Transmission electron microscopy of subsolidus oxidation and weathering of olivine

Olivine crystals in basaltic andesites which crop out in the Abert Rim, south-central Oregon have been studied by high-resolution and analytical transmission electron microscopy. The observations reveal three distinct assemblages of alteration products that seem to correspond to three episodes of olivine oxidation. The olivine crystals contain rare, dense arrays of coherently intergrown Ti-free magnetite and inclusions of a phase inferred to be amorphous silica. We interpret this first assemblage to be the product of an early subsolidus oxidation event in the lava. The second olivine alteration assemblage contains complex ordered intergrowths on (001) of forsterite-rich olivine and laihunite (distorted olivine structure with Fe³⁺ charge balanced by vacancies). Based on experimental results for laihunite synthesis (Kondoh et al. 1985), these intergrowths probably formed by olivine oxidation between 400 and 800°C. The third episode of alteration involves the destruction of olivine by low-temperature hydrothermal alteration and weathering. Elongate etch-pits and channels in the margins of fresh olivine crystals contain semi-oriented bands of smectite. Olivine weathers to smectite and hematite, and subsequently to arrays of oriented hematite crystals. The textures resemble those reported by Eggleton (1984) and Smith et al. (1987). We find no evidence for a metastable phase intermediate between olivine and smectite (M — Eggleton 1984). The presence of laihunite exerts a strong control on the geometry of olivine weathering. Single laihunite layers and laihunite-forsteritic olivine intergrowths increase the resistance of crystals to weathering. Preferential development of channels between laihunite layers occurs where growth of laihunite produced compositional variations in olivine, rather than where coherency-strain is associated with laihunite-olivine interfaces.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

Geochemistry and Intrusive History of the Ashland Pluton, Klamath Mountains, California and Oregon

The Ashland pluton is a calc-alkaline plutonic complex thatintruded the western Paleozoic and Triassic belt of the KlamathMountains in late Middle Jurassic time. The pluton comprisesa series of compositionally distinct magma pulses. The oldestrocks are hornblende gabbro and two-pyroxene quartz gabbro withinitial ⁸⁷Sr/⁸⁶Sr = 0{dot}7044, ¹⁸O = 8{dot}7%, and REE patternswith chondrite normalized La/Lu = 7. These units were followedby a suite of tonalitic rocks (La_N/Lu_N = 7) and then by a suiteof K₂O- and P₂O₅ rocks of quartz monzodioritic affinity (La_N/Lu_N= 13–21; La_N/Sm_N = 2{dot}4–3{dot}) The quartz monzodioriticrocks were then intruded by biotite granodiorite and granitewith lower REE abundances but more fractionated LREE(La_N/Lu_N= 13–19; La_N/Sm_N = 4{dot}3–6 and they, in turn,were host to dikes and bosses of hornblende diorite. The latestintrusive activity consisted of aplitic and granitic dikes.Combined phase equilibria and mineral composition data, indicateemplacement conditions of approximately P_total = 2{dot}3kb,P_H2O between 1{dot}5 and 2{dot}2 kb, and f_O2 between the nickel-nickeloxide and hematite-magnetite buffers. Successive pulses of magma display increasing SiO₂ togetherwith increasing ¹⁸O and decreasing initial ⁸⁷Sr/⁸⁶Sr. The isotopicdata are consistent with either (1) combined fractional crystallizationof andesitic magma and concurrent assimilation of crustal materialcharacterized by low Sr₁ and high (¹⁸O or, more probably, (2)a series of partial melting events in which sources were successivelyless radiogenic but richer in ¹⁸O Each intrusive stage displaysevidence for some degree of crystal accumulation and/or fractionalcrystallization but neither process adequately accounts fortheir compositional differences. Consequently, each stage appearsto represent a distinct partial melting or assimilation event. The P₂O₅-rich nature of the quartz monzodiorite suite suggestsaccumulation of apatite. However, the suite contains abundantmafic microgranitoid enclaves and most apatite in the suiteis acicular. These observations suggest that magma mixing affectedthe compositional variation of the quartz monzodiorite suite.Mass balance calculations are consistent with a simple mixingprocess in which P₂O₅-rich alkalic basalt magma (representedby the mafic microgranitoid enclaves) was combined with a crystal-poorfelsic magma (represented by the tonalite suite), yielding aquartz monzodioritic magma that then underwent differentiationby crystal fractionation and accumulation.     

Interaction of S- and L-bursts in Jupiter's decametric radio spectra

Dynamic spectra of Jupiter's decametric emission are observed with a high-resolution radio spectrograph. Certain events observed in region Io-B display interaction effects between the S- and L-emissions. The effect appears as a gap in the L-emission after a passage of an S-burst. In a typical case the L-emission has a relatively narrow bandwidth, the S-burst appears as a sloping line crossing it, and the duration of the emission gap is a substantial fraction of a second. The gap has sharp, sloped edges; its leading edge has anf-t slope which is the same as that of the S-burst while the slope of the trailing edge is lower. A kind of tilted V-pattern is thus formed. It is suggested that some more complicated spectral patterns may also be produced this way. It seems that an emission model consisting of S-bursts from bunches of gyrofrequency-emitting electrons ascending a flux tube and interacting with L-emitting bunches of electrons having more stationary guiding centers is inadequate to explain the complex S-L interactions.Contribution of No. 36 of the Department of Astronomy, University of Florida, U.S.A.     

