Preliminary attempt to characterize the rotation of seafloor in the Pito Deep area of the Easter Microplate using a submersible magnetometer

Several mechanisms have been proposed to account for the rotation of the nearly north-south abyssal hill fabric formed on the East Pacific Rise north of the Easter Microplate to the nearly east-west trends in the northern microplate interior. Proposed mechanisms include rigid microplate rotation, transform fault – parallel shear, and bookshelf faulting during the transfer of lithosphere from the Nazca Plate to the microplate. We used a submersible magnetometer on a NAUTILE dive program to measure the magnetic vector rotation of a pillow basalt and dike spur near Pito Deep, the present location of the tip of the propagating rift system that created the microplate. Our results, although too limited to draw strong conclusions from, suggest clockwise rotations of the seafloor magnetic vectors inconsistent with the transform-parallel shear model, and larger than can be explained solely by rigid microplate rotation.     

Parameter identification of a compliant nonlinear SDOF system in random ocean waves by reverse MISO method

The determination of the drag and inertia coefficients, which enter into the wave force model given by Morison's equation, is particularly uncertain and difficult when a linear spectral model is used for ocean waves, and the structure is compliant and has nonlinear dynamic response. In this paper, a nonlinear System Identification method, called Reverse Multiple Inputs–Single Output (R–MISO) is applied to identify the hydrodynamic coefficients as well as the nonlinear stiffness parameter for a compliant single-degree-of-freedom system. Four different types of problems have been identified for use in various situations and the R–MISO has been applied to all of them. One of the problems requires iterative solution strategy to identify the parameters. The method has been found to be efficient in predicting the parameters with reasonable accuracy and has the potential for use in the laboratory experiments on compliant nonlinear offshore systems.     

Stratal patterns in the southwestern margin of the Ulleung Basin off southeast Korea: sequence architecture controlled by back-arc tectonism

 Major variations in type and rate of tectonic movement in the southwestern margin of the Ulleung Basin coincide in time with changes in stratal patterns at succession boundaries, suggesting that the effect of tectonism was dominant for the development of sequence architecture. During the back-arc opening (16–12 Ma), the rise of relative sea level and the high rate of sediment supply gave rise to sequences with sigmoid progradational patterns. During the back-arc closing (12–6.5 Ma), fall- and rise-dominated relative sea-level fluctuations resulted in sequences with varying stratal patterns depending upon changes in deposition rate. The rise-dominated relative sea level has been prevalent during the later stage (6.5 Ma–Present) with low sedimentation rate. Received: 16 January 1996 / Revision received: 7 February 1997     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.     

An Annotated Check-List of Planktonic Diatoms from the Gulf of Naples

Abstract. New data on the planktonic diatoms from the Gulf of Naples are presented together with those from the literature. Information is given on abundances, seasonal cycles and distributions of 183 taxa, including species, varieties and forms.     

Hydrothermal Metalliferous Sediments and Waters Off the Lesser Antilles

Considerable metal enrichments have been found in hydrothermal fluids and metalliferous sediments off the central Lesser Antilles Volcanic Arc. The elements variably enriched in the fluids as a result of the hydrothermal activity are Fe, Mn, As, Si, B, Li and in the sediments, Fe, P, Mo, As, Sb, Hg, Cu and Pb. Variations in the concentrations of these elements in both fluids and sediments along the arc result from a number of factors, the most important of which is the stage that each island's volcano has reached in its eruptive cycle. Although hydrothermal mineralization on the sea floor off the islands is only low grade, phase separation in the hydrothermal fluids at depth could be leading to higher grade stockwork mineralization below the vent fields or the discharge of metal rich brines on the lower flanks of the volcanic islands.     

A hypothesis for the formation of a mud bank in the Gulf of Papua

The riverine mud that escapes retention in the estuaries and enters the Gulf of Papua appears to be transported southeastward, across depth contours, by the prevailing currents in a series of wind-driven events. The mud deposits to the southeast of the rivers, at the mid-shelf region within a depth range of 40–60 m. Mud transported farther eastward is carried down the continental rise. Coarser riverine sediment (silt and sand) is deposited closer inshore. On the outer shelf (depth >60 m) relict carbonate debris dominates. The area of mud has maximum rates of pelagic and benthic productivity in the gulf.     

A detailed geochemical and rock magnetic study of dredged basalt from the Sheba Ridge,Gulf of Aden

We report the results of petrological, geochemical and rock magnetic studies of basalt dredged from the eastern end of the west Sheba Ridge during cruise 11/1979 of R. R. S. Shackleton to the Western Gulf of Aden. The ridge is part of the Red Sea-Gulf of Aden spreading axis and the basalts are olivine tholeiites. The abundances of some elements are characteristic of normal MORB (mid-ocean ridge basalt) but other elemental abundances suggest affinites with transitional-type MORB.The observed magnetic properties are interpreted in terms of the composition, concentration and microstructure of the magnetic mineral fraction by recourse to the available data on synthetic analogues. The analysis has been carried out in greater detail than has been attempted in previous magneto-petrological studies. It appears that submarine weathering of the magnetic minerals (maghemitization) brings about not only the expected change in composition but also a fall in concentration of the magnetic fraction. This could result from the removal-of-iron oxidation mechanism operating in the submarine environment. It is also found that the fall in remanence with increasing degree of maghemitization is not explicable in terms of the change in composition and concentration of the magnetic minerals. A further influence—probably microstructural change—significantly reduces the remanence intensity.