Pattern-Recognition-Verfahren in der Umweltanalytik und Ökotoxikologie: Methodische Grundlagen

Modern methods of analyses of environment yield multivariate data sets of measured objects which are used as the basis of the evaluation and interpretation of substances, differentiated effects, but also of samples or processes. The integrated evaluation and assessment of such multivariate data requires the application of mathematical-statistical methods, the method of pattern recognition being particularly suitable. Pattern recognition program systems constitute a compilation of different methods, as e.g. the multivariate linear regression, classification methods (discriminant analysis, multivariate variance analysis), cluster algorithms, multidimensional scaling, factorial analysis. A few possibilities of such pattern comparisons and identifications are represented by the example of gas chromatography and of the structure/effect analysis for the mutagenity to be expected of 117 substances.     

Kimberlite metasomatism at Murowa and Sese pipes, Zimbabwe

Metasomatism accompanying kimberlite emplacement is a worldwide phenomenon, although infrequently described or recognised. At the Cambrian-aged Murowa and Sese kimberlite clusters located within the Archean Zimbabwe Craton just north of the boundary with the Limpopo Mobile Zone in southern central Zimbabwe, the metasomatism is intense and well exposed and the processes can be readily studied. Dykes, sills and the root zones of pipes are exposed at the current erosion level. Kimberlite lithologies present are hypabyssal macrocrystic kimberlite (“HMK”), HMK breccia, and tuffisitic kimberlite breccia (“TKB”) including minor lithic tuffisitic kimberlite breccia (“LTKB”). Country rocks are 2.6 Ga Chibi and Zimbabwe granite batholiths emplaced into 2.6–2.9 Ga or earlier Archean tonalitic gneiss and greenstones. During initial metasomatism, the granites become spotted with green chlorite, needles of alkaline amphiboles (winchite, riebeckite, arfvedsonite) and pyroxenes (aegirine–augite) with minor carbonate and felts of talc. Oligoclase feldspar becomes converted to albite, extensively altered, dusted and reddened with hematite, whereas K-feldspar remains unaffected. The granites become converted to syenite through removal of quartz. More intense metasomatism at Murowa and Sese results in veins of green metasomatite which cut and disrupt the granite. Progressive disruption entrains granite blocks, breaking down the granite still further, spalling off needle-like granite slivers, and so giving rise to LTKB. This process of disruption and entrainment appears to be the manner of initial development of the pipe structure. The chemistry of the metasomatite is intermediate between granite and kimberlite. Compared to granite country rock it has markedly higher Mg, Cr, Ni, CO₂ and H₂O+, higher Ca, Mn, Nb, Sr, P, Fe³⁺/Fe²⁺ ratio, U, Co, and Cu, approximately equal TiO₂, K₂O, Na₂O, La, Ta, Rb, Zr, Zn and resultant lower SiO₂, Al₂O₃, Ga and Y. The metasomatite Na₂O/K₂O ratio is slightly higher than that of the granite. The metasomatic process is broadly analogous to fenitisation of granitic wall rock accompanying carbonatite complex emplacement. The metasomatism at Murowa and Sese was caused by fluids from the rising but confined proto-kimberlite melt penetrating into cracks and matrix of granite country rock and reacting with it. These fluids were CO₂-rich, hydrous, oxidising, enhanced in ultramafic elements and carried low levels of Na.     

Late Dinantian palaeokarst of England and Wales: implications for exposure surface development

Palaeokarst is an important feature of late Dinantian exposure surfaces. Soil-filled depressions are widely developed. These are comparable to modern day solution dolines and were probably interspersed by areas of relatively bare limestone pavement. The palaeokarst primarily exhibits a smooth, mamillated to potholed surface form, consistent with its formation beneath a soil cover. Areas between the depressions have been extensively stylolitised and would likely have originally been characterized by small-scale fretted and sculpted karren forms typical of subaerial karstification. Palaeokarst pits making up the depressions are thought to have been initiated through stem-flow drainage from trees. Rain water, intercepted by the crown of the tree, was concentrated at specific sites on the emergent surface and dissolution beneath the trunk produced cylindrical pits that propagated vertically downwards. Trees responsible for concentrating drainage may also have enhanced the acidic nature of the rain water through leaching of organic acids from foliar and woody tissues. Downward propagation of the pits was limited to the uppermost 1–2 m and enlargement primarily occurred through lateral amalgamation of adjacent pits. Once initiated, continued development of the depressions would have been self perpetuating; the preferential accumulation of volcanic ash and organic matter enhancing water retention and encouraging further vegetation growth. In contrast, intervening areas would have been characterized by slow vertical denudation only. Karstification likely took of the order of a few hundred years in the case of potholed palaeokarstic surfaces formed solely by stem-flow drainage, to a few tens of thousands of years where the palaeokarst is more mature.     

