3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.     

Stochastic evaluation of simple pairing approaches to reconstruct incomplete rainfall time series

Two-station pairing approaches are routinely used to infill missing information in incomplete rainfall databases. We evaluated the performance of three simple methodologies to reconstruct incomplete time series in presence of variable nonlinear correlation between data pairs. Nonlinearity stems from the statistics describing the marginal peak-over-threshold (POT) values of rainfall events. A Monte Carlo analysis was developed to quantitatively assess expected errors from the use of chronological pairing (CP) with linear and nonlinear regression and frequency pairing (FP). CP is based on a priori selection of regression functions, while FP is based on matching the probability of non-exceedance of an event from one time series with the probability of non-exceedance of a similar event from another time series. We adopted a generalized Pareto (GP) model to describe POT events, and a t-copula algorithm to generate reference nonlinearly correlated pairs of random temporal distributions distributed according with the GP model. The results suggest that the optimal methodology strongly depends on GP statistics. In general, CP seems to provide the lowest errors when GP statistics were similar and correlation became linear; we found that a power-2 function performs well for the selected statistics when the number of missing points is limited. FP outperforms the other methods when POT statistics are different and variables are markedly nonlinearly correlated. Ensemble-based results seem to be supported by the analysis of observed precipitation at two real-world gauge stations.     

Studying local sources in the radio range based on the partial solar eclipse of January 4, 2011, at the Mountain Astronomical Station, Central Astronomical Observatory, Russian Academy of Sciences

Data are presented on a partial solar eclipse, which occurred on January 4, 2011, and was observed with RT-3 (?? = 4.9 cm) and RT-2 (?? = 3.2 cm) radio telescopes at the Mountain Astronomical Station, Central Astronomical Observatory, Russian Academy of Sciences (MAS CAO RAS). The radioemission flux in two channels was registered using digital methods with a time resolution of 0.5 s. Comparisons were performed with observations in the optical, UV, and X-ray ranges. The following local sources of increased radioemission on the solar disk have been identified: sunspot groups 1 (NOAA 1142) and 126 (NOAA 1141), unipolar sunspot 127 (NOAA 1140), facula areas, and polar and midlatitude coronal holes. It has been indicated that the brightness of a unipolar sunspot (for ?? = 4.9 cm, I _rel = 29.5; for ?? = 3.2 cm, I _rel = 10.1) and two sunspot groups (for ?? = 4.9 cm, I _rel = 10.1 and 14.2; for ?? = 3.2 cm, I _rel = 5.1 and 6.2) is maximal. The radioemission flux of all found coronal holes is decreased, and the decrease is more contrasting in the 4.9-cm range as compared to such a decrease in the 3.2-cm range. Radio maps of the Sun and changes in the radioemission flux of undisturbed solar regions from the center to the limb for ?? = 4.9 and 3.2 cm have been constructed based on the eclipse data.     

On Geoseismic Noise and Helioseismic Oscillations

Izvestiya, Physics of the Solid Earth - Abstract—In their paper published in Izvestiya, Physics of the Solid Earth, G.A. Sobolev et al. (2020) discussed the results of their study. Firstly,...     

Wind and freshwater influence over hydrocarbon dispersal on Patos Lagoon, Brazil

The two-dimensional barotropic, hydrodynamic and transport model MOHID is applied to the Patos Lagoon system using a nested modelling approach to reproduce both the lagoon and estuary hydrodynamics. A new Lagrangian oil spill model is presented and used to simulate a hypothetical oil spill in the estuary. Hydrodynamic fields are validated and used to force the oil model. Results show that the hydrodynamics of this system is mainly controlled by the wind and freshwater discharge. The dispersion, concentration and thickness evolution of the oil in the first day after the spill is determined by the equilibrium between these two factors. The freshwater discharge is the major factor controlling the oil dispersion for discharges greater than 5000 m3 while the wind assumes control for lower discharge amounts. The results presented are a first step toward a coastal management tool for the Patos Lagoon.     

Exploring the diverse potentials of <Emphasis Type="Italic">Planococcus</Emphasis> sp. TRC1 for the deconstruction of recalcitrant kraft lignin

Kraft lignin (KL) is the chief contaminant which is responsible for dark coloration, toxicity and high chemical oxygen demand (COD) of paper pulp mill effluent. The present study investigated the diverse potentials of Planococcus sp. TRC1 in the biodegradation of KL. Preliminary evaluation indicated that the strain was able to grow on broad spectrum of lignin-derived compounds, decolorize lignin-mimicking dyes and catabolize substrates of ligninolytic enzymes. Response surface methodology (RSM) was executed to perform the optimization of different process parameters. The results displayed that Planococcus sp. TRC1 could completely utilize 100 mg L^?1 of KL and 78% of 200 mg L^?1 of KL as sole source of carbon with concurrent reduction in COD and color. The biokinetic details of KL biodegradation showed that the values of \(\mu^{*}\), µ _max, \(q^{*}\) and q _max were 0.018 h^?1, 0.01 h^?1, 0.023 g g^?1 h^?1 and 0.05 g g^?1 h^?1, respectively. UV–visible spectrophotometry, SEM and FTIR indicated the significant alterations in the surface morphology, functional groups and chromophores during the course of biodegradation. XRD revealed the emergence of peak signifying the formation of low molecular weight intermediates after bacterial treatment. Considering the environmental impact, bacterial-treated KL illustrated less phytotoxicity using Vigna radiata seed bioassay. These results suggested that Planococcus sp. TRC1 could be a promising strain for the degradation of KL in an ecofriendly way.