Solubility of carbon dioxide in aqueous fluids and mineral suspensions at 294 K and subcritical pressures

An experimental investigation has been carried on the solubility of CO₂ in water and 1 M NaCl between 0.3 and 4 MPa, in order to test the validity of the results given by various modelling codes. In addition to experiments with pure fluids, the effect of a range of likely reservoir minerals on CO₂–water interactions, including K-feldspar, kaolinite, calcite, Ca-montmorillonite and Na-montmorillonite were also investigated. In addition to measurements of CO₂ solubility, the pH of the CO₂-saturated suspensions was also measured directly at pressures of up to 1 MPa. The results demonstrate that predictions of CO₂ solubility made with PHREEQC and Geochemist’s Workbench agree to within 20% with the experimental value, provided corrections are first made off-line for the fugacity coefficient of CO₂, while predictions from standalone models are slightly more accurate. In the presence of mineral suspensions, PHREEQC and Geochemist’s Workbench give good results for calcite and kaolinite but underestimate the pH of montmorillonite-bearing assemblages while slightly overestimating the pH of K-feldspar suspensions. These results are significant because they indicate that CO₂-charged fluids reacted with clays may be less acidic than indicated by the models, which will impact predictions of the potential for dissolution of reservoir and cap rock minerals, as well as the potential for leaching of toxic metals.     

A geologic study of the Juan del Grijalva landslide,the most important mass movement during the last century in Mexico

On November 4th 2007, along the Grijalva River in the state of Chiapas, Mexico, has occurred one of the largest landslides ever known. This landslide, known as Juan del Grijalva, destroyed the town of the same name, killing 20 people, and moved 55 million cubic meters of rock and debris down slope to completely block the Grijalva River. In order to understand the characteristics and factors that triggered the Juan del Grijalva landslide, geologic studies were conducted at the site. The results indicate that the landslide was composed of a lithologic sequence of thin-bedded shales and thin to medium-thick-bedded sandstones. This was faulted into several blocks dipping in the same sense as the mass movement. The main triggering factor was the increment of the pore pressure into the lithologic unit due to water saturation after 5 days of heavy rain before the incident. According to records from the last century, the Juan del Grijalva mass movement represents one of the largest mass movements recorded all over the world. The risk conditions of the area after the landslide lead to the rapid construction of an artificial channel to drain the accumulating mass of water upstream and therefore prevent a future catastrophic inundation down stream.     

Composition of hydrous melts in equilibrium with quartz eclogites

Summary Compositions of the hydrous melts in equilibrium with garnet, omphacitic clinopyroxene and quartz have been investigated experimentally at 28.5 and 35 kbar. They are represented by silica-rich liquids (> 70% SiO₂) with low MgO, FeO and CaO contents. The removal of ca 10–15% of the magma of this composition may be sufficient to convert quartz eclogite formed after subduction of altered MORB into a quartz-free bimineralic eclogite assemblage, which is a common type of xenoliths in kimberlites.At 28.5 kbar the solidus temperature is between 700 and 750° C in the system quartz eclogite—water, and the high pressure amphibole-out boundary lies at ca 25 kbar in accord with the previous studies.

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Die Zusammensetzung wasserhältiger Schmelzen im Gleichgewicht mit Quarz-Eklogiten

Zusammenfassung Um Prozesse zu simulieren, die bei der Subduktion von Ozeanbodenbasalten durch partielle Anatexis im Stabilitätsfeld von Eklogiten ablaufen, wurde die Zusammensetzung wasserhältiger Schmelzen in Gleichgewicht mit Granat, Omphacit und Quarz bei 28.5 und 35 Kbar experimentell untersucht. Diese Schmelzen sind reich an SiO₂ (> 70 Gew%) und arm an Mg0, Fe0 and CaO. Die Extraktion von ca. 10–15% derartiger Schmelzen würde genügen, um quarzführende Eklogite, die durch die Subduktion von alteriertem MORB Material entstanden sind, in quarzfreie bimineralische Eklogite umzuwandeln wie sie häufig als Xenolithe in Kimberliten beobachtet werden.Im System Quarz-Eklogit-Wasser liegt die Solidustemperatur bei 28.5 Kbar zwischen 700 und 750°C. Die obere Stabilitätsgrenze von Amphibol liegt in diesem Temperaturbereich bei ca. 25 Kbar.