Mineralogical and Geochemical Constraints on the Sediment Sources of Late Stone Age Pottery from the Birimi Site,Northern Ghana

The mineralogy and bulk chemical compositions of 15 Kintampo (Late Stone Age) potsherds from the Birimi site on the Gambaga Escarpment and eight samples of local sediment were determined with the intent of characterizing these wares and identifying the material used in their manufacture. Sediment from clay pits still used by potters north of the escarpment contains iron‐rich laterite clasts (100 × XFeO_t = 100 × FeO_t/[FeO_t + Al₂O₃ + SiO₂] ≥10). Sedimentary clasts in stream sediments are relatively siliceous and iron‐poor (100 × XFeO_t < 10). Bulk geochemical data together with the compositions of lithic clasts (laterite, siltstone/sandstone) link the pottery to sediment sources, including escarpment sediments not presently used by Ghanaian potters. Fresh granite clasts found in some of the sherds were not found in the analyzed sediment samples, although some of their distinctive mineralogical constituents (e.g., variably barian alkali feldspar) are present. The analytical data suggest that pots found at Birimi were made locally by mixing escarpment sediment with clay and stream sediment brought in from below the escarpment. This contrasts with present‐day practice, whereby the pots themselves are imported. The place where Birimi pottery was made and the outcrop source of aluminous sediment (mudstone with an “escarpment” trace element signature) used in these wares, however, remain unidentified. © 2013 Wiley Periodicals, Inc.     

Magnetic anomalies across Campbell Plateau,New Zealand

Magnetic measurements over the Campbell Plateau, New Zealand, show the existence of a linear positive anomaly belt which extends for 900 km along an approximately east-west trend. This anomaly belt is considered to be a continuation of the Stokes Magnetic Anomaly occurring through New Zealand and associated with rocks of the New Zealand Geosyncline. If this is so, a transcurrent fault with a dextral displacement of about 330 km and aligned in a northeast-southwest direction must occur between the eastern end of the Stokes Magnetic Anomaly and the western end of the anomaly belt across Campbell Plateau.     

Thickness and spatial distributions of clastic dykes, northwest Sacramento Valley, California

The geometry and distribution of the clastic dykes of the Ono district, North Sacramento Valley are examined within stream sections. Five traverses along dry stream beds provide good exposure allowing the spacing, thickness and geometry of the dykes to be recorded. The spatial and thickness distribution of the dykes are considered using cumulative frequency plots, allowing a visual estimation of a best fit distribution. Dyke thickness conforms best to a log-normal distribution. There is also a characteristic minimum dyke thickness in a traverse and this is attributed to the minimum aperture that a fluid with sand clasts is able to exploit. Dyke spacing, however, shows a good correlation with a power-law distribution for four traverses, suggesting that there is a mechanistic control on the spatial distribution. Plotting dyke thickness against minimum dyke spacing reveals that thin dykes do not generally intrude in isolation. Unlike veins and igneous dykes, clastic dykes continue to provide preferential pathways for fluid flow, subsequent to their intrusion, thus inhibiting intrusion in the area surrounding a pre-existing dyke. A combination of this process and dyke branching provides the best model for the observed spatial and thickness distribution of clastic dykes seen in the Ono district, California.     

Pollution monitoring with meiofauna,using the ratio of nematodes to copepods

The ratio of nematodes to copepods was calculated for meiofauna samples from 17 beaches and additional values for intertidal and sublittoral sites were obtained from the literature. Intertidal ratios increased with decreasing particle size, but ratios from polluted sites were always extremely high. Sublittoral ratios increased with depth. It is suggested that this ratio has potential for monitoring organic pollution of sandy beaches.     

Interactive effects of the type of milling media and CuSO4 addition on the flotation performance of sulphide minerals from Merensky ore Part II: Froth stability

The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (k_t and k_w). The rate constant (k_w) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and k_t was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically.