Cobalt zoning in microscopic pyrite from Kamoto,Republic of the Congo (Kinshasa)

The Kamoto deposit consists of two stratiform orebodies separated by a barren sedimentary unit. It is a copper and cobalt deposit, the main features of which are summarized in the first part of the paper. Above the upper orebody, dolostone beds are found, where pyrite is the only sulfide mineral. This pyrite was investigated with the help of a microprobe: all idiomorphic grains were found to be surrounded by a well-defined rim, where the cobalt content reaches 4%; framboidal grains were also found to be heterogeneous with respect to cobalt. The distribution of nickel and copper is described. These observations afford one more evidence that post-depositional events played an important role in the Mine Series of Katanga, especially with regard to heavy metals geochemistry.

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Resume Le gisement de Kamoto est constitué de deux corps minéralisés stratiformes séparés par une unité sédimentaire stérile. C'est un gisement de cuivre et de cobalt dont les principales caractéristiques sont brièvement résumées. Audessus du corps minéralisé supérieur, on trouve des couches de dolomie, où la pyrite est le seul sulfure présent. Cette pyrite a été étudiée à l'aide d'une microsonde: tous les grains idiomorphes y sont entourés d'une bordure bien nette, où la teneur en cobalt atteint 4%; les grains d'apparence framboïdale sont également hétérogènes au point de vue de leur teneur en cobalt. La distribution du nickel et du cuivre est décrite. Ces observations apportent um témoignage supplémentaire de l'importance des événements postérieurs au dépôt dans la «Série des Mines» katangaise, tout spécialement en ce qui concerne la géochimie des métaux lourds. Elles démontrent que le «système» constitué par la roche sédimentaire est resté ouvert pendant un certain temps après la sédimentation.

     

P travel-times from Nevada Test Site explosions and the determination of average global P travel-times

An analysis of P travel-times from the Nevada Test Site is carried out using data from 23 explosions between 1966 and 1976. Results show a scatter of travel times which may partly arise in the lower mantle. P travel-times over the distance range 25–100° are 2.0–2.5 s faster than the Jeffreys-Bullen travel times.     

Hypoxia in the northern Gulf of Mexico: Does the science support the Plan to Reduce,Mitigate, and Control Hypoxia?

We update and reevaluate the scientific information on the distribution, history, and causes of continental shelf hypoxia that supports the 2001 Action Plan for Reducing, Mitigating, and Controlling Hypoxia in the Northern Gulf of Mexico (Mississippi River/Gulf of Mexico Watershed Nutrient Task Force 2001), incorporating data, publications, and research results produced since the 1999 integrated assessment. The metric of mid-summer hypoxic area on the LouisianaTexas shelf is an adequate and suitable measure for continued efforts to reduce nutrients loads from the Mississippi River and hypoxia in the northern Gulf of Mexico as outlined in the Action Plan. More frequent measurements of simple metrics (e.g., area and volume) from late spring through late summer would ensure that the metric is representative of the system in any given year and useful in a public discourse of conditions and causes. The long-term data on hypoxia, sources of nutrients, associated biological parameters, and paleoindicators continue to verify and strengthen the relationship between the nitratenitrogen load of the Mississippi River, the extent of hypoxia, and changes in the coastal ecosystem (eutrophication and worsening hypoxia). Multiple lines of evidence, some of them representing independent data sources, are consistent with the big picture pattern of increased eutrophication as a result of long-term nutrient increases that result in excess carbon production and accumulation and, ultimately, bottom water hypoxia. The additional findings arising since 1999 strengthen the science supporting the Action Plan that focuses on reducing nutrient loads, primarily nitrogen, through multiple actions to reduce the size of the hypoxic zone in the northern Gulf of Mexico.     