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With 1 Figures     

Aerodynamic Parameters of a UK City Derived from Morphological Data

Detailed three-dimensional building data and a morphometric model are used to estimate the aerodynamic roughness length z ₀ and displacement height d over a major UK city (Leeds). Firstly, using an adaptive grid, the city is divided into neighbourhood regions that are each of a relatively consistent geometry throughout. Secondly, for each neighbourhood, a number of geometric parameters are calculated. Finally, these are used as input into a morphometric model that considers the influence of height variability to predict aerodynamic roughness length and displacement height. Predictions are compared with estimations made using standard tables of aerodynamic parameters. The comparison suggests that the accuracy of plan-area-density based tables is likely to be limited, and that height-based tables of aerodynamic parameters may be more accurate for UK cities. The displacement heights in the standard tables are shown to be lower than the current predictions. The importance of geometric details in determining z ₀ and d is then explored. Height variability is observed to greatly increase the predicted values. However, building footprint shape only has a significant influence upon the predictions when height variability is not considered. Finally, we develop simple relations to quantify the influence of height variation upon predicted z ₀ and d via the standard deviation of building heights. The difference in these predictions compared to the more complex approach highlights the importance of considering the specific shape of the building-height distributions. Collectively, these results suggest that to accurately predict aerodynamic parameters of real urban areas, height variability must be considered in detail, but it may be acceptable to make simple assumptions about building layout and footprint shape.     

Hydrometeorological conditions in the Barents Sea during El Niño of 1997–1998

Interadapted fields of main hydrophysical characteristics in the vicinity of hydrological sections carried out in 1997–1998 in the Barents Sea are obtained on the basis of model computations. The complex analysis of these materials and atmospheric situation in the region during 1997–1998 enabled to estimate quantitatively the variations of significant hydrodynamic conditions: the decrease in the inflow of rather warm and salty North Atlantic waters and the compensation inflow of polar waters, the decrease in total heat content and the weakening of water dynamics in the system of the general cyclonic circulation, and the increase in the ice coverage of the Barents Sea in anomalously cold winter 1997/98. It is revealed with a high degree of the confidence probability that the significant deviations from the normal conditions occur in response to the global El Niño disturbance which took place in the same years with the maximum values of the Southern Oscillation Index in January–March 1998.     

Visual comparison of computer aided landsat map and air photo map : A case study from Karimnagar district Andhra Pradesh

The use of aerial photo-interpretation technique in preparing an applied hydromorphological map is discussed. The practical utility of the map for ground water exploration in granitic terrain is presented. An attempt to prepare a similar map using LANDSAT CCT by analysis through a Multispectral Data Analysis System and the relative merits of computer aided map and aerial photo map are discussed. The details available in aerial photo map have been found to be lacking in computer aided map. Visual interpretation of LANDSAT imagery can improve the computer aided classification results.     

Using an inerter‐based device for structural vibration suppression

This paper proposes the use of a novel type of passive vibration control system to reduce vibrations in civil engineering structures subject to base excitation. The new system is based on the inerter, a device that was initially developed for high‐performance suspensions in Formula 1 racing cars. The principal advantage of the inerter is that a high level of vibration isolation can be achieved with low amounts of added mass. This feature makes it an attractive potential alternative to traditional tuned mass dampers (TMDs). In this paper, the inerter system is modelled inside a multi‐storey building and is located on braces between adjacent storeys. Numerical results show that an excellent level of vibration reduction is achieved, potentially offering improvement over TMDs. The inerter‐based system is compared to a TMD system by using a range of base excitation inputs, including an earthquake signal, to demonstrate how the performance could potentially be improved by using an inerter instead of a TMD. Copyright © 2013 John Wiley & Sons, Ltd.     