Hypersensitization of Kodak infrared plates: Results of some chemical methods and pre-exposure

Tests have been carried out on Kodak Spectroscopic Plates Type I-N, in order to find a treatment which could be easily applied to the infrared plates to be used with the Loiano 152 cm,f/8, Ritchey-Chrétien telescope. Different techniques have been tested, not only with the aim of achieving the higher speed gain, but also to obtain the better uniformity and reproducibility. Our results suggest that the advantages of preexposure techniques are underestimated in this respect. Furthermore, we find that blue and infrared preexposures (at 0.8 s) give different results, suggesting a different degree of dispersity in the latent image produced by pre-exposure in the two cases.Baths including both ammonia and Ag-compounds provide the higher speed gains, but the increment of the fog is often non-uniform and/or very high. The best results have been obtained with baths including AgNO₃ and AgCl. The rejuvenation process found by Sanduleak and the results obtained by Jenkins and Farnell on the reversibility of the gains due to silver-nitrate baths have been confirmed.     

Compton scattering of relativistic electrons in compact X-ray sources

The problem of single Compton scattering is considered and the resulting spectrum, angular distribution and polarization of scattered photons in a general case are obtained. The inverse Compton scattering (ICS) for arbitrary energies of electronsE and photons ₀ is investigated in detail. In the case of isotropically-distributed initial photons and relativistic electrons, a strong rise of the scattered spectrum near the upper edge takes place, starting from the values of the characteristic parameterb4E ₀10 (in units of mc²=1). The energy-loss rate of relativistic electrons due to ICS is calculated. It is shown that the relativistic electrons of the energiesE100 MeV, when scattering on the X-rays with ₀~10KeV, transmit the dominant part of their energy to the photons which fall after scattering into the energy range of the electrons (100 MeV).The radiation spectrum of ICS, as well as the energy-losses of relativistic electrons distributed by power-lawE ^–, are calculated. The radiation spectrum reveals the power-law behaviour with the different indices in two limits: the dependence ^–(1)/2 at ₀1 gradually changes to ^–(+1) ln (₀) law for ₀1.     

The spectra and light curves of two gamma-ray bursts

During the last half of 1977 the UCSD/MIT Hard X-Ray and Low Energy Gamma-Ray Experiment of HEAO-1 observed two of the three gamma-ray bursts detected by at least three satellites. The first of these bursts (20 October, 1977) had a fluence of (3.1±0.5)×10^–5 erg cm^–2 integrated over the energy range 0.135–2.05 MeV and over its duration of 38.7 s, placing it among the largest bursts observed. The second (10 November, 1977) had a fluence of (2.1±0.8)×10^–5 erg cm^–2 integrated over the energy range 0.125–3 MeV and over its duration of 2.8 s. The light curves of both bursts exhibit time fluctuations down to the limiting time resolution of the detectors (0.1 s). The spectrum of the 20 October, 1977 burst can be fitted with a power law (index –1.93±0.16), which is harder than other reported gamma-ray burst spectral fits. This burst was detected up to 2.05 MeV, and approximately half of its energy was emitted at photon energies above 0.5 MeV. The spectrum of the 10 November, 1977 burst is softer (index –2.4±0.7) and is similar to the spectrum of the 27 April, 1972 burst.Paper presented at the Symposium on Cosmic Gamma-Ray Bursts held at Toulouse, France, 26–29 November, 1979.     

OSO-8 observations of CaII H and K,MgII h and k,Lα and Lβ above a sunspot

Observations with the French (L.P.S.P.) experiment on board OSO-8 of a sunspot and nearby plage region are described. The behaviour of the emission cores of the Ca II H and K and Mg II h and k resonance lines is very similar and the correspondence in intensity between the four lines persists in all observed features. In contrast, the Lyman lines show little correlation with the other lines. Their emission regions appear broader in the spectroheliograms than the underlying sunspot structure and must not necessarily possess a counterpart in lower layers. From the central intensity of L above the umbra an electron density of 4.3 × 10¹⁰ cm^-3 n _e ^* 2.3 × 10¹¹ cm^-3 at 20 000 K is estimated.Mitteilungen aus dem Kiepenheuer-Institut Nr. 186.Stockholm Observatorium, S-13300 Saltsjöbaden, Sweden.Laboratoire de Physique Stellaire et Planétaire, CNRS, P.O. Box 10, F-91370 Verrières-le-Buisson, France.     

On periodic flybys of the moon

This paper considers the plane circular restricted three-body problem for small . Symmetric periodic solutions of the second species (passing near the body of mass ) and their distance from the center of the body of mass are studied by constructing perturbations of arc-solutions (solutions with consecutive collisions) existing for =0. Orbits which also pass near the body of mass 1- are studied in detail. The results are applied to finding periodic orbits in the Earth-Moon system and in the Sun-Jupiter system.Russian version: Preprint No. 91 (1978) of Inst. Appl. Math.; present English translation was made by L. M. Perko and W. C. Schulz (February 1979).     

The inter-relationship of hard X-ray and EUV bursts during solar flares

A comparison is made between the flux-versus-time profile in the EUV band and the thick target electron flux profile as inferred from hard X-rays for a number of moderately large solar flares. This complements Kane and Donnelly's (1971) study of small flares. The hard X-ray data are from ESRO TD-1A and the EUV inferred from SFD observations.Use of a ₂ minimising method shows that the best overall fit between the profile fine structures obtains for synchronism to 5 s which is within the timing accuracy. This suggests that neither conduction nor convection is fast enough as the primary mechanism of energy transport into the EUV flare and rather favours heating by the electrons themselves or by some MHD wave process much faster than acoustic waves.The electron power deposited, for a thick target model, is however far greater than the EUV luminosity for any reasonable assumptions about the area and depth over which EUV is emitted. This means that either most of the power deposited is conducted away to the optical flare or that only a fraction 1–10% of the X-ray emitting electrons are injected downwards. Recent work on H flare heating strongly favours the latter alternative - i.e. that electrons are mostly confined in the corona.