85 Peg A: what age for a low-metallicity solar-like star?

We explore the possible evolutionary status of the primary component of the binary 85 Pegasi, listed as a target for asteroseismic observations by the MOST satellite. In spite of the assessed 'subdwarf' status, and of the accurate distance determination from the Hipparcos data, the uncertainties in the metallicity and age, coupled with the uncertainty in the theoretical models, lead to a range of predictions on the oscillation frequency spectrum. Nevertheless, the determination of the ratio between the small separation in frequency modes, and the large separation as suggested by Roxburgh, provides a very good measure of the star age, quite independent of the metallicity in the assumed uncertainty range. In this range, the constraint on the dynamical mass and the further constraint provided by the assumption that the maximum age is 14 Gyr limits the mass of 85 Peg A to the range from 0.75 to  0.82 M_⊙  . This difference of a few hundredths of a solar mass leads to well detectable differences both in the evolutionary stage (age) and in the asteroseismic properties. We show that the age determination which will be possible through the asteroseismic measurements for this star is independent either of the convection model adopted or the microscopic metal diffusion. The latter conclusion is strengthened by the fact that, although metal diffusion is still described in an approximate way, recent observations suggest that real stars suffer a smaller metal sedimentation compared with the models.     

The diagenetic production of α-keto acids in heated and fossil Chione shells

Both pyruvic and α-ketobutyric acids are formed during heating experiments with modern Chione shells. These α-keto acids are also present in fossil specimens. These findings provide additional evidence that the dehydration reaction of free serine and threonine or the β-elimination reaction of peptide bound serine and threonine occurred in fossil materials. These experiments suggest that the formation of α-keto acids occurs early in protein diagenesis. A large fraction of the α-keto acids which were formed have been lost either by subsequent reactions or by diffusion out of the shell matrix.     

Estimation of abl Parameters Using the Vertical Velocity Measurements of an Acoustic Sounder

The friction velocity, the surface heat flux and the height of the Atmospheric Boundary Layer (ABL) are important parameters. In this work, vertical velocity variance ( _w ² ) and wind velocity structure parameter (C _v ² ) profiles estimated by acoustic sounder measurements are used, along with similarity relations, to estimate these parameters in the unstable Atmospheric Boundary Layer and the friction velocity in the stable one. The data were collected by two acoustic sounders with different height range and resolution under various atmospheric conditions (stability) and at two experimental sites in different terrain. The C _v ² profiles are estimated using gate difference of the vertical velocity measurements and the assumption of local isotropy. The vertical velocity data are corrected for the significant effects of noisy measurements and sampling volume averaging on the _w ² and C _v ² estimations using original techniques that are presented in this work. The results of the similarity method using acoustic sounder data are compared against estimates of the corresponding atmospheric parameters obtained from direct measurements. The comparison confirms the ability of the method to provide reasonably accurate estimates of these parameters especially in the middle of the day.     

European Phanerozoic metallogenesis

Phanerozoic metallogenesis in Europe displays divergent characteristics which may be related to the variable nature of the three great European Phanerozoic orogens: Caledonian, Variscan and Alpine. These reflect different geodynamic processes. The Caledonian orogen resulted from the interaction of essentially oceanic with continental lithosphere, whilst the Variscan and Alpine orogens evolved mainly from continent-continent collisions with the involvement of a series of smaller oceanic basins. Each major stage of the orogenic processes is characterised by a typical metallogeny. The occurrence of subduction-related processes in the Caledonian orogeny gave rise to extensive VHMS deposition with characteristic Zn:Cu ratio signatures. The relative lack of abundance of metal-rich, Andean-type porphyry-type mineralisation remains unexplained, unless present erosional levels have prevented the preservation of such deposits. Continent-continent collisions do not appear to result in extensive mineralisation unless elevated heat flows result, possibly as a result of lithospheric delamination at the peak collisional stage. The development of late stage and peri-orogenic sedimentary basins are characterised by extensive Pb-Zn-Ba-F mineralisation as expressions of basinal fluid flow of regional dimensions.     

Two-Dimensional Periodic Waves in an Inviscid Continuously Stratified Fluid

Izvestiya, Atmospheric and Oceanic Physics - In this paper we study the propagation of two-dimensional periodic waves in an inviscid continuously stratified fluid with a free surface in the...     

Lunar nomenclature: A dissenting note

This note reviews the nature of the traditional (Mädler) lunar nomenclature and the recent developments based on the use of more than 2000 named provinces. It appears that the new nomenclature is less efficient than the old in many cases and may lead to an impossible publication situation. The unnecessary break with the past is especially critized.