Thermal emission spectroscopy (5.2-38 μm) of three Trojan asteroids with the Spitzer Space Telescope: Detection of fine-grained silicates

We present thermal emission spectra (5.2-38 μm) of the Trojan asteroids 624 Hektor, 911 Agamemnon, and 1172 Aneas. The observations used the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. Emissivity spectra are created by dividing the measured Spectral Energy Distribution (SED) by a model of the thermal continuum. We employ the Standard Thermal Model (STM), allowing physical parameters (e.g., radius and albedo) to vary in order to find the best thermal continuum fit to the SED. The best-fit effective radius (R) and visible geometric albedo (pv) for Hektor (R=110.0±7.3, ) and Aneas (R=69.1±5.1, ) agree very well with previous estimates, and for Agamemnon (R=71.5±5.2, ) we find slightly a smaller size and higher albedo than previously derived. Other thermal models (e.g., thermophysical) result in estimates of R and pv that vary a few percent from the STM, but the resulting emissivity spectra are identical. The emissivity spectra of all three asteroids display an emissivity plateau near 10-μm and another broader rise from ∼18 to 28 μm. We interpret these as indications of fine-grained silicates on the surfaces of these asteroids. The emissivity spectra more closely resemble emission spectra from cometary comae than those from solid surfaces and measured in the laboratory for powdered meteorites and regolith analogs. We hypothesize that the coma-like emission from the solid surfaces of trojans may be due to small silicate grains being imbedded in a relatively transparent matrix, or to a very under-dense (fairy-castle) surface structure. These hypotheses need to be tested by further laboratory and theoretical scattering work as well as continued thermal emission observations of asteroids.     

Seasonal Diatom Variability and Paleolimnological Inferences – A Case Study

The seasonality of physical, chemical, and biological water variables is a major characteristic of temperate, dimictic lakes. Yet, few investigations have considered the potential information that is encoded in seasonal dynamics with respect to the paleolimnological record. We used a one-year sequence of diatoms obtained from sediment traps and water samples, as well as the sedimentary diatom record covering the past ca. 1000 years in Bates Pond, Connecticut (USA), to investigate which variables influence the seasonal distribution of diatoms and how this can be used for the interpretation of the fossil record. The seasonal patterns in diatom assemblages were related to stratification and, to a lesser extent, to nitrate, silica, and phosphorus. During mixing periods in spring and autumn, both planktonic and benthic species were collected in the traps, while few lightly silicified, spindle-shaped planktonic diatoms dominated during thermal stratification in summer. Changes in fossil diatom assemblages reflected human activity in the watershed after European settlement and subsequent recovery in the 20th century. A long-term trend in diatom assemblage change initiated before European settlement was probably related to increased length of mixing periods during the Little Ice Age, indicated by the increase of taxa that presently grow during mixing periods and by application of a preliminary seasonal temperature model. We argue that the analysis of seasonal diatom dynamics in temperate lakes may provide important information for the refinement of paleolimnological interpretations. However, investigations of several lakes and years would be desirable in order to establish a more robust seasonal data set for the enhancement of paleolimnological interpretations.     

Assessing redox properties of standard humic substances

Redox properties of humic substances (HS) control important biogeochemical processes. Thus, accurate estimation of redox properties of HS is essential. However, there is no general consensus regarding the best available measurement method of HS redox properties. In this study, we compared several common HS redox property measurement methods using anthraquinone-2,6-disulfonate (AQDS) as model compound, and standard Elliot soil humic acid (1S102H, ESHA), reference Pahokee peat (1R103H, PPHA), and Suwannee River natural organic matter (1R101N, SRNOM) as representative HS. We found that the H₂/Pd reduction method followed by incubation with ferric citrate (FeCit) reagent was incomplete, and the H₂/Pd reduction method followed by incubation with potassium ferricyanide (K₃Fe(CN)₆) was insensitive. Stannous chloride (SnCl₂) reduction followed by titration of excess stannous (Sn²⁺) by potassium dichromate (K₂Cr₂O₇) was found to be most accurate. These findings will help in future investigations on detailed characterizations of functional groups of HS responsible for oxidation/reduction reactions.