element concentrations over the particle cross-section and as a result of their normalization it leads to the surface enrichment by some elements (Si and others).The mechanism of dust formation due to the surface rocks attack by volatilizing alkaline metals (Naughtonet al.) on the Moon probably is not effective. It is the consequence of such a fact that the condensate of the target materials evaporated due to other simultaneous micrometeoric impacts and had the same (as the target has) elemental composition is the very strong background for volatilizing and condensating alkaline elements.Preliminary conclusions about a possible correlation between the composition and the sizes of dust particles in the Solar system and in the Universe (at similar initial composition) have been drawn.     

Linear force-free fields in the lower corona

We have computed the surface Green's function for linear force-free magnetic fields, where × B = B and is a constant, for application to low coronal levels of the solar atmosphere. Boundary conditions are imposed on the normal component of B on two parallel planes which delineate the force-free volume. This procedure ensures that the magnetic field energy remains bounded, and that the field lines have a smooth behavior. A simple bipolar source distribution is treated and representative field line tracings are shown.     

Doppler radar spectral width broadening due to beamwidth and wind shear

The spectral width observed by Doppler radars can be due to several effects including the atmospheric turbulence within the radar sample volume plus effects associated with the background flow and the radar geometry and configuration. This study re-examines simple models for the effects due to finite beam-width and vertical shear of the horizontal wind. Analytic solutions of 1- and 2-dimensional models are presented. Comparisons of the simple 2-dimensional model with numerical integrations of a 3-dimensional model with a symmetrical Gaussian beam show that the 2-dimensional model is usually adequate. The solution of the 2-dimensional model gives a formula that can be applied easily to large data sets. Analysis of the analytic solutions of the 2-dimensional model for off-vertical beams reveals a term that has not been included in mathematical formulas for spectral broadening in the past. This term arises from the simultaneous effects of the changing geometry due to curvature within a finite beamwidth and the vertical wind shear. The magnitude of this effect can be comparable to that of the well-known effects of beam-broadening and wind shear, and since it can have either algebraic sign, it can significantly reduce (or increase) the expected spectral broadening, although under typical conditions it is smaller than the beam-broadening effect. The predictions of this simple model are found to be consistent with observations from the VHP radar at White Sands Missile Range, NM.     

The Pleistocene history of Wales and the borderland

The Pleistocene rock-stratigraphic record is accorded more or less traditional time-stratigraphic interpretation which was held widely before application of an Irish developmental model in 1960. The following sequence of events are recognised: (1) Complete glaciation, of indeterminate age, which antedated the raised beach interglacial. (2) The raised beach episode which is shown to be the last (Ipswichian) interglacial. (3) The last (Devensian/Weichselian) glaciation, followed by possible readvance in northwest and northeast Wales; prior and subsequent to glaciation periglacial conditions obtained. It is shown that the Irish model, relying heavily as it does on the equation of rock and time stratigraphy, is inapplicable in Wales.     

Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.