Land use and the spatial distribution of perfluoroalkyl compounds as measured in the plasma of bottlenose dolphins (Tursiops truncatus)

The distribution of perfluoroalkyl compounds (PFCs) in the environment is well documented with higher concentrations observed in wildlife located in industrial and urban areas. This study examined the distribution of PFCs in relation to land use using blood samples collected from bottlenose dolphins during capture-release health assessment surveys conducted in Charleston, SC. The study area was partitioned into three subareas (ACW, CHS, and SRE) based upon habitat and land use characteristics. The ACW and CHS subareas are characterized by high degrees of industrial and urban land uses, while the SRE subarea is more residential and characterized by a lower degree of developed land use. Long-term monitoring data from photo-identification surveys were used to group bottlenose dolphins based on their proportions of sightings in the different subareas. Dolphins affiliated with both the ACW and CHS subareas were observed to have significantly higher mean plasma concentrations of perfluorooctane sulfonate (PFOS), perfluorodecanoic acid (PFDA) and perfluoroundecanoic acid (PFUnA) than those affiliated with the SRE subarea. Dolphins affiliated with the ACW subarea were found to have a significantly higher mean plasma concentration of PFUnA than those affiliated with the CHS subarea. Further examination of the distribution of the PFCs revealed positive correlations with developed land uses and negative correlations with wetland/marsh land cover. A positive correlation was also observed between PFUnA and agricultural land use. The variability and scale of the observed contaminant burdens have important implications for the conservation and management of living marine resources and illustrates the importance of long-term monitoring of free-ranging wildlife species.     

The assessment of vitellogenin as a biomarker of exposure to estrogenic compounds in two Australian perciformes

Vitellogenin (Vtg) is a yolk protein precursor that has been identified as a sensitive biomarker for exposure to estrogenic compounds. We evaluated specific monoclonal and polyclonal antibodies for reactivity with plasma Vtg from two Australian Perciformes, the tropical barramundi (Lates calcarifer) and the temperate black bream (Acanthopagrus butcheri). Blood plasma from 17beta-estradiol exposed (E2) male barramundi (20 mg kg(-1)) and male black bream (2.5-5.0 mg kg(-1)) were sent to Biosense Laboratories (Norway) for cross-reactivity testing using their extensive anti-Vtg antibody selection. Indirect ELISA results determined barramundi plasma displayed the highest binding affinities to ND-3G2 (monoclonal-Mab) and PO-1 (polyclonal-Pab). Black bream was most cross-reactive with ND-1C8 (Mab) and PO-2 (Pab). Next, plasma was assessed for Vtg induction in E2-dosed (5 mg kg(-1)), hatchery-reared barramundi and black bream versus a non-injected control group. Vtg production was assessed by Western blot and indirect ELISA using ND-3G2 and ND-1C8 Mabs, respectively. A prominent band was identified in the range of 100-200 kDa for all female black bream and for all E2-treated barramundi and black bream males, which was confirmed as Vtg by Western blot. Indirect ELISA results for barramundi demonstrated highly significant differences in E2-dosed fish as compared to control fish (Student t, P<0.001). E2 male black bream were significantly different than control males (Student t, P<0.001) and control and E2 females displayed highly significant differences (Student t, P<0.001). These results indicate that exposure to 17beta-estradiol induces significant Vtg production in males of the two Australian Perciformes, with potential use as a biomarker for exposure to estrogenic compounds.     

Near-field dispersion of produced formation water (PFW) in the Adriatic Sea: an integrated numerical-chemical approach

Produced formation waters (PFWs), a by-product of both oil and gas extraction, are separated from hydrocarbons onboard oil platforms and then discharged into the sea through submarine outfalls. The dispersion of PFWs into the environment may have a potential impact on marine ecosystems. We reproduce the initial PFW-seawater mixing process by means of the UM3 model applied to offshore natural gas platforms currently active in the Northern Adriatic Sea (Mediterranean Sea). Chemical analyses lead to the identification of a chemical tracer (diethylene glycol) which enables us to follow the fate of PFWs into receiving waters. The numerical simulations are realized in different seasonal conditions using both measured oceanographic data and tracer concentrations. The numerical results show the spatial and temporal plume development in different stratification and ambient current conditions. The analytical approach measures concentrations of the diethylene glycol at a maximum sampling distance of 25 m. The results show a good agreement between field observations and model predictions in the near-field area. The integration of numerical results with chemical analyses also provides new insight to plan and optimize PFW monitoring and discharge.     

H2 PRODUCTION BY ANABAENA VARIABILIS MUTANT IN COMPUTER CONTROLLED TWO-STAGE AIR-LIFT TUBULAR PHOTOBIOREACTOR

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Water evacuations in remote tourist regions: evaluating case studies from natural hazards in North Patagonian lakes,Argentina

The remote North Patagonian region is a sparsely populated territory and a world famous tourist destination located on the leeward side of the Andes Mountains. Recent disasters triggered by various types of geoenvironmental hazards(including volcanic eruptions, mass-wasting processes and extreme weather events) heavily disrupted ground transport networks in a region with already limited territorial accessibilities. All these catastrophes prompted the need to evacuate or assist a number of seclud...     

Nonlinear numerical assessment of the seismic response of hillside RC buildings

Major damage has been reported in hilly areas after major earthquakes,primarily because of two special conditions:the variation in the seismic ground motion due to the inclined ground surface and the irregularities caused by a stepped base level in the structure.The aim of this study is to evaluate possible differences in the responses of Chilean hillside buildings through numerical linear-elastic and nonlinear analyses.In the first step,a set of response-spectrum analyses were performed on four simplified 2D structures with mean base inclination angles of 0°,15°,30°,and 45°.The structures were designed to comply with Chilean seismic codes and standards,and the primary response parameters were compared.To assess the seismic performance of the buildings,nonlinear static(pushover)and dynamic(time-history)analyses were performed with SeismoStruct software.Pushover analyses were used to compare the nonlinear response at the maximum roof displacement and the damage patterns.Time-history analyses were performed to assess the nonlinear dynamic response of the structures subjected to seismic ground motions modified by topographic effects.To consider the topographic modification,acceleration records were obtained from numerical models of soil,which were calculated using the rock acceleration record of the Mw 8.01985 Chilean earthquake.Minor differences in the structure responses(roof displacements and maximum element forces and moments)were caused by the topographic effects in the seismic input motion,with the highly predominant ones being the differences caused by the step-back configuration at the base of the structures.High concentrations of shear forces in short walls were observed,corresponding to the walls located in the upper zone of the foundation system.The response of the structures with higher angles was observed to be more prone to fragile failures due to the accumulation of shear forces.Even though hillside buildings gain stiffness in the lower stories,resulting in lower design roof displacement,maximum roof displacements for nonlinear time-history analyses remained very close for all the models that were primarily affected by the drifts of the lower stories.Additionally,vertical parasitic accelerations were considered for half the time-history analyses performed here.The vertical component seems to considerably modify the axial load levels in the shear walls on all stories.     

A Large Therizinosauroid （Dinosauria： Theropoda） from the Early Cretaceous of Northwestern China

We herein describe an associated partial postcranial skeleton of a theropod dinosaur discovered in the Lower Cretaceous Xinminpu Group of the Yujingzi Basin, in the Jiuquan area of Gausu Province, northwestern China. Features of its humerus, such as strongly expanded proximal and distal ends, a well developed medial tuberosity, distal condyles expressed on the humeral cranial surface, and a hypertrophied entepicondyle, definitively establish the therizinosauroid affinities of the specimen. It differs from other therizinosauroids in having a shallow, poorly demarcated glenoid fossa with a prominent rounded and striated tumescence on the dorsomedial surface of its scapular portion, and a pubis with a strongly concave cranial margin. It represents a new taxon, Suzhousaurus megatherioides gen. et sp. nov. Cladistic analysis recovers Suzhousaurus as the sister taxon of Nothronychus mckinleyi from the mid-Cretaceous of western North America; together, they are basal members of the Therizinosauroidea, more derived than the Early Cretaceous Falcarius and Beipiaosaurus but less derived than Alxasaurus and the Therizinosauridae. Along with ＂Nanshiungosaurus＂ bohlini from possibly coeval beds in the Mazongshan area of northern-most Gansu, Suzhousaurus represents one of the largest-known Early Cretaceous therizinosauroids, demonstrating that this clade attained considerable body size early in its evolutionary history.     

On the Forcing of the Radial-vertical Circulation within Cyclones-Part 1: Concepts and Equations

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中国大陆地区对流层臭氧及痕量气体测量与气候变化的关系

中国和亚洲人口的增长、流动、城市的扩张以及工业的不断发展正影响着局地、区域甚至整个全球范围的空气质量、大气化学及气候系统。近年来，研究组一直在香港和中国大陆地区从事空气污染方面研究。本概述了中国大陆和香港地区对流层臭氧和痕量气体的变化情况，特别就东南亚地区生物体燃烧释放对对流层臭氧的影响及中国华南地区气候变化之间的关系作了讨论。     

热带和中高纬地区季节内振荡的特征及其动力学诊断

使用5年低阶全球谱模式资料,对中高纬大气和热带大气季节内振荡的动力学性质和传播特征进行了诊断研究。分析发现模式再现了大气中季节内振荡在热带和中高纬地区的传播特性以及它们之间的差异。热带大气30—60天振荡在速度势场上表现为纬向—波结构和行波特性,而在散度风场上反映了赤道西太平洋—印度洋东西向偶极子型的振荡。中高纬大气30—60天振荡表现为定常波位相和振幅的变化,即波包络的传播特征。它与中高纬地区遥相关型的转换有关,通过遥相关位相和振幅的变化,不仅完成了热带和中高纬地区之间以及热带不同区域之间的能量输送,而且通过这种能量输送过程把南、北半球中高纬地区季节内振荡联系起